The Gronnedal-Ika Carbonatite-Syenite Complex, South Greenland: Carbonatite Formation by Liquid Immiscibility   总被引：1，自引：0，他引：1  

HALAMA  RALF; VENNEMANN  TORSTEN; SIEBEL  WOLFGANG; MARKL  GREGOR 《Journal of Petrology》2005,46(1):191-217

The Grønnedal-Ika complex is dominated by layered nephelinesyenites which were intruded by a xenolithic syenite and a centralplug of calcite to calcite–siderite carbonatite. Aegirine–augite,alkali feldspar and nepheline are the major mineral phases inthe syenites, along with rare calcite. Temperatures of 680–910°Cand silica activities of 0·28–0·43 weredetermined for the crystallization of the syenites on the basisof mineral equilibria. Oxygen fugacities, estimated using titanomagnetitecompositions, were between 2 and 5 log units above the fayalite–magnetite–quartzbuffer during the magmatic stage. Chondrite-normalized REE patternsof magmatic calcite in both carbonatites and syenites are characterizedby REE enrichment (La_CN–Yb_CN = 10–70). Calcite fromthe carbonatites has higher Ba (5490 ppm) and lower HREE concentrationsthan calcite from the syenites (54–106 ppm Ba). This isconsistent with the behavior of these elements during separationof immiscible silicate–carbonate liquid pairs. _Nd(T =1·30 Ga) values of clinopyroxenes from the syenites varybetween +1·8 and +2·8, and _Nd(T) values of whole-rockcarbonatites range from +2·4 to +2·8. Calcitefrom the carbonatites has ¹⁸O values of 7·8 to 8·6and ¹³C values of –3·9 to –4·6. ¹⁸Ovalues of clinopyroxene separates from the nepheline syenitesrange between 4·2 and 4·9. The average oxygenisotopic composition of the nepheline syenitic melt was calculatedbased on known rock–water and mineral–water isotopefractionation to be 5·7 ± 0·4. Nd and C–Oisotope compositions are typical for mantle-derived rocks anddo not indicate significant crustal assimilation for eithersyenite or carbonatite magmas. The difference in ¹⁸O betweencalculated syenitic melts and carbonatites, and the overlapin _Nd values between carbonatites and syenites, are consistentwith derivation of the carbonatites from the syenites via liquidimmiscibility. KEY WORDS: alkaline magmatism; carbonatite; Gardar Province; liquid immiscibility; nepheline syenite  相似文献   

冀北甲山正长岩的矿物学、地球化学及Sr-Nd同位素特征     

杨富全  吴海  刘晓文  夏浩东  马伯永  邓会娟  左文喆 《现代地质》2005,19(4):522-530

甲山岩体形成于早白垩世晚期,可划分为3个单元。电子探针分析结果表明,碱性长石主要为Na-正长石和歪长石,少量为正长石;角闪石主要为钙角闪石中的铁浅闪石,少数为铁角闪石和铁阳起石;单斜辉石属钙铁辉石和普通辉石。化学成分上,该岩体富S i、全碱、全Fe、REE、Th、Ga、Nb、Zr、H f,贫Mg、Ba、Sr、Ti,Cr、Co、N i、V等过渡元素亏损,富轻稀土,中等铕负异常,具有A型花岗岩的特点。甲山正长岩的N(87Sr)/N(86Sr)初始比值ISr=0.701 41~0.707 41,εNd(t)值为-2.27~-5.58,表明岩浆为富集的大陆岩石圈地幔部分熔融形成。岩石圈的拆沉和减薄作用是引发岩石圈地幔部分熔融的原因之一,岩石圈地幔的富集作用可能发生在中元古代晚期。  相似文献   

Comparison of petrogenetic signatures between mantle-derived alkali silicate intrusives with and without associated carbonatite, Namibia     

B. Bühn  R. B. Trumbull 《Lithos》2003,66(3-4):201-221

We compare the petrogenetic and chemical signatures of two alkali silicate suites from the Cretaceous Damaraland igneous province (Namibia), one with and one without associated carbonatite, in order to explore their differences in terms of magma source and evolution. The Etaneno complex occurs in close spatial proximity to the Kalkfeld bimodal carbonatite–alkali silicate complex, and is dominated by nepheline (ne)-monzosyenites and ne-bearing alkali feldspar syenites. The Etaneno samples have isotopic compositions of ⁸⁷Sr/⁸⁶Sr(i)=0.70462–0.70508 and Nd=−0.5 to −1.5, with the highest ⁸⁷Sr/⁸⁶Sr(i) and lowest Nd values observed in evolved samples. The magma differentiated via olivine, feldspar, clinopyroxene, and nepheline (ne) fractionation in a F-rich system, which fractionated Zr from Hf, and Y from Ho. Partly glassy, recrystallized inclusions in some samples are less evolved than their host rocks and contain a cumulate component (nepheline, plagioclase). The Kalkfeld ne-foidites (ijolites) and ne-syenites have ⁸⁷Sr/⁸⁶Sr(i)=0.70285–0.70592 and Nd=0.5 to 1.1. The isotope ratios show no consistent variation with rock composition, and they are in the same range as the associated carbonatites. The Kalkfeld silicate magma fractionated nepheline and alkali-feldspar in a CO₂-dominated, F- and Ca-poor system. As a result, the rocks display some major and trace element trends distinctly different from those of the Etaneno samples.

