水中矿物油荧光特性实验研究     

夏达英  张士魁  李宝华  王振先  孙培光  史锦珊  尚丽平 《海洋科学进展》2002,20(2):91-98

为了实现现场测量地表水中矿物油含量的全光纤荧光计的研制。采用荧光光谱测量分析方法 ,于 1 999年 1 0月— 2 0 0 0年 5月 ,采集了国内外不同的地区原油和成品油共 2 3种 ,用1 4种不同波长的激发光激励 ,进行荧光光谱特性测量实验研究。同时 ,对不同浓度的矿物油、水混合液也进行了测量实验 ,得出其最低检测浓度为 0 .0 0 5mg/L ;测量了青岛近岸海域表层受油污染海水的含油量为 0 .0 1～ 0 .2 2mg/L ;此外对水中矿物油受激荧光发射原理也作了简述。并对水中矿物油荧光光谱特性、浓度与荧光强度的关系 ,以及为研制现场测量水中矿物油浓度的全光纤荧光计的可能性作出了结论性的意见  相似文献   

高精度CTD剖面仪研制过程中的专用设备   总被引：1，自引：1，他引：1  

王欣 《海洋技术学报》2001,20(1):140-142

本文介绍了“油水分离压力罐”的主要理论依据及该设备采用的特殊的机械结构，实践证明，利用该设备实现了在实验室条件下，模拟深海重力场检测CTD剖面仪中的某些关键传感器的目的。  相似文献   

Bottom Simulating Reflector and Gas Seepage in Okinawa Trough： Evidence of Gas Hydrate in an Active Back-Arc Basin     

栾锡武  Kelin  Wang  Roy  Hyndman  Eleanor  Willoughby 《中国地质大学学报(英文版)》2008,19(2):152-161

To look for gas hydrate, 22 multi-channel and 3 single-channel seismic lines on the East China Sea (ECS) shelf slope and at the bottom of the Okinawa Trough were examined. It was found that there was indeed bottom simulating reflector (BSR) occurrence, but it is very rare. Besides several BSRs, a gas seepage was also found. As shown by the data, both the BSR and gas seepage are all related with local geological structures, such as mud diapir, anticline, and fault-controlled graben-like structure. However, similar structural "anomalies" are quite common in the tectonically very active Okinawa Trough region, but very few of them have developed BSR or gas seepage. The article points out that the main reason is probably the low concentration of organic carbon of the sediment in this area. It was speculated that the rare occurrence of gas hydrates in this region is governed by structure-controlled fluid flow. Numerous faults and fractures form a network of high-permeability channels in the sediment and highly fractured igneous basement to allow fluid circulation and ventilation. Fluid flow in this tectonic environment is driven primarily by thermal buoyancy and takes place on a wide range of spatial scales. The fluid flow may play two roles to facilitate hydrate formation:to help gather enough methane into a small area and to modulate the thermal regime.  相似文献   

Main Controlling Factors on Hydrocarbon Accumulation and Distribution in Marine Sedimentary Sequences in South China     

蔡立国  周雁  白振瑞 《中国地质大学学报(英文版)》2008,19(6):645-655

Multiple source rock assemblages were deposited in the sedimentary provinces in South China in geologic history,and some of them were destructed by and some survived against multiple tectonic movements.Therefore,multiple sources,mixed sources,and uneven distribution of sources occurred in the marine sedimentary basins in South China during the late stage of hydrocarbon pooling.Epidiagenesis of the marine carbonate reservoirs and its modification to reservoir poroperm characteristics determined the formation and the scale of natural gas pools.The exploration practices show that the large to medium gas fields mainly occur in areas with high-quality reservoirs.Detailed study of the paleo-oil accumulations and typical oil and gas reservoirs reveals that the basins experienced multiphase superimposition and modification,leading to the distribution of the Paleozoic paleo-oil accumulations and bitumen in the peripheral areas.The phenomenon that oil and gas production concentrates in the Sichuan basin indicates that the overall sealing conditions of a basin determine the oil/gas potentials and the scale of oil and gas production.This is a critical factor controlling the accumulation and distribution of gas in the marine sequences in South China.The early oil and gas pools in the Yangtze platform left billions of bitumen in the peripheral areas due to the destruction of seals.Since the Himalayan,"late-generation and late-accumulation" gas pools represented by the gas pools in the Sichuan (四川) basin were formed in the marine sedimentary sequences in South China as a result of the change of the sealing conditions.Current gas discoveries appear to be "paleo-generation and paleo-accumulation" gas pools but actually are "late-generation and late-accumulation" gas pools.These patterns of hydrocarbon pooling clearly depict themselves in western Sichuan basin and Weiyuan (威远)gas field.It is revealed that the gas pools in the Sichuan basin were mainly formed as a result of hydrocarbon phase change (thermal cracking of oil to gas),miscible migration,and dynamic equilibration since the Himalayan.A large number of gas pools were formed in the Himalayan and the gas pools in the marine sequences are characterized by late pooling; this kind of gas fields/pools are controlled by:(1) effectiveness of modification and superimposition of the marine basins,(2) effectiveness of the source rocks,(3) effectiveness of the overall preservation conditions,and (4) effectiveness of plays.  相似文献   

