钾长石分解反应热力学与过程评价   总被引：2，自引：2，他引：2  

马鸿文  苏双青  王芳  徐锦明  谭丹君  刘浩 《现代地质》2007,21(2):426-434

综述了添加各种助剂分解钾长石的研究进展。对不同体系中钾长石分解反应的G ibbs自由能和能耗计算,综合考虑一次性资源、能源消耗量和烧结过程的环境相容性、产品方案等因素,结果表明:只有以石灰石、碳酸钠为配料的工艺路线具有实际工业应用价值;而唯有以碳酸钠为配料时,钾长石原料烧结过程才具有一次性资源消耗量最少、能耗最低、温室气体CO2排放量最小、且可生产高附加值产品、实现完全清洁生产等优点。因此,选择以碳酸钠为配料分解钾长石的技术路线,具有良好的工业化应用前景。  相似文献   

青藏高原西北缘高原面与陡坡地貌形成过程的裂变径迹热年代学约束   总被引：9，自引：1，他引：9  

黎敦朋 赵越胡健民  万景林李新林周小康  杜少喜潘燕兵 裴军令 《岩石学报》2007,23(5):900-910

对青藏高原西北缘高原内部和陡坡地貌带2个花岗岩体10件磷灰石裂变径迹年龄测定表明,高原内部大红柳滩—郭扎错逆冲断裂上盘磷灰石裂变径迹年龄为24.8±4.9～14.0±1.3Ma,此外,一个玄武岩烘烤的热事件年龄为7.9±0.8Ma;而陡坡地貌带的西昆仑中间逆冲断裂上盘的磷灰石裂变径迹年龄为2.9±0.5～0.9±0.3Ma。进一步的热历史模拟结果显示,高原内部自渐新世以来经历了2期隆升-剥露,分别是渐新世—早中新世(30～16Ma)和上新世以来(≤5Ma),而陡坡带只记录了晚中新世以来(≤8Ma)的隆升-剥露,暗示他们经历了不同的热演化历史。结合前人在该区的磷灰石裂变径迹年龄数据和野外地质现象,认为现今高原边缘陡坡地貌带可能是自晚中新世以来(≤8Ma)高原边界断裂伴有向塔里木盆地后展式叠瓦逆冲产生的构造抬升的结果;现今高原面有可能是由高原边界断裂系于大约5～2Ma以来强烈活动逐渐形成的,其隆升-剥蚀幅度>2000～3000m。这对自晚中新世以来青藏高原西北缘高原面与陡坡地貌形成过程提供了磷灰石裂变径迹热年代的重要约束。  相似文献   

Mineral Components, Texture, and Forming Conditions of Hydrothermal Chimney on the East Pacific Rise at 9°-10°N   总被引：1，自引：0，他引：1  

郑建斌  曹志敏安伟 《中国地质大学学报(英文版)》2007,18(2):28-134

To characterize the hydrothermal processes of East Pacific rise at 9°-10°N, sulfide mineral compositions, textural, and geochemical features of chimney ores were studied using ore microscope,scanning electron microscope, X-ray diffraction analysis, and electron microprobe techniques. Results show that there are three mineral assemblages for the hydrothermal chimney ores, namely：（i） anhydrite ＋ marcasite ＋ pyrite, （ii） pyrite ＋ sphalerite ＋ chalcopyrite, and （iii） chalcopyrite ＋ bornite ＋ digenite ＋ covellite. Mineral assemblages, zonational features, and geochemical characteristics of the ore minerals indicate that ore fluid temperature changed from low to high then to low with a maximum temperature up to 400 ℃. The chimney is a typical black smoker. The initial structure of the chimney was formed by the precipitation of anhydrites, and later the sulfides began to precipitate in the inner wall.  相似文献   

青海东昆仑成矿带综合选区研究          下载免费PDF全文

丁清峰孙丰月  李钟山 《中国地质》2007,34(6):1101-1108

笔者通过改进先前提出的基于专家证据权重法的成矿远景区划与评价方法的不足之处,重新对青海东昆仑地区Au、Cu和Co3矿种进行成矿远景区划与评价,将各矿种的远景区按成矿潜力大小划分为A、B、C三级。在此基础上,提出了将多个单矿种远景区合成综合成矿远景区的评价方法和手段,最终圈定出青海东昆仑的综合远景区25个,并对它们也按成矿潜力大小划分为A、B、C三级。从青海东昆仑地区已知Au、Cu、Co矿床(点)在各综合远景区内的数量和规模分布情况来看,结果令人满意。青海东昆仑地区的综合选区研究成果可望为该区进一步找矿工作部署提供部分科学依据。  相似文献   

中国云南易门式铜矿床的主要类型及成因   总被引：2，自引：0，他引：2  

韩润生  邹海俊  刘丛强  马更生 《地质通报》2007,26(12):1549-1563

系统地概括了易门铜矿田的成矿地质背景及2种矿床类型的地质特征,在此基础上论证了火山热水沉积作用、构造改造作用、岩浆叠加作用、地下热水再造作用与成矿密切相关。易门式铜矿床为"裂谷成矿背景-火山热水沉积-构造改造富集-深源岩浆叠加-地下热水再造"型多因复成矿床,建立了新的成矿模式,为该类矿床深部及外围的找矿预测指明了方向。  相似文献   

