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21.
Plagioclase ultraphyric basalts (PUBs) with up to 54% plagioclasephenocrysts were dredged in the rift valley and adjacent flanksof the ultraslow-spreading Mohns and Knipovich ridges. The PUBsshow large variations in crystal morphologies and zoning. Thelarge variations suggest that single basalt samples containa mixture of plagioclase crystals that aggregated at differentlevels in the magma conduits. Resorbed crystals and repeatedreverse zones suggest that the magma reservoirs were replenishedand heated several times. Thin concentric zones with melt inclusions,and sharp reductions in the anorthite content of 3–7%,are common between the reverse zones. These zones, and skeletalcrystals with distinctly lower anorthite contents than massivecrystals, are interpreted to be the result of rapid crystalliztionduring strong undercooling. The changes between short periodsof cooling and longer periods with reheating are explained bymultiple advances of crystal-rich magma into cool regions followedby longer periods of gradual magma inflow and temperature increase.The porphyritic basalts are characterizd by more depleted andmore fractionated compositions than the aphyric basalts, withlower (La/Sm)N, K2O and Mg-numbers. This relationship, and theobservation that PUBs are sampled only close to segment centresalong these ridges, suggests that the PUBs formed by higherdegrees of melting and evolved in more long-lived magma reservoirs.We propose that the zoning patterns of plagioclase crystalsand crystal morphologies of these PUBs reflect the developmentand flow of magma through a stacked sill complex-like conduitsystem, whereas the aphyric equivalents represent later flowof magma through the conduit. The formation of voluminous higher-degreemelts may trigger the development of the magma conduits andexplain the generally depleted compositions of PUB magmas. KEY WORDS: basalt; mineral chemistry; MORB; magma mixing; magma chamber; major element  相似文献   
22.
Economic concentrations of Fe–Ti oxides occur as massive,conformable lenses or layers in the lower part of the Panzhihuaintrusion, Emeishan Large Igneous Province, SW China. Mineralchemistry, textures and QUILF equilibria indicate that oxidesin rocks of the intrusion were subjected to extensive subsolidusre-equilibration and exsolution. The primary oxide, reconstructedfrom compositions of titanomagnetite in the ores and associatedintergrowths, is an aluminous titanomagnetite (Usp40) with 40wt % FeO, 34 wt % Fe2O3, 16·5 wt % TiO2, 5·3 wt% Al2O3, 3·5 wt % MgO and 0·5 wt % MnO. This compositionis similar to the bulk composition of the oxide ore, as inferredfrom whole-rock data. This similarity strongly suggests thatthe ores formed from accumulation of titanomagnetite crystals,not from immiscible oxide melt as proposed in earlier studies.The occurrence of oxide ores in the lower parts of the Panzhihuaintrusion is best explained by settling and sorting of densetitanomagnetite in the ferrogabbroic parental magma. This magmamust have crystallized Fe–Ti oxides relatively early andabundantly, and is likely to have been enriched in Fe and Tibut poor in SiO2. These features are consistent with fractionationof mantle-derived melts under relatively high pressures (10kbar), followed by emplacement of the residual magma at 5 kbar.This study provides definitive field and geochemical evidencethat Fe–Ti oxide ores can form by accumulation in ferrogabbro.We suggest that many other massive Fe–Ti oxide depositsmay have formed in a similar fashion and that high concentrationsof phosphorus or carbon, or periodic fluctuation of fO2 in themagma, are of secondary importance in ore formation. KEY WORDS: ELIP; Fe–Ti oxide ore; layered intrusion; Panzhihua; QUILF  相似文献   
23.
