Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   

Double–double radio galaxies: remnants of merged supermassive binary black holes     

F. K. Liu  Xue-Bing Wu  S. L. Cao 《Monthly notices of the Royal Astronomical Society》2003,340(2):411-416

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Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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Spatial measurements of stream baseflow,a relevant method for aquifer characterization and permeability evaluation. Application to a hard‐rock aquifer,the Oman ophiolite     

B. Dewandel  P. Lachassagne  A. Qatan 《水文研究》2004,18(17):3391-3400

The structure, functioning and hydrodynamic properties of aquifers can be determined from an analysis of the spatial variability of baseflow in the streams with which they are associated. Such analyses are based on simple low‐cost measurements. Through interpreting the hydrological profiles (Q = f(A)) it is possible to locate the aquifer(s) linked to the stream network and to determine the type of interrelated flow, i.e. whether the stream drains or feeds the aquifer. Using an analytical solution developed for situations with a positive linear relationship, i.e. where the baseflow increases linearly with increasing catchment size, it is also possible to estimate the permeability of the aquifer(s) concerned at catchment scale. Applied to the hard‐rock aquifers of the Oman ophiolite, this method shows that the ‘gabbro’ aquifer is more permeable than the ‘peridotite’ aquifer. As a consequence the streams drain the peridotites and ‘leak’ into the gabbro. The hydrological profiles within the peridotite are linear and positive, and indicate homogeneity in the hydrodynamic properties of these formations at the kilometre scale. The permeability of the peridotite is estimated at 5 · 10^?7 to 5 · 10^?8 m/s. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Revised masses of dust and gas of SCUBA Local Universe Survey far-infrared bright galaxies based on a recent CO survey     

Ernest Seaquist  Lihong Yao  Loretta Dunne  Heather Cameron 《Monthly notices of the Royal Astronomical Society》2004,349(4):1428-1434

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莱州湾南岸潍河下游地区咸水入侵灾害成因及特征   总被引：8，自引：1，他引：7  

刘恩峰  张祖陆  沈吉  宋俊峰 《地球科学与环境学报》2004,26(3):78-82,87

通过对莱州湾南岸咸水入侵较严重地潍河下游地区晚更新世以来沉积特征及现代自然环境条件变化的分析，探讨了沉积相对咸水入侵产生及空间范围特征的环境机理。晚更新世以来的三次海平面升降变化造成了潍河下游地区海陆沉积环境交替，形成了巨厚的海陆交互相沉积层。海进时期，大面积的滨海平原被淹没，在近海平原洼地滞留的海水经过蒸发、浓缩变为卤水，成为咸水入侵的物源；海退后陆源碎屑在滨海地区沉积形成了巨厚的古河道砂层。20世纪70年代末期以来，随着对地下淡水的过度开采，淡咸水水头压力差减小．卤水通过古河道砂层快速南侵。通过对潍河下游地区100余个地质钻孔水化学连续监测资料分析，阐明了咸水入侵的特征，有针对性地提出了咸水入侵的防治措施。  相似文献   

用C#.Net实现软件系统的动态更新     

刘才铭  李旭伟  朱宏  张雁 《成都信息工程学院学报》2005,20(3):313-318

为了便于大型软件系统的后续开发和用户软件系统的升级，介绍了软件系统在Internet/Intranet上更新功能或数据的原理和方法，并用C#．Net进行了编程实现。  相似文献   

双酶法制备低黏度辛烯基琥珀酸淀粉钠的工艺条件   总被引：4，自引：0，他引：4  

阳元娥  罗发兴  黄强  谭伟 《广东海洋大学学报》2004,24(4):49-53

对双酶法制备用作微胶囊壁材的低黏度辛烯基琥珀酸淀粉钠的工艺路线与工艺条件进行了研究。正交实验结果表明 ,在酯化淀粉乳质量浓度 2 0 %、每 g淀粉α 淀粉酶的用量为 6SKBU的条件下 ,影响产品性能的各因素中 ,糖化酶的用量对产品的DE值和流度的影响最大 ,各因素的重要性依次是 :糖化酶的用量、糖化酶作用时间、α 淀粉酶保温作用时间。最佳工艺条件是 :α 淀粉酶保温作用时间 4min ,每 g淀粉糖化酶用量 0 .2GAU ,糖化酶作用时间 2 .5h ,此时产品的DE值为 30 ,流度为 80左右  相似文献   

隧道工程地质评价的内容和方法   总被引：2，自引：0，他引：2  

陈新建  孙琳  李新星  孙巧银 《地球科学与环境学报》2004,26(1):41-45

结合工程隧道实际,首先阐述了隧道工程的基本地质环境和工程地质条件,然后针对隧道工程可能出现的不良地质现象和可采取的工程措施,从大气降水、围岩稳定、围岩压力、洞口稳定、隧道比选等角度探讨隧道工程地质评价的主要方法和一般内容,进行隧道工程地质评价,为隧道施工、支护提供了依据.  相似文献