地球化学块体与大型矿集区的关系——以东天山为例   总被引：11，自引：5，他引：11  

王学求  申伍军  张必敏  聂兰仕  迟清华  徐善法 《地学前缘》2007,14(5)

通过在东天山15万km2的战略性深穿透地球化学调查共圈出大于1000km2以上的地球化学块体18处,其中铜-铅-锌-银地球化学块体5处,铜地球化学块体3处,铜-镍地球化学块体1处,金的地球化学块体4处,铀的地球化学块体3处,铂-钯地球化学块体1处,钨地球化学块体1处。有6处地球化学块体与已知矿集区相对应,新圈定的地球化学块体12处,其中有3处发现了新的矿床。根据这些块体与矿集区的对比得出如下结论:所有的已知矿集区都位于地球化学块体的范围之内,地球化学块体为矿集区的形成提供了丰富的物质基础;有矿集区的存在一定有地球化学块体的存在,但反过来有地球化学块体的存在不一定有矿集区的存在,地球化学块体是客观存在的,而矿集区是已经发现了一系列矿床并勘探到一定程度才能称作矿集区,因此,地球化学块体内可能会存在潜在的矿集区,这为利用地球化学块体预测新的矿集区提供了依据。  相似文献   

Genesis of the Changba–Lijiagou Giant Pb-Zn Deposit, West Qinling, Central China: Constraints from S-Pb-C-O isotopes     

WEI Ran  WANG Yitian  MAO Jingwen  HU Qiaoqing  QIN Siting  LIU Shengyou  YE Dejin  YUAN Qunhu  DOU Ping 《《地质学报》英文版》2020,94(4):884-900

The extensive Changba-Lijiagou Pb-Zn deposit is located in the north of the Xihe–Chengxian ore cluster in West Qinling. The ore bodies are mainly hosted in the marble, dolomitic marble and biotite-calcite-quartz schist of the Middle Devonian Anjiacha Formation, and are structurally controlled by the fault and anticline. The ore-forming process can be divided into three main stages, based on field geological features and mineral assemblages. The mineral assemblages of hydrothermal stage I are pale-yellow coarse grain, low Fe sphalerite, pyrite with pits, barite and biotite. The mineral assemblages of hydrothermal stage II are black-brown cryptocrystalline, high Fe shalerite, pyrite without pits, marcasite or arsenopyrite replace the pyrite with pits, K-feldspar. The features of hydrothermal stage III are calcite-quartz-sulfide vein cutting the laminated, banded ore body. Forty-two sulfur isotope analyses, twenty-five lead isotope analyses and nineteen carbon and oxygen isotope analyses were determined on sphalerite, pyrite, galena and calcite. The δ34 S values of stage I(20.3 to 29.0‰) are consistent with the δ34 S of sulfate(barite) in the stratum. Combined with geological feature, inclusion characteristics and EPMA data, we propose that TSR has played a key role in the formation of the sulfides in stage I. The δ34 S values of stage II sphalerite and pyrite(15.1 to 23.0‰) are between sulfides in the host rock, magmatic sulfur and the sulfate(barite) in the stratum. This result suggests that multiple S reservoirs were the sources for S2-in stage II. The δ34 S values of stage III(13.1 to 22‰) combined with the structure of the geological and mineral features suggest a magmatic hydrothermal origin of the mineralization. The lead isotope compositions of the sulfides have 206 Pb/204 Pb ranging from 17.9480 to 17.9782, 207 Pb/204 Pb ranging from 15.611 to 15.622, and 208 Pb/204 Pb ranging from 38.1368 to 38.1691 in the three ore-forming stages. The narrow and symmetric distributions of the lead isotope values reflect homogenization of granite and mantle sources before the Pb-Zn mineralization. The δ13 CPDB and δ18 OSMOW values of stage I range from-0.1 to 2.4‰ and from 18.8 to 21.7‰. The values and inclusion data indicate that the source of fluids in stage I was the dissolution of marine carbonate. The δ13 CPDB and δ18 OSMOW values of stage II range from-4 to 1‰ and from 12.3 to 20.3‰, suggesting multiple C-O reservoirs in the Changba deposit and the addition of mantle-source fluid to the system. The values in stage III are-3.1‰ and 19.7‰, respectively. We infer that the process of mineralization involved evaporitic salt and sedimentary organic-bearing units interacting through thermochemical sulfate reduction through the isotopic, mineralogy and inclusion evidences. Subsequently, the geology feature, mineral assemblages, EPMA data and isotopic values support the conclusion that the ore-forming hydrothermal fluids were mixed with magmatic hydrothermal fluids and forming the massive dark sphalerite, then yielding the calcite-quartz-sulfide vein ore type at the last stage. The genesis of this ore deposit was epigenetic rather than the previously-proposed sedimentary-exhalative(SEDEX) type.  相似文献   