Pressures of Crystallization of Icelandic Magmas   总被引:1,自引:0,他引:1  
Iceland lies astride the Mid-Atlantic Ridge and was createdby seafloor spreading that began about 55 Ma. The crust is anomalouslythick (20–40 km), indicating higher melt productivityin the underlying mantle compared with normal ridge segmentsas a result of the presence of a mantle plume or upwelling centeredbeneath the northwestern edge of the Vatnajökull ice sheet.Seismic and volcanic activity is concentrated in 50 km wideneovolcanic or rift zones, which mark the subaerial Mid-AtlanticRidge, and in three flank zones. Geodetic and geophysical studiesprovide evidence for magma chambers located over a range ofdepths (1·5–21 km) in the crust, with shallow magmachambers beneath some volcanic centers (Katla, Grimsvötn,Eyjafjallajökull), and both shallow and deep chambers beneathothers (e.g. Krafla and Askja). We have compiled analyses ofbasalt glass with geochemical characteristics indicating crystallizationof ol–plag–cpx from 28 volcanic centers in the Western,Northern and Eastern rift zones as well as from the SouthernFlank Zone. Pressures of crystallization were calculated forthese glasses, and confirm that Icelandic magmas crystallizeover a wide range of pressures (0·001 to 1 GPa), equivalentto depths of 0–35 km. This range partly reflects crystallizationof melts en route to the surface, probably in dikes and conduits,after they leave intracrustal chambers. We find no evidencefor a shallow chamber beneath Katla, which probably indicatesthat the shallow chamber identified in other studies containssilica-rich magma rather than basalt. There is reasonably goodcorrelation between the depths of deep chambers (> 17 km)and geophysical estimates of Moho depth, indicating that magmaponds at the crust–mantle boundary. Shallow chambers (<7·1 km) are located in the upper crust, and probablyform at a level of neutral buoyancy. There are also discretechambers at intermediate depths (11 km beneath the rift zones),and there is strong evidence for cooling and crystallizing magmabodies or pockets throughout the middle and lower crust thatmight resemble a crystal mush. The results suggest that themiddle and lower crust is relatively hot and porous. It is suggestedthat crustal accretion occurs over a range of depths similarto those in recent models for accretionary processes at mid-oceanridges. The presence of multiple stacked chambers and hot, porouscrust suggests that magma evolution is complex and involvespolybaric crystallization, magma mixing, and assimilation. KEY WORDS: Iceland rift zones; cotectic crystallization; pressure; depth; magma chamber; volcanic glass  相似文献   
24.
The petrological parameters Na8 and Fe8, which are Na2O andFeO contents in mid-ocean ridge basalt (MORB) melts correctedfor fractionation effects to MgO = 8 wt%, have been widely usedas indicators of the extent and pressure of mantle melting beneathocean ridges. We find that these parameters are unreliable.Fe8 is used to compute the mantle solidus depth (Po) and temperature(To), and it is the values and range of Fe8 that have led tothe notion that mantle potential temperature variation of TP= 250 K is required to explain the global ocean ridge systematics.This interpreted TP = 250 K range applies to ocean ridges awayfrom ‘hotspots’. We find no convincing evidencethat calculated values for Po, To, and TP using Fe8 have anysignificance. We correct for fractionation effect to Mg# = 0·72,which reveals mostly signals of mantle processes because meltswith Mg# = 0·72 are in equilibrium with mantle olivineof Fo89·6 (vs evolved olivine of Fo88·1–79·6in equilibrium with melts of Fe8). To reveal first-order MORBchemical systematics as a function of ridge axial depth, weaverage out possible effects of spreading rate variation, local-scalemantle source