乙醇增强—电感耦合等离子体质谱法直接测定地质样品中碲   总被引：9，自引：3，他引：9       下载免费PDF全文

韩丽荣李冰  马新荣 《岩矿测试》2003,22(2):98-102

建立了HF—HN03密封酸溶以及Na2O2熔融处理样品，乙醇增强灵敏度，电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ＝4％)，在0．85L/min的载气流速下，碲信号可增强2．5倍以上。碲的方法检出限(100，DF＝1000)为0．02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度，标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲，结果与其他方法相符，精密度试验RSD(n＝3)＜10％。  相似文献   

宁南汤家坪地壳形变异常的调查研究     

程式  钱洪  杨永林  朱文庆 《四川地震》2003,(1):12-16

根据宁南汤家坪流动水准、基线测量出现的重大异常，进行了野外实地考察。发现点位是稳定的；A点与B、C点之间是跨断层的；但原始选点报告所提供的断层产状与作者实测的断层产状有一定的偏差。通过对相关资料分析，认为该场地的地壳形变异常是可靠的。并对其形成机理作了初步探讨。  相似文献   

GPS技术应用于中国地壳运动研究的方法及初步结果   总被引：10，自引：0，他引：10  

江在森  马宗晋  牛安福  张晓亮  王双绪  陈兵 《地学前缘》2003,10(1):71-79

文中主要就中国利用GPS等空间测地资料研究地壳运动、构造变形 ,以及用于地震预测探索方面 ,从方法技术和近年来取得的一些初步结果进行了概要性论述。介绍了利用GPS技术资料研究地壳水平运动速度场、水平应变场、建立地壳运动模型等方法研究的进展。由GPS观测给出的地壳水平运动初步结果表明 :中国大陆现时水平运动在全球参考系中为整体向东 ,并兼有顺时针扭转运动。西部地区构造形变强烈 ,整个青藏块体及其边界带 ,以及新疆西部是应变值最高的区域 ,水平应变场主压应变优势分布方向为近NE向 ,空间差异显著 ,反映了印度板块碰撞推挤和青藏块体强烈构造运动的影响。中国大陆东部水平运动的差异性不显著。强震分布于地壳运动的大小、方向显著变化的区域 ,大地震通常发生在水平剪应变高值区或其边缘 ,尤其是与区域主干断裂的构造活动背景相一致的剪应变率高值区。  相似文献   

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle     

Manuel Moreira  Jerzy Blusztajn  Joshua Curtice  Stan Hart  Henry Dick  Mark D. Kurz 《Earth and Planetary Science Letters》2003,216(4):635-643

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.  相似文献   

Petrology and Geochemistry of the Volcanic Rocks Dredged from the Geophysicist Seamount in the Kurile Basin: Evidence for the Existence of Thinned Continental Crust     

Igor A. Tararin  Eugeniy P. Lelikov  Reinhard Werner 《Gondwana Research》2003,6(4):757-765

Dredged samples from the Geophysicist seamount volcano in the northeastern part of the Kurile Basin include volcanic and volcanoclastic rocks ranging from basalt to andesite. The rocks have geochemical features typical of high-K island-arc calc-alkaline volcanism. They are enriched in LILE and depleted in Zr, Ti, Nb, Ta and Y. The chondrite-normalized REE patterns are characterized by enrichment of LREE similar to those of island-arc lava from the submarine volcanoes of rear-arc zone of the Kurile Island Arc. The volcanic rocks have a wide range of ⁸⁷Sr/⁸⁶Sr ratios (0.70287-0.70652), varying ¹⁴³Nd/¹⁴⁴Nd and Pb isotopic ratios. Their trace-element compositions and Sr-Nd-Pb isotope signatures may be explained by a small addition of crustal continental component to mantle-derived magmas that suggest the existence of thinned continental basement under the eastern part of the Kurile Basin.  相似文献   

Pn arrivals and lateral variations of Moho geometry beneath the Kaapvaal craton     

M. T. O. G. Kwadiba  C. Wright  E. M. Kgaswane  R. E. Simon  T. K. Nguuri   《Lithos》2003,71(2-4):393-411

Pn arrivals from mining-induced earthquakes on the edge of the Witwatersrand basin show that the P wavespeeds in the uppermost mantle are almost constant throughout most of the Kaapvaal craton. The presence of only small wavespeed variations allows the use of a simple method of estimating crustal thicknesses below the stations of the Kaapvaal broad-band network using Pn times that has been compared with results from receiver functions. One thousand three hundred thirty-seven Pn arrivals were used to derive crustal thicknesses at 46 stations on the Kaapvaal craton. The average crustal thicknesses for 19 centrally located stations on each of the northern and southern regions of the craton that yielded well-constrained thicknesses were 50.52±0.88 km and 38.07±0.85 km, respectively. In contrast, the corresponding average thicknesses determined from receiver functions were 43.58±0.57 km and 37.58±0.70 km, respectively. The systematically lower values for receiver functions in the northern part of the Kaapvaal craton that was affected by the Bushveld magmatism at 2.05 Ga, suggest that the receiver functions do not enable the petrological crust mantle boundary to be reliably resolved due to variations in composition and metamorphic grade in a mafic lower crust. The Pn times also suggest pervasive azimuthal anisotropy with maximum wavespeeds of about 8.40 km/s at azimuths of about 15° and 217° in the northern and southern regions of the craton, respectively, and minimum wavespeeds of about 8.25 km/s.  相似文献   

