The structure and dynamics of 2-dimensional fluids in swelling clays   总被引：3，自引：0，他引：3  

Neal T. Skipper  Peter A. Lock  James O. Titiloye  Jan Swenson  Zakaria A. Mirza  W. Spencer Howells  Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.  相似文献   

Mineral and fluid inclusions in zircon of UHP metamorphic rocks from the CCSD-main drill hole: A record of metamorphism and fluid activity   总被引：18，自引：0，他引：18  

Zeming Zhang  Kun Shen  Yilin Xiao  Jochen Hoefs  J.G. Liou 《Lithos》2006,92(3-4):378-398

The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H₂O–CO₂, H₂O- or CO₂-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H₂O- and/or CO₂-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.  相似文献   

The role of friction and secondary flaws on deflection and re-initiation of hydraulic fractures at orthogonal pre-existing fractures   总被引：1，自引：0，他引：1  

Xi Zhang  Robert G. Jeffrey 《Geophysical Journal International》2006,166(3):1454-1465

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Reply to comment by Y. Park and J.-H. Ree on 'Chemical remagnetization of the Upper Carboniferous-Lower Triassic Pyeongan Supergroup in the Jeongseon area, Korea: fluid migration through the Ogcheon Fold Belt'     

Yong-Hee Park  Seong-Jae Doh  Dongwoo Suk 《Geophysical Journal International》2006,167(1):20-23

In their comment, Park & Ree have raised several points against the interpretation by Park et al. , and argued that the remagnetization in the Jeongseon area was caused by the thermal effects of a Late Cretaceous pluton and/or associated short-range hydrothermal fluids, rather than by long-range fluids advocated by us.
We disagree with most points raised by Park & Ree and we make a case that these are invalid because of what we believe is incorrect geologic evidence. Hence, our model—that the fluids causing the chemical remagnetization might migrate through the fault system within the Ogcheon Fold Belt—is the most plausible scenario. We recognize that our model needs to be tested in a future study and we welcome new interpretations for or against our model based on reliable geologic or geophysical data.  相似文献   

粤北地区产铀岩体的铀矿化特征及其成矿机制探讨   总被引：7，自引：0，他引：7  

张敏  陈培荣  陈卫锋 《化工矿产地质》2006,28(1):9-14,26

粤北地区是中国花岗岩型铀矿最为重要的大型矿聚集区,其主要的产铀花岗岩体是诸广山岩体和贵东岩体,均为多期多阶段的复式岩体,主要以印支期和燕山期的花岗岩为主。粤北地区的铀矿床主要由诸广山的长江铀矿田、澜河铀矿田、鹿井铀矿田和贵东岩体的下庄铀矿田组成,根据铀的成矿特征可分为硅化带型、交点型和碱交代型。粤北地区的铀成矿流体主要来自于地幔,而不是以往认为的花岗岩浆期后热液,铀源主要是粤北产铀岩体的印支期花岗岩。因此在华南开展新一轮铀矿找矿时,跳出以往“沿带找矿”的老思路,聚焦于印支期岩浆作用与铀矿床的关系,并重点关注华南地区可能的地幔柱或热点区域。  相似文献   

PDC钻头在寺河煤矿瓦斯预抽放钻井中的应用   总被引：2，自引：1，他引：2  

吴小建  李新民 《中国煤田地质》2006,18(1):64-65,68

在寺河矿区一期瓦斯地面预抽放钻井施工中，使用传统的镶齿三牙轮钻头钻进，钻进速度低，仅为2.0m／h，且井斜不易控制、钻头寿命短、成本较高。通过对寺河煤矿地层特征的分析，在二期工程施工中，9#煤以上地层优选六翼内凹式PDC钻头钻进，采取一定技术措施并合理调整钻压、转速及泵量等钻进参数，钻速可达7．0m/h，井斜也得到有效控制，降低了钻井成本。  相似文献   

Decarbonation reaction of magnesite in subducting slabs at the lower mantle     

N. Takafuji  K. Fujino  T. Nagai  Y. Seto  D. Hamane 《Physics and Chemistry of Minerals》2006,33(10):651-654

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.  相似文献   

下庄铀矿田337矿床成矿流体稀土元素示踪     

张国玉  王正其  梁良 《华东地质学院学报》2006,29(1):27-31

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。  相似文献   

Experimental research on a new encapsulated heat-generating hydraulic fracturing fluid system     

吴金桥  张宁生  吴新民  刘晓娟 《中国地球化学学报》2006,25(2):162-166

1 IntroductionFracturing plays an important role in increasingthe production and injection and enhancing the final re-covery of oil and gas. At present, the use of ahydroxypropyl guar gum, borate-crosslinked, hydraulicfracturing fluid systemhas become ext…  相似文献   

非等截面桩超声波成孔质量检测     

韩亮 《物探与化探》2005,29(2):185-188

分析了非等截面超声波成孔质量检测的几个主要影响因素,给出了相应得改进措施。用工程实例说明超声波反射技术是一种保证非等截面桩成孔质量和成桩质量必不可少的检测方法。  相似文献