Formation Models and Distribution of Oil and Gas Pools in Tarim Basin,China     

龙胜祥 《中国地质大学学报(英文版)》2008,19(6):665-674

This article reports the main formation models and distribution of the oil and gas pools in Tarim basin,China,including (I) occurrence of the found oil and gas pools,(2) main formation models of oil and gas pools,and (3) distribution law of oil/gas pools.Petroleum is distributed widely in the strata of Tarim basin from the Sinian at the bottom to the Neogene at the top.However,the found oil and gas fields are mainly distributed in Shaya (沙雅) uplift,Tazhong (塔中) uplift,and Kuche (库车)depression.This article presents 4 main formation models,namely,early formation and long-term preservation,early formation and late reformation,middle-late multiphase-multisource formation,late single-stage formation.Tarim basin is very rich in petroleum resources.Long-term inherited intrabasinal paleohighs and slope zones are the most favorable areas for accumulation of hydrocarbons,but the types of oil and gas pools are different from area to area.The control of unconformities and faults on hydrocarbon accumulating is prominent in Tarim basin.Preservation conditions are of utmost importance.Formation of some oil and gas pools is the result of reforming and re-accumulating of early accumulated hydrocarbons.  相似文献   

关注苏皖南部地区海相油气资源          下载免费PDF全文

范小林 《江苏地质》2008,32(1):16-18

据苏皖南部地区地表露头及部分井下所发现的海相油气显示表明,这里存在海相油气资源勘探远景,关注这一地区的海相油气资源,如何开展和寻找这类油气资源,将有利于该地区区域性经济建设的可持续发展。  相似文献   

岩石圈深部温压条件下萜烷演化的实验研究     

王传远  杜建国  段毅  周晓成  陈志 《矿物岩石》2008,28(2):76-80

在密闭体系中700℃、压力高达3 GPa条件下进行褐煤加水的模拟实验,分析实验产物中的萜烷的变化规律,进而对高压高温下有机质演化进行研究.实验结果表明,相同压力条件下,温度升高有利于有机质的成熟演化;压力增加会抑制或延迟油气的生成和有机质成熟;五环三萜烷ββ生物构型转化为αβ地质构型所需能量比烯烃双键加氢饱和更高.高温超高压条件下,研究样品中C24四环萜烷存在4种同分异构体,含量由高到低依次包括10β(H)-降A-羽扇烷、10p(H)-降A-奥利烷、C24-17,21-断藿烷和10β(H)-降A-乌散烷.高碳数烷烃在地幔高压力条件下仍可以存在,这为认识超压盆地的油气资源与深层油气成藏及保存提供了新的思路.  相似文献   

IODP 311航次底栖有孔虫碳稳定同位素对天然气水合物地质系统的指示     

李清  王家生  王晓芹  陈祈  陈洪仁 《地球科学进展》2008,23(11):1161-1166

为了探索海洋天然气水合物背景下有孔虫特征的响应,对综合大洋钻探计划(IODP) 311航次岩芯沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana进行了初步研究。通过对冷泉站位U1328和毗邻的非冷泉站位U1327沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana的显微形貌特征和碳、氧稳定同位素测试等,证实有孔虫壳体未受到后期成岩作用的改造和自生碳酸盐岩的交代影响,有孔虫壳体的碳稳定同位素呈现明显的负偏。其中U1327站位中U.peregrina δ¹³C为-0.67‰～-2.75‰（PDB）,B.mexicana δ¹³C为-0.51‰～-1.52‰（PDB）;U1328站位中U.peregrina δ¹³C为 -0.72‰～-2.71‰（PDB）,B.mexicanaδ¹³C为 -0.58‰～-1.45‰（PDB）。底栖有孔虫壳体的碳稳定同位素负偏成因可能与水合物不稳定分解释放的甲烷厌氧氧化作用和食物源有关,因而可较好地指示海底天然气水合物系统地质背景。  相似文献   

吐哈盆地丘东凝析气藏中侏罗统储层流动单元划分     

解伟  马广明  孙卫 《现代地质》2008,22(1):81-85

对吐哈盆地丘东凝析气藏中侏罗统储层的流动单元的划分方法和参数选取进行探讨。针对丘东凝析低渗透气藏的储层和流体特点,纵向上对研究区中侏罗统地层进行小层精细划分,平面上应用SPSS统计分析软件对厚度、孔隙度、泥质含量、流动带指数等4个参数进行聚类分析和判别分析,将研究区中侏罗统储层砂体划分为4类流动单元。结果表明各流动单元的类型与储层物性、沉积微相具有很好的对应关系,能够客观地反映气藏储层的地质特征。虽然丘东凝析低渗透气藏中流动单元的划分和油藏中流动单元的划分没有太大差别,但是参数的选取却与油藏中的存在着明显的不同。  相似文献   

渤海湾盆地南堡凹陷原油成因类型及其分布规律   总被引：8，自引：3，他引：5  

李素梅  姜振学  董月霞  王旭东 《现代地质》2008,22(5)

南堡凹陷近年油气勘探取得了重大突破,为揭示该区滩海与陆地油气成因及分布规律,对67个原油和油砂样品进行了详细的地球化学研究。南堡凹陷原油具有低硫、中高蜡含量特征,陆相成因特点显著。共分为4种类型原油:(1)陆地沙三段深部层系原油,具有高4-甲基甾烷丰度、低奥利烷丰度与低甲基菲指数值和轻微偏高成熟度特征;(2)陆地Es1—Ed原油与Ng和Nm原油,其特征与第一类原油相反;上第三系原油普遍遭遇生物降解;(3)滩海东营组原油,以较高伽马蜡烷/C30藿烷和高甾烷/藿烷值区别于陆地原油;(4)滩海奥陶系潜山原油,具有低丰度甾萜类生物标志物、相对高丰度孕甾烷、三环萜烷与重排甾烷系列等特征,显示较高成熟度。上述4种成因类型原油指示南堡凹陷陆地、滩海均存在多层导有利烃源岩;同层位中滩海Es1-Ed存在较陆地更为优越的有利烃源岩,南堡滩海地区具有广泛的油气勘探前景。  相似文献