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101.
含钒石煤的穆斯堡尔谱研究 总被引:2,自引:0,他引:2
本文收集了我国湘鄂淅地区含钒石煤样品,使用化学分析和穆斯堡尔谱方法,测定和研究了石煤中钒铁的赋存方式和价态,以及不同焙烧温度下钒铁价态变化等。初步研究表明,石煤中钒铁价态及价态变化的测定,对含钒石煤中钒铁矿物和成因研究,钒的提取和石煤的综合利用有重要意义。 相似文献
102.
J. N. Desai 《Journal of Earth System Science》1984,93(3):189-200
The paper describes use of Fabry-Perot (fp) systems in spectroscopic studies of astronomy and earth’s upper atmosphere. Factors influencing the resolution, luminosity
and instrumental line shape offp spectrometer are discussed and the need for their optimization is emphasised, if desired luminosity gain is to be realised
in practice. Use offp as imaging spectrometer, scanning spectrometer and as a narrow band filter are illustrated. Tandemfp systems are briefly dealt with. 相似文献
103.
D. Perner U. Platt M. Trainer G. Hübler J. Drummond W. Junkermann J. Rudolph B. Schubert A. Volz D. H. Ehhalt K. J. Rumpel G. Helas 《Journal of Atmospheric Chemistry》1987,5(2):185-216
Using long path UV absorption spectroscopy we have measured OH concentrations close to the earth's surface. The OH values observed at two locations in Germany during 1980 through 1983 range from 0.7×106 to 3.2×106 cm-3. Simultaneously we measured the concentrations of O3, H2O, NO, NO2, CH4, CO, and the light non methane hydrocarbons. We also determined the photolysis rates of O3 and NO2. This allows calculations of OH using a zero dimensional time depdendent model. The modelled OH concentrations significantly exceed the measured values for low NO
x
concentrations. It is argued that additional, so far unidentified. HO
x
loss reactions must be responsible for that discrepancy. 相似文献
104.
浙江缙云斜发沸石水的核磁共振分析 总被引:1,自引:0,他引:1
本文应用宽线NMR技术,结合红外测定,研究了缙云斜发沸石中水的结构类型、存在状态、运动特征和热稳定性。结果表明:缙云斜发沸石中的沸石水按其运动特性可以分为受阻旋转水、自由旋转水和自扩散运动水三种类型,它们以谱线中分裂的双线和线宽不同的单峰相区别。低温时,受阻旋转运动的水在晶格中转变为刚性配置。其脱水次序决定于各类型水与沸石结构骨架键合的强弱,脱水是连续的。研究显示缙云斜发沸石的结构骨架相当疏宽,骨架对水分子的吸引力没有严格的方向性,这一特性有利于阳离子的交换。 相似文献
105.
Yoshihiro Uji 《Organic Geochemistry》1986,9(6)
This study examines the effect of contact metamorphism by an igneous dyke on parameters for kerogen maturation, such as elemental composition (H/C, O/C, N/C), 1H-NMR T1, vitrinite reflectance and infrared spectra. Although elemental composition and 1H-NMR T1 of the kerogen changed only within 1.5 and 5.0 m from the dyke respectively, vitrinite reflectance of the kerogen was thermally affected beyond 10.0 m from the intrusion. It is concluded that vitrinite reflectance is the most sensitive of the parameters evaluated to assess thermal stress of kerogens. 相似文献
106.
An infrared routine has been developed to estimate the aliphatic portion of kerogen carbon in sedimentary rocks. The procedure does not require isolation of the organic matter and is based on a computer-assisted determination of global band areas in the region of the aliphatic carbon-hydrogen stretching vibrations around 2900cm−1. From these integrated absorptions the amount of aliphatic carbon Cal (mg of aliphatic carbon per gram of solvent-extracted rock) is calculated by means of a calibration with model rocks. Carbonate overtones which interfere in the case of limestones are eliminated by comparison to a CaCO3 standard.The method has been applied to rocks containing kerogens of different types and maturities at TOC levels of 0.5 to 12%. The aliphatic carbon concentrations range from 0.5 to 60mg·g−1 and correlate reasonably well with the residual genetic potentials of the rocks as measured by S2 values from Rock-Eval pyrolysis. The ratio S2/Cal is found to decrease with burial depth reflecting a maturity enhanced conversion of aliphatic carbon to fixed aromatic carbon under Rock-Eval conditions. 相似文献
107.
Based on the tested data of pressure and vitrinite reflectance of some wells in sedimentary basins, abnormal high pressure
is regarded as not the only factor to retard the increase of vitrinite reflectance (R
o). Apart from the types of the organic matter, the physical environment (temperature and pressure) and chemical environment
(fluid composition and inorganic elements) will result in the abnormal vitrinite reflectance values in the sedimentary basins.
This paper tested trace elements and vitrinite reflectance data from the the abnormal high pressure and normal pressure strata
profiles, respectively, and found that the acidic and lower salinity starta are favorable for the increase of R
o. By discussing the corresponding relationship between the contents of some trace elements in the mudstone and the vitrinite
reflectance values, the typical trace elements were found to suppress and/or catalyze the vitrinite reflectance of organic
matter, while the elements of Ca, Mn, Sr, B, Ba and P may result in the retardation of R
o. However, elements of Fe, Co, Zn, Ni and Rb may catalyze the organic matter maturation. This study is conductive to the organic
maturation correction, oil and gas assessment and thermal history reconstruction by the paleothermometry.
Translated from Acta Geologica Sinica, 2006, 80(11): 1760–1769 [译自: 地质学报] 相似文献
108.
利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿 总被引:5,自引:0,他引:5
针铁矿(Gt)和赤铁矿(Hm)是广泛存在于土壤和沉积物中的重要铁矿物。这两种矿物在土壤和沉积物中含量很低,常规的测试手段很难有效地测定其含量。利用反射光谱联合加热处理的方法,可对土壤及沉积物样品中针铁矿和赤铁矿进行定性或半定量测定。实验结果显示,样品加热到300℃后,针铁矿的反射光谱的一阶导数特征峰发生了变化,赤铁矿的一阶导数特征峰却没有明显的变化。因此加热前后样品反射光谱一阶导数的变化取决于针铁矿和赤铁矿的含量。利用这种方法估计黄土高原第三纪红粘土样品中的赤铁矿含量约为0.3%~0.4%,针铁矿含量约为0.5%~1%。 相似文献
109.
Shin-Ichi Machida Hisako Hirai Taro Kawamura Yoshitaka Yamamoto Takehiko Yagi 《Physics and Chemistry of Minerals》2007,34(1):31-35
High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa
at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν
1 appeared at 17 GPa and that the splitting of vibration mode of ν
3 occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between
the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might
result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up
to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman
shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into
another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition
of the structure. 相似文献
110.
Sven-Ulf Weber Michael Grodzicki Werner Lottermoser Günther J. Redhammer Gerold Tippelt Johann Ponahlo Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515
Natural alexandrite Al2BeO4:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by 57Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The 57Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe3+ and Fe2+, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe3+ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe3+ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe3+ on M1. 相似文献