克拉通盆地构造转折区中-新生界构造特征及其控藏意义——以鄂尔多斯盆地西南部镇泾地区延长组为例     

张园园  任战利  何发岐  崔军平  杨桂林  王琨  吉园园 《岩石学报》2020,36(11):3537-3549

基于三维地震、测井、岩矿测试等资料，分析了镇泾地区中生界断裂体系特征与成因，结合源岩热演化与储层物性反演结果，恢复了长8段油气成藏的动态演化过程，探讨了中生代以来构造活动对长8段油气成藏的影响作用。研究认为鄂尔多斯盆地内部镇泾构造转折区构造变形受盆地边缘影响明显，发育复杂断裂体系，构造特征及演化对油气藏的形成与分布有重要控制作用。结果表明：（1）中生界北西向、北东东向、近东西向3组断裂发育，平面上呈雁列式带状展布，剖面上为高陡产状且小断距错动。印支期北西向主断裂走滑明显，中、晚燕山期北东向断裂活动加强，喜山期北东东向次级断裂密度增大，并派生大量剪切裂隙。（2）长8段油藏经历了晚三叠世储集层、烃源岩层初始沉积形成，早白垩世初期少量低熟油近源充注形成岩性油藏，早白垩世末成熟油快速输导形成受断层及裂缝控制的构造-岩性油气藏，晚白垩世以来早期油藏调整等4个阶段。（3）印支运动控制了烃源岩及储层展布范围，I类北西向走滑断裂控制了镇泾地区中生界构造格局；中、晚燕山运动加速烃源岩热演化进程，并改善储层物性，II类断裂活动，为烃类输导提供垂向通道；喜山运动使先存中生界断裂活动，控制油气调整范围及油藏差异富集；其中北东东向II类张性或张扭性断裂导流性能好，是最为有效的富油断层。  相似文献   

Heterogeneous mantle melting and magmatic processes at the East Pacific Rise (2.6–3.1°S): Evidence from mid-ocean ridge basalt geochemistry and Sr–Nd–Pb isotopes     

Wei Li  Jin Liang  Shili Liao  Weifang Yang 《International Geology Review》2020,62(11):1387-1405

ABSTRACT

We present the major and trace elements and Sr, Nd, and Pb isotopes in mid-ocean ridge basalts (MORB) from the East Pacific Rise (EPR) at 2.6–3.1°S. These samples are low-K tholeiites and show significant variation in their major element compositions (e.g. 4.60–8.18 wt% MgO, 8.34–12.12 wt% CaO, 9.78–14.25 wt% Fe₂O₃, and 0.06–0.34 K₂O wt%). Trace element abundances of the 2.6–3.1°S MORB are variably depleted (e.g. (La/Sm), _N = 0.51–0.78, Zr/Y = 2.35–3.42, Th/La = 0.035–0.056, and Ce/Yb = 2.38–3.96) but closely resemble the average N-MORB. In the compatible elements (Ni and Cr) against incompatible element Zr plots, the 2.6–3.1°S MORB show well-defined negative correlations, together with a liquid line of descent (LLD) modelling and petrographic observations, implying a significant role of olivine, plagioclase and clinopyroxene fractionation during magma evolution. When compared to global MORB and peridotites, the 2.6–3.1°S MORB and most of the other axial lavas from the South EPR show similar Zn/Fe, Zn/Mn, and Fe/Mn ratios, attesting to a peridotite-dominated mantle lithology. However, the relationships between incompatible trace element ratios, such as Zr/Rb and Nb/Sm, and the negative correlation between Zr/Nb and ⁸⁷Sr/⁸⁶Sr indicate a geochemically heterogeneous mantle source. The mantle beneath the South EPR likely consists of two components, with the enriched component residing as physically distinct domains (e.g. veins or dikes) in the depleted peridotite matrix. In the Sr–Nd–Pb isotope space, the South EPR MORB lie along the mixing lines between the depleted MORB mantle (DMM) and the ‘C’-like Pukapuka endmember. We infer that low-F melts derived from these enriched materials may cause localized mantle heterogeneity (veins or dikes) via an infiltration process. Subsequent melting of the refertilized mantle may impart an isotopically distinct characteristic to South EPR MORB.  相似文献   

辽宁东平金矿床地质特征及找矿方向     

王林世  彭虎  郭亚波  郭晓丹 《地质与资源》2020,29(3):246-251

东平金矿位于辽西凌源-阜新金成矿带上，金矿（化）体主要赋存在硅化构造角砾岩、硅化流纹岩和硅化流纹质角砾熔岩中.矿石以自然金和银金矿为主，其中自然金约占80%，银金矿约占20%.激电中梯及钻探结果显示矿体主要受北北西向构造控制，金矿（化）体主要位于高阻低极化率的F2构造蚀变带内.土壤地球化学测量圈定综合异常22处，Ⅰ-4异常区经钻探验证发现多个隐伏金矿（化）体.在详细研究矿床地质特征的基础上，通过对比邻区赵家沟金矿，初步推断其成因类型为低温热液型金矿.同时认为区内北北西向构造蚀变带内具有的黄铁矿化、强硅化和碳酸盐化是主要的矿化蚀变信息，高阻低极化率及Au土壤地球化学综合异常带是重要的找矿方向.  相似文献