Au–Ag–Te Mineralization of the Low‐Sulfidation Epithermal Aginskoe Deposit,Central Kamchatka,Russia     

Elena D. Andreeva  Hiroharu Matsueda  Victor M. Okrugin  Ryohei Takahashi  Shuji Ono 《Resource Geology》2013,63(4):337-349

Mineralogic studies of major ore minerals and fluid inclusion analysis in gangue quartz were carried out for the for the two largest veins, the Aginskoe and Surprise, in the Late Miocene Aginskoe Au–Ag–Te deposit in central Kamchatka, Russia. The veins consist of quartz–adularia–calcite gangue, which are hosted by Late Miocene andesitic and basaltic rocks of the Alnei Formation. The major ore minerals in these veins are native gold, altaite, petzite, hessite, calaverite, sphalerite, and chalcopyrite. Minor and trace minerals are pyrite, galena, and acanthine. Primary gold occurs as free grains, inclusions in sulfides, and constituent in tellurides. Secondary gold is present in form of native mustard gold that usually occur in Fe‐hydroxides and accumulates on the decomposed primary Au‐bearing tellurides such as calaverite, krennerite, and sylvanite. K–Ar dating on vein adularia yielded age of mineralization 7.1–6.9 Ma. Mineralization of the deposit is divided into barren massive quartz (stage I), Au–Ag–Te mineralization occurring in quartz‐adularia‐clays banded ore (Stage II), intensive brecciation (Stage III), post‐ore coarse amethyst (Stage IV), carbonate (Stage V), and supergene stages (Stage VI). In the supergene stage various secondary minerals, including rare bilibinskite, bogdanovite, bessmertnovite metallic alloys, secondary gold, and various oxides, formed under intensely oxidized conditions. Despite heavy oxidation of the ores in the deposit, Te and S fugacities are estimated as Stage II tellurides precipitated at the log f Te₂ values ?9 and at log fS₂ ?13 based on the chemical compositions of hypogene tellurides and sphalerite. Homogenization temperature of fluid inclusions in quartz broadly ranges from 200 to 300°C. Ore texture, fluid inclusions, gangue, and vein mineral assemblages indicate that the Aginskoe deposit is a low‐sulfidation (quartz–adularia–sericite) vein system.  相似文献   

四川盆地富硫天然气与盆地周缘铅锌铜矿的成因联系   总被引：1，自引：0，他引：1  

李厚民  张长青 《地质论评》2012,58(3):495-510

金属元素的搬运和沉淀是热液矿床成矿机理研究的重要方面。目前人们普遍认为热液矿床中金属元素主要呈硫的络合物和卤素络合物形式搬运。MVT铅锌矿床等硫化物矿床盐度较高,包裹体成分中阳离子以Na+、K+、Ca2+、Mg2+为主,阴离子以Cl-、F-、CO2-3为主,很少有HS-、S2-,表明金属元素主要以氯的络合物形式搬运,外来硫的加入是导致铅锌成矿物质以硫化物形式沉淀成矿的关键。四川盆地天然气中富含H2S,其与周缘MVT铅锌矿床具有密切的时空关系,据此推测天然气中的H2S可能是导致铅锌硫化物沉淀形成MVT铅锌矿床的主要硫源,天然气中的H2S与铅锌成矿流体在古油藏中作用形成含沥青的铅锌矿床;当含硫化氢的天然气运移离开古油藏后与含矿流体混合时,形成不含沥青的铅锌矿床。另外,石油热裂解产生的不含H2S的天然气使得含铜热液中的铜还原,以自然铜形式沉淀形成含沥青的玄武岩铜矿;石油热化学硫酸盐还原(TSR)过程中,还会发生溶蚀作用,扩大碳酸盐岩孔隙,为成矿提供空间。  相似文献   