一个大洋环流模式和相应的海气耦合模式的评估 I.热带太平洋年平均状态     

张学洪  俞永强  宇如聪  刘海龙  周天军  李薇 《大气科学》2003,(6)

评估了中国科学院大气物理研究所大气科学和地球流体动力学数值模拟国家重点实验室海洋环流模式L30T63和海气耦合模式FGCM 0模拟的热带太平洋年平均状态 ,资料取自L30T63由观测的大气强迫驱动的Control试验、由NCARCCM3大气强迫驱动的Spinup试验、以及相应的海气耦合模式FGCM 0。主要的结论是 :( 1 )在“准确”的海表强迫下 ,Control模拟的海面温度和温跃层与观测结果相当接近 ,模式的固有误差是赤道冷舌过分西伸和东南太平洋温跃层偏浅。 ( 2 )Spinup能模拟出合理的热带太平洋上层海洋环流 ,但存在两个问题 ,即 :暖池区海面温度显著偏高、沿赤道的梯度过大 ;赤道温跃层偏浅、东西向坡度偏小 ,它们分别与CCM3提供的海表短波辐射通量和风应力的系统误差有关。这两个问题很可能是海气耦合模式FGCM 0运行初期误差迅速发展的重要原因。 ( 3)FGCM 0模拟的赤道暖池区上层 1 0 0m的平均温度比观测低 3℃。分析表明FGCM 0夸大了暖池区海洋动力过程的降温作用 ,使得模拟的“暖池”在一定程度上具有冷舌的属性。FGCM 0模拟的热带南太平洋温跃层比观测结果偏浅数十米到 1 0 0m ,以致赤道两侧的上层海洋温度分布趋于对称 ,成为“doubleITCZ”现象在上层海洋中的表现。风应力旋度的系统误差和垂直混合随深度衰减过快  相似文献   

洋脊和年轻洋壳俯冲与埃达克岩生成的热模拟          下载免费PDF全文

张健  石耀霖  吴春明 《地震地质》2003,25(4):617-624

新生代以来 ,环太平洋周边分布的埃达克岩 (Adakite)主要与年轻洋壳俯冲时在 70～ 90km深处的部分熔融有关。利用数值方法 ,模拟了洋壳俯冲的热演化过程并讨论了脱水、熔融对埃达克岩浆活动的影响。结果表明 :仅在活动海岭俯冲前后约 10Ma内 ,年轻的、热的俯冲海洋板片在 75～85km深度范围内 ,温度升高至 82 5～ 10 0 0℃脱水 ,导致年轻洋壳中角闪岩部分熔融 ,形成埃达克岩(Adakite)。而一般洋壳俯冲在 10 0km以下深度才脱水 ,由于脱水区压力较高洋壳自身不能熔融 ,水进入上覆地幔楔状体导致部分熔融 ,形成安山岩 (Andesite  相似文献   

长白山天池火山区上地壳三维速度层析成像   总被引：6，自引：4，他引：6       下载免费PDF全文

赵金仁  张先康  杨卓欣  张成科  王夫运  张建狮  刘宝峰  段玉玲  王帅军 《地球物理学报》2003,46(6):796-802

利用三维地震透射观测系统所获得的莫霍界面反射波对长白山天池火山区下方上地壳的三维速度细结构进行了反演计算，得到了研究区下方地壳内不同深度的P、S波速度层析成像和VP/VS扰动分布图像，结果表明，天池火山区及其周边速度结构所呈现出的非均匀性变化与该区的地质构造和岩浆系统的存在有着密切的关系，异常变化比较明显的低P波速度异常体分布和高VP/VS扰动体意味这些介质体处在“软化高温”的状态，这与该地区广泛分布的地热异常和低Q值结构的研究结果是一致的.  相似文献   

Wide-angle seismic velocities in heterogeneous crust   总被引：5，自引：0，他引：5  

John Brittan  Mike Warner 《Geophysical Journal International》1997,129(2):269-280

Seismic velocities measured by wide-angle surveys are commonly used to constrain material composition in the deep crust. Therefore, it is important to understand how these velocities are affected by the presence of multiscale heterogeneities. The effects may be characterised by the scale of the heterogeneity relative to the dominant seismic wavelength (λ); what is clear is that heterogeneities of all scales and strengths bias wide-angle velocities to some degree. Waveform modelling was used to investigate the apparent wide-angle P -wave velocities of different heterogeneous lower crusts. A constant composition (50 per cent felsic and 50 per cent ultramafic) was formed into a variety of 1- and 2-D heterogeneous arrangements and the resulting wide-angle seismic velocity was estimated. Elastic, 1-D models produced the largest velocity shift relative to the true average velocity of the medium (which is the velocity of an isotropic mixture of the two components). Thick (width > λ) horizontal layers, as a result of Fermat's Principle, provided the largest increase in velocity; thin (width ≪λ) vertical layers produced the largest decrease in velocity. Acoustic 2-D algorithms were shown to be inadequate for modelling the kinematics of waves in bodies with multiscale heterogeneities. Elastic, 2-D modelling found velocity shifts (both positive and negative) that were of a smaller magnitude than those produced by 1-D models. The key to the magnitude of the velocity shift appears to be the connectivity of the fast (and/or slow) components. Thus, the models with the highest apparent levels of connectivity between the fast phases, the 1-D layers, produced the highest-magnitude velocity shifts. To understand the relationship between measured seismic velocities and petrology in the deep crust it is clear that high-resolution structural information (which describes such connectivity) must be included in any modelling.  相似文献