heterogeneity, melting region geometry variation,and dynamic topography on regional and segment scales by usingactual sample depths, regardless of geographical location, withineach of 22 ridge depth intervals of 250 m on a global scale.These depth-interval averages give Fe72 = 7·5–8·5,which would give TP = 41 K (vs 250 K based on Fe8) beneathglobal ocean ridges. The lack of Fe72–Si72 and Si72–ridgedepth correlations provides no evidence that MORB melts preservepressure signatures as a function of ridge axial depth. We thusfind no convincing evidence for TP > 50 K beneath globalocean ridges. The averages have also revealed significantcorrelations of MORB chemistry (e.g. Ti72, Al72, Fe72,Mg72, Ca72, Na72 and Ca72/Al72) with ridge axial depth. Thechemistry–depth correlation points to an intrinsic linkbetween the two. That is, the 5 km global ridge axial reliefand MORB chemistry both result from a common cause: subsolidusmantle compositional variation (vs TP), which determines themineralogy, lithology and density variations that (1) isostaticallycompensate the 5 km ocean ridge relief and (2) determine thefirst-order MORB compositional variation on a global scale.A progressively more enriched (or less depleted) fertileperidotite source (i.e. high Al2O3 and Na2O, and low CaO/Al2O3)beneath deep ridges ensures a greater amount of modal garnet(high Al2O3) and higher jadeite/diopside ratios in clinopyroxene(high Na2O and Al2O3, and lower CaO), making a denser mantle,and thus deeper ridges. The dense fertile mantle beneath deepridges retards the rate and restricts the amplitude of the upwelling,reduces the rate and extent of decompression melting, givesway to conductive cooling to a deep level, forces melting tostop at such a deep level, leads to a short melting column,and thus produces less melt and probably a thin magmatic crustrelative to the less dense (more refractory) fertile mantlebeneath shallow ridges. Compositions of primitive MORB meltsresult from the combination of two different, but geneticallyrelated processes: (1) mantle source inheritance and (2) meltingprocess enhancement. The subsolidus mantle compositional variationneeded to explain MORB chemistry and ridge axial depth variationrequires a deep isostatic compensation depth, probably in thetransition zone. Therefore, although ocean ridges are of shalloworigin, their working is largely controlled by deep processesas well as the effect of plate spreading rate variation at shallowlevels. KEY WORDS: mid-ocean ridges; mantle melting; magma differentiation; petrogenesis; MORB chemistry variation; ridge depth variation; global correlations; mantle compositional variation; mantle source density variation; mantle potential temperature variation; isostatic compensation  相似文献   
25.
Beard  James S. 《Journal of Petrology》2008,49(5):1027-1041
If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with87Sr/86Sr of 0·7058, whereas the complementary crystal-poorsample has 87Sr/86Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite  相似文献   
26.
桃山铀矿田桃山断裂及其保矿作用   总被引:2,自引:0,他引:2  
张万良 《地质论评》2008,54(6):768-774
桃山铀矿田位于江西省中部,断裂构造发育,既有成矿构造,也有保矿构造,其中斜贯桃山矿田的桃山断裂即是一保矿构造,它形成于车免近时期,走向北东,倾向南东,右行正断,并具铰链断层性质,上盘地块掀斜下落,致使上盘成矿壳层向NW和NE倾斜,由于倾末端的侵蚀深度较小,保矿条件较好,加强这些地带的铀矿勘查和评价具有重要意义。  相似文献   
27.
新疆北部后碰撞与幔源岩浆有关的成矿谱系   总被引:18,自引:12,他引:6  
新疆北部与后碰撞幔源岩浆作用有关的矿床主要有四类:铜镍硫化物矿床、钒钛磁铁矿矿床、钛铁矿-铜镍硫化物复合矿床和玄武岩型自然铜矿床。上述四类矿床成矿时代相近(主成矿期为二叠纪),空间相邻,跨构造单元分布,彼此之间可出现过渡或复合矿床类型,构成了独特的后碰撞与幔源岩浆作用有关的成矿谱系,也是中亚型造山后碰撞阶段颇具特色的成矿组合。依据其成矿专属性的不同,新疆北部与幔源岩浆有关的矿床可分为两个系列:钛铁系列和铜镍系列。钛铁系列以尾亚矿床为代表,以高钛富碱为特征,为碱性系列,REE总量高,LREE富集,ε_(Nd)(t)近0值,其含矿岩体的地球化学特征与峨嵋大火成岩省钒钛磁铁矿含矿岩体特征一致,推测其含矿岩浆来源与地幔柱活动有关;而以黄山、喀拉通克为代表的铜镍矿床成矿岩体,以相对富镁为特征,属钙碱系列和拉斑玄武岩系列,REE总量较低,模式曲线呈LREE略富集的平缓型分布,ε_(Nd)(t)为明显的正值,可能来自亏损岩石圈地幔的部分熔融。新疆北部后碰撞阶段除发育了与幔源岩浆有关的成矿谱系外,还发育了与造山带有关的构造-岩浆-成矿体系。这种既有地幔柱成矿又有造山带成矿的双重特性,可能是二叠纪地幔柱活动与造山(后碰撞)作用叠加的结果。  相似文献   
28.
