合浦珠母贝铁的穆斯堡尔谱学研究     

林伟雄  林岳光等 《台湾海峡》1995,14(2):135-138

应用^57Fe穆斯堡尔谱学的方法研究了四个不同生长期合浦珠母贝铁的化学状态和Fe^2 /Fe^3 的值，它们的Fe^2 和Fe^3 的相对含量分别为4.1%～29.4%和76.6%～95.9%,Fe^2 /Fe^3 值的变化为0.043～0.42。3个月龄的Fe^2 /Fe^3 值大于10个月龄，从10个月龄到22个月龄的Fe^2 /Fe^3 值呈增加的趋势，这可能反映了不同生长期合浦珠母贝对不同价态的铁的需求。  相似文献   

盐酸羟胺-盐酸体系提取黄土中游离氧化铁     

孙玉兵  谢巧勤  陈天虎 《海洋地质与第四纪地质》2007,27(3):133-136

黄土中游离氧化铁是指示夏季风的替代性气候指标之一。使用经典的CBD法提取游离氧化铁实验过程烦琐,而且实验条件不同对浸提结果影响很大。本实验采用盐酸羟胺-盐酸体系在不同的温度下浸提黄土中的游离氧化铁。实验结果表明:温度对实验结果影响最大,盐酸浓度次之。与经典的CBD法进行对比,在一定的条件下可以代替CBD法,从而简化试验。  相似文献   

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis   总被引：1，自引：1，他引：1  

Hongbin Liu  Koji Suzuki  Hiroaki Saito 《Journal of Oceanography》2004,60(1):119-137

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Native aluminium (spherules and particles) in the Central Indian Basin sediments: Implications on the occurrence of hydrothermal events     

Sridhar D. Iyer  M.B.L. Mascarenhas-Pereira  B. Nagender Nath 《Marine Geology》2007,240(1-4):177-184

We have sampled particles of native aluminium (Al°) in two sediment cores from the Central Indian Basin (CIB). The cores are geographically separated but are located at the base of two seamounts. The native Al° particles occurring as grains and spherules, have an average Al content of  95% and are associated with volcanogenic–hydrothermal material. Morphologically and compositionally, the specimens are similar to those reported from the East Pacific Rise. After ruling out several processes for the presence of the native Al°, we hypothesize that during progressive melting of magma, a basaltic magma is produced which has high contents of reductants such as methane and hydrogen, and a low oxygen fugacity. During the upward migration of such magma, reduction to metallic aluminium and the formation of native Al° particles takes place.  相似文献   

江苏镇江韦岗铁矿区深部找矿前景分析   总被引：1，自引：0，他引：1       下载免费PDF全文

黄震  黄建平 《江苏地质》2008,32(3):184-188

镇江韦岗铁矿是一个已经勘查开发数十年的老矿山,目前保有资源储量保证程度已达严重危机。分析矿区成矿地质条件和矿床特征,铁矿体主要分布在碳酸盐岩层与中酸性侵入岩的接触带上,铁矿体普遍磁性强,且在地表形成一定规模的磁异常,梯度北陡南缓,向南有规则地递减呈梯形散开,说明矿体有一定的延伸。深部已施工的见矿钻孔和井中磁测异常对应,反映矿区深部-200m～-800m找矿前景良好。  相似文献   

河南省卢氏县张家山铁矿地质特征及成因浅析     

周红春  刘传权  郭克剑  彭松民  张毅星  王凌云 《华南地质与矿产》2008,(2):43-48

通过对张家山铁矿床矿体与围岩的接触关系、蚀变特征、矿石的矿物组合、化学组分等地质特征及成因的分析研究,认为张家山铁矿床应属风化淋滤型铁矿床,其原生矿床为铁多金属硫化物矿床,并厘定了该地区铁矿的找矿标志。  相似文献   

Rare Earth Deposits of North America     

Stephen B. Castor 《Resource Geology》2008,58(4):337-347

Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor.  相似文献   

酸性矿山废水中生物成因次生高铁矿物的形成及环境工程意义   总被引：10，自引：1，他引：9  

周立祥 《地学前缘》2008,15(6)

酸性矿山废水(acid mine drainage,AMD)是一类pH低并含有大量有毒金属元素的废水。AMD及受其影响的环境中次生高铁矿物类型主要包括羟基硫酸高铁矿物(如黄铁矾和施威特曼石等)和一些含水氧化铁矿物(如针铁矿和水铁矿等),而且这些矿物在不同条件下会发生相转变,如施氏矿物向针铁矿或黄铁矾矿物相转化。基于酸性环境中生物成因次生矿物的形成会"自然钝化"或"清除"废水中铁和有毒金属这一现象所获得的启示,提出利用这些矿物作为环境吸附材料去除地下水中砷,不但吸附量大(如施氏矿物对As的吸附可高达120mg/g),而且可直接吸附As(III),还几乎不受地下水中其他元素影响。利用AMD环境中羟基硫酸高铁矿物形成的原理,可将其应用于AMD石灰中和主动处理系统中,构成"强化微生物氧化诱导成矿-石灰中和"的联合主动处理系统,以提高AMD处理效果和降低石灰用量。利用微生物强化氧化与次生矿物晶体不断生长的原理构筑生物渗透性反应墙(PRB)并和石灰石渗透沟渠耦联,形成新型的AMD联合被动处理系统,这将有助于大幅度增加处理系统的寿命和处理效率。此外,文中还探讨了上述生物成因矿物形成在AMD和地下水处理方面应用的优点以及今后需要继续研究的问题。  相似文献   

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes     

Eric A. Betterton 《Journal of Atmospheric Chemistry》1993,17(4):307-324

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.  相似文献   

Kinetics of redox cycling of iron coupled with fulvic acid     

Yiwei Deng  Werner Stumm 《Aquatic Sciences - Research Across Boundaries》1993,55(2):103-111

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献