电感耦合等离子体发射光谱法测定铬矿石中的二氧化硅     

王小强  杨惠玲 《岩矿测试》2012,31(5):820-823

以过氧化钠为熔剂,经高温熔融-热水提取-盐酸酸化前处理样品,选用金为内标元素,电感耦合等离子体发射光谱法测定铬矿石中的二氧化硅。试验了熔融试样时引入的基体元素钠对被测元素的干扰情况,结果表明,钠含量高于300 mg/L时,二氧化硅的回收率均低于92.5%。采用金内标法有效克服了基体效应及仪器波动产生的影响,改善和提高了准确度和精密度。二氧化硅的检出限为0.0075 mg/L,测定范围为0.025%～10.0%。对铬矿石标准物质进行测定,结果与标准值一致,方法精密度(RSD,n=9)小于2%。与常规化学分析法进行比对试验,二氧化硅的测定值吻合较好,但克服了常规化学分析方法步骤繁琐、耗时长、工作量大的不足,提高了工作效率。本方法也可用于同时测定铬矿石中铝、铁、钙、镁、磷等主次量成分。  相似文献   

Epigenetic hydrothermal origin of native copper and supergene enrichment in the Vista Alegre district,Paraná basaltic province,southernmost Brazil     

《International Geology Review》2012,54(10):1163-1179

Native copper is widespread in the Lower Cretaceous Paraná basaltic province, southern Brazil, both as films in fractures and as massive balls in amygdules. The focus of this investigation is on the large concentration of occurrences (n = 85) that forms the Vista Alegre district in the border region of Rio Grande do Sul and Santa Catarina states. The high average of 220 ppm Cu content of the basalts resulted in ore of native copper, Cu oxides, abundant chrysocolla in the top of mineralizations, and minor malachite and azurite. Native copper is associated with dioctahedral and trioctahedral smectites, zeolites (heulandite and clinoptilonite), quartz, and calcite, typical of a low-T (100–150°C) hydrothermal alteration assembly. The PGE distribution shows enrichment in Pd in relation to Pt both in basalts and in native copper, supporting the hypothesis of hydrothermal origin of the mineralization. No evidence was found of direct precipitation of copper from the lava; based on field and petrographic evidence, integrated with BSE images, EPMA analyses, EGP contents of native copper, and bulk rock analyses, this is an epigenetic hydrothermal copper mineralization, followed by supergene enrichment.  相似文献   

云南省蝉战河自然铜矿床类型及找矿方向研究     

刘恩法  李建全  吕星海  李瑞欣  陈奕霖  任强 《地质与资源》2016,25(2):167-170

扬子地块西南缘是我国重要铜成矿带之一,该区已发现多个典型的火山-沉积碎屑岩型和陆相砂页岩型铜矿.蝉战河铜矿床具有典型的两种矿床类型特征.在系统总结该矿床地质特征的基础上,分析了两种矿床类型的各自特征,初步认为区内具中—大型铜矿成矿条件,并提出了找矿方向.  相似文献   

干旱区不同土壤和作物灌溉量的无机碳淋溶特征实验研究   总被引：2，自引：0，他引：2       下载免费PDF全文

陆晴  王玉刚  李彦  唐立松 《干旱区地理》2013,36(3):450-456

为探讨干旱区作物灌溉对盐碱土无机碳传输的影响,通过选择不同含盐量的土壤,即耕地土（F）、混合土（C）和原生荒漠土（D）,分别种植水稻（R）和棉花（C）,进行了一个生长季的淋溶实验,并定期收取且分析土壤淋溶液中的可溶性无机碳（DIC）含量。结果表明：（1）水稻处理无机碳的淋溶主要集中在秧苗分蘖期和幼穗发育期,而棉花处理则集中在花铃期和吐絮期;（2）不同含盐量土壤在同一灌溉量下,土壤含盐量越高,其淋溶过程得到的无机碳总量越大,最高约为8.4 g·m^-2·a^-1,最低仅约0.7 g·m^-2·a^-1;（3）同种土壤不同灌溉量,其水稻高于棉花,高出值范围为2.9～4.1 g·m^-2·a^-1;种植作物处理得到的无机碳总量均大于其相应对照处理的量（p＜0.05）。研究结果表明,土壤的盐含量及作物灌溉量对土壤无机碳淋溶有重要影响。  相似文献   

广西4大海湾红树林区硅含量的变化特征及其影响因素     

韦蔓新  何本茂  范航清  潘良浩  曹庆先 《广东海洋大学学报》2013,(4)