We suggest that the Etaneno and the Kalkfeld magmas represent different melt fractions of a heterogeneous mantle source, resulting in different compositions especially with respect to CO₂ contents of the primitive, parental magmas. In this scenario, the carbonated alkali silicate Kalkfeld parental melt contained a critical CO₂ concentration and underwent liquid separation of carbonate and silicate melt fractions at crustal depths. The resulting silicate melt fraction experienced a very different mode of differentiation than the carbonate-poor Etaneno parental magma. Thus, the Kalkfeld rocks are depleted in Ca and other divalent cations, as well as F, rare-earth elements (REE), Ba, and P relative to the Etaneno syenites. We interpret these differences to reflect the partitioning of these elements into the carbonate melt fraction during immiscible separation.  相似文献   

甘肃龙首山芨岭地区古生代正长岩成因及构造意义   总被引：1，自引：0，他引：1  

张志强  王凯兴  王刚  刘晓东  刘文恒  邬斌 《地质论评》2018,64(4):1017-1029

甘肃龙首山芨岭正长岩产于芨岭复式岩体中,产有我国少见的交代岩型铀矿床。为揭示正长岩成因,并探讨其构造意义,本文对正长岩进行了岩相学、年代学、地球化学特征等研究。部分斜长石和石英呈椭圆或圆形以包裹体的形式出现在钾长石中、针状磷灰石和角闪石熔蚀现象都暗示芨岭正长岩可能由两种不同性质的岩浆混合形成。锆石LA-ICP-MS U-Pb定年结果显示,芨岭正长岩形成于427.2±3.6 Ma,与北祁连地区同碰撞花岗岩成岩年龄吻合。芨岭正长岩Si O_2含量中等,全碱含量为8.49%~11.74%,K_2O/Na_2O值为1.07~1.20,属于钾玄岩系列;芨岭正长岩相对富集Rb、Ba、Th、U和Pb,亏损Nb、Ta、P和Ti等元素;稀土元素总量高且相对富集轻稀土,中等Eu亏损;[n(~(87)Sr)/n(~(86)Sr)]_i值为0.70798~0.70799,ε_(Nd)(t)值变化于-3.57~-3.35,与区域I型花岗岩类似。综合岩相学、年代学和地球化学特征表明,芨岭正长岩是由壳—幔岩浆混合而成。芨岭正长岩的形成可能与古祁连洋闭合之后,祁连—柴达木板块和阿拉善板块的碰撞有关。由于古祁连洋在奥陶纪晚期(445 Ma)封闭,祁连—柴达木板块与阿拉善板块碰撞,并俯冲到阿拉善板块之下,碰撞引发龙首山断裂右旋走滑形成的局部伸展环境导致软流圈地幔上涌,并加热大陆地壳物质形成长英质岩浆,该长英质岩浆与地幔岩浆混合形成芨岭正长岩。  相似文献   

洛南任家滩—荞麦山正长斑岩成因及其对古元古代晚期裂解的指示——岩石化学及锆石U- Pb年龄和Lu—Hf同位素特征     

李毅  李佐臣  赵端昌  赵鹏彬  吕军利  张亚峰 《地质论评》2024,70(1):83-101

华北克拉通南缘的陕西洛南—河南豫西地区出露一系列形成于1. 8~1. 6 Ga的碱性岩,对这些碱性岩的研究有助于提高对华北克拉通南缘古元古代构造环境的认识。笔者等选取陕西省洛南县任家滩—荞麦山一带碱性侵入体进行系统的岩石学、LA- ICP- MS锆石U- Pb年代学、Lu—Hf同位素分析和岩石地球化学研究,讨论了其成因机制和构造背景。研究表明,任家滩—荞麦山岩体的主体岩性为正长斑岩,加权平均年龄为1689±20 Ma（MSWD=0. 12）,表明其侵位时代为古元古代。该岩体富碱（Na2O+K2O=7. 95% ~ 9. 5%）,高钾（K2O=4. 67% ~ 8. 51%）;稀土元素总量较高（496. 15×10-6 ~ 650. 16×10-6,平均543. 06×10-6）,轻、重稀土元素分馏比较明显,轻稀土元素相对富集（LREE=454×10-6 ~ 605×10-6）,重稀土元素亏损（HREE=39. 3×10-6 ~ 45. 6×10-6）,具有弱负铕异常;K、Rb、Ba、Th富集,Nb、Ta、P、Ti亏损,并且具有明显的Sr负异常。εHf（t）值<0,TDM1值为2038 ~ 2218 Ma,TDM2值为2250 ~ 2516 Ma,说明岩浆源区物质与富集地幔有关或受到过地壳物质的混染。因此,任家滩—荞麦山岩体是由地幔玄武质岩浆与地壳基底太华杂岩形成的中酸性花岗质岩浆混合后形成的熔体,经强烈的结晶分异作用形成的,其形成于陆内裂谷的构造环境,是华北克拉通南缘对哥伦比亚超大陆裂解事件的响应。  相似文献