利用2007年12月至2008年11月对广西沿海4个海湾红树林区进行系统调查的数据资料,分析不同海湾红树林区Si含量的变化特征及其与环境因素的关系。结果表明,广西海湾红树林区Si含量较高,年平均值高达52.26μmol·dm-3,明显高于20世纪80年代河口区的30.83μmol·dm-3;在季节上主要依赖于径流的变化而呈夏高、冬低,春、秋季适中的特征,区域分布亦具有随S下降而增加,随硅藻占浮游植物比例上升而下降的良好规律,依次排列为廉州湾>钦州湾>珍珠湾>铁山港红树林区。相关分析显示,影响研究海区Si含量变化的主要因素是陆源径流与海水的物理混合过程,其次是生物作用,有机体分解的化学过程影响相对较小。Si与N、P营养盐的关系极为密切,其中Si与N的同源性极好,4个季节均达到了非常显著(p值<0.01)的正相关水平;而Si与P含量之间却出现明显分区现象,海湾特征尤为突出。  相似文献   

政府与村民的行为对古村落保护及景观变迁的影响——基于本土社会学理论视角   总被引：3，自引：1，他引：2  

翁时秀  彭华 《地理科学》2011,31(3):372-377

为探究中国古村落景观变迁的发生机理及不同行动者在此过程中的行为逻辑,对浙江省永嘉县境内的楠溪江古村落群进行了案例研究。从本土社会学的理论视角,指出:中国的乡土社会是一个情理社会,国家正式权力镶嵌于乡土文化之中,正式权力与非正式权力、政府与村民的互动推动了古村落景观的变迁。借用"国家-社会"二元框架,将变迁中的行动者分为县(市)政府,乡镇政府,有关系村民和无关系村民四类,指出不同的行动者具有各不相同又彼此联系的行为逻辑,为常态下的中国古村落景观变迁提供了一种行动者类型框架和一种理解方式。  相似文献   

Deep scattering layers resolved by narrow‐beam echo sounder along 35°s in the south pacific     

Dale C. Krause 《新西兰海洋与淡水研究杂志》2013,47(2):219-232

The narrow‐beam echo sounder (3.5° half angle, 20 kHz) is capable of resolving the configuration of deep scattering layers to 750 m and was used to study the ecology and population density of organisms that make up the layers. Several layers to 1,000 m depth were identified in the South Pacific Ocean, and the population densities calculated. Swimming speeds of possible predators are estimated at 0.2–0.3 m.sec‐¹. Among organisms calculated to range in length from 0.01 m to 0.07 m, the larger were interpreted as grazing on smaller organisms, after comparing results from two echo sounders of 12 kHz and 20 kHz frequencies respectively.  相似文献   

The Genetic Relationship between the H2S-bearing Gas in Sichuan Basin and Lead-Zinc-Copper Deposits around the Basin     

LI Houmin  ZHANG Changqing 《地质论评》2012,58(3)

金属元素的搬运和沉淀是热液矿床成矿机理研究的重要方面.目前人们普遍认为热液矿床中金属元素主要呈硫的络合物和卤素络合物形式搬运.MVT铅锌矿床等硫化物矿床盐度较高,包裹体成分中阳离子以Na+、K+、Ca2+、Mg2+为主,阴离子以Cl-、F-、CO32-为主,很少有HS-、S2-,表明金属元素主要以氯的络合物形式搬运,外来硫的加入是导致铅锌成矿物质以硫化物形式沉淀成矿的关键.四川盆地天然气中富含H2S,其与周缘MVT 铅锌矿床具有密切的时空关系,据此推测天然气中的H2S可能是导致铅锌硫化物沉淀形成MVT铅锌矿床的主要硫源,天然气中的H2S与铅锌成矿流体在古油藏中作用形成含沥青的铅锌矿床;当含硫化氢的天然气运移离开古油藏后与含矿流体混合时,形成不含沥青的铅锌矿床.另外,石油热裂解产生的不含H2S的天然气使得含铜热液中的铜还原,以自然铜形式沉淀形成含沥青的玄武岩铜矿;石油热化学硫酸盐还原(TSR)过程中,还会发生溶蚀作用,扩大碳酸盐岩孔隙,为成矿提供空间.  相似文献