河南洛宁段河金矿流体包裹体研究和矿床成因   总被引:2,自引:1,他引:1  
河南省洛宁县段河石英脉型金矿主要包括石寨沟和岭东两个矿区,分别由3~4条含金石英脉构成。矿化过程从早到晚包括石英-黄铁矿、石英-多金属硫化物和石英-碳酸盐等3个阶段.其中中阶段金矿化最强,次为早阶段。各阶段石英中流体包裹体以气液两相包裹体为主.次为纯液体包裹体。激光拉曼测试表明,气液两相包裹体的液相为H2O,气相主要为Ho和CO2混合、纯H2O,次为纯CO2;纯液体包裹体为纯H2O。石寨沟矿区包裹体均一温度从早到晚依次为240.9~315.9℃.188.7~304.5℃,137.3~259.3℃:流体盐度变化依次为(6.74~12.85)wt%NaCl.eq,(2.41~8.68)wt%NaCl.eq,(2.24-7.86)wt%NaCl.eq。岭东矿区均一温度从早到晚依次为303.7-343.1℃,251.8-325.4℃,305.7~355.0℃:流体盐度变化依次为(5.11~11.70)wt%NaCl.eq,(2.74-10.11)wt%NaCl.eq,(0.53-6.74)wt%NaCl.eq。两矿区主成矿期流体均为中温、低盐度,早阶段流体为改造热液和变质热液的混合体,含一定量CO2,且流体CO2含量和盐度从早到晚逐渐降低。石寨沟矿区包裹体均一温度逐渐降低,而岭东矿区包裹体均一温度先降后升,加之岭东矿区各阶段成矿温度均高于石寨沟矿区.表明成矿流体系统主要受岩浆热驱动,岭东矿区更靠近岩体,且在晚阶段又有脉动性的岩浆加热.段河金矿区南部存在隐伏岩体。  相似文献   
29.
河南省洛宁县寨凹钼矿床流体包裹体研究及矿床成因   总被引:10,自引:0,他引:10  
寨凹钼矿床位于华北克拉通南缘的熊耳地体.矿床定位受马超营断裂带的次级断裂控制,矿体呈脉状贼存于太华超群石板沟组黑云角闪斜长片麻岩中。成矿过程包括3个阶段:石英-辉钼矿阶段(I)、石英-多金属硫化物阶段(Ⅱ)、石英-碳酸盐阶段(Ⅲ),其中,I阶段为主成矿阶段。寨凹钼矿床可见2类流体包裹体,即水溶液型和含子晶包裹体;激光拉曼指示包裹体成分主要为H2O。从早到晚,流体包裹体均一温度从I阶段100~260℃,经Ⅱ阶段110~160℃.变化为Ⅲ阶段120—180℃.矿床总体属于低温热液矿床:流体包裹体盐度从I阶段的2~25wt%NaCl.eqv演化至Ⅱ阶段的6—30wt%NaCl.eqv.然后降为Ⅲ阶段的7~25wt%NaCl.eqv。I阶段均一温度范围宽广、流体包裹体盐度由双峰式演化为单峰式以及包裹体温度-盐度双变图的负相关性指示了流体混合是主要的成矿机制。寨凹钼矿流体包裹体以高密度、高盐度的低温低压流体为特征,是含CaCl,流体参与成矿的结果,热的岩浆流体与冷的含CaCl,的卤水的混合.导致了辉钼矿的沉淀。寨凹钼矿床地质和流体包裹体特征与侵入岩相关的成矿系统一致.指示其成因类型为与侵入岩有关的钼矿床.  相似文献   
30.
红透山块状硫化物矿石主要成分为黄铁矿、磁黄铁矿、黄铜矿、闪锌矿和石英、角闪石、黑云母等脉石矿物。将此矿石烘干后作为试料置于岩石三轴应力试验机,在13h内将轴压、围压和温度分步升至1276MPa、414MPa和350℃,然后在空气中自然冷却至室温。实验产物中黄铁矿、石英、长石等以脆性碎裂为主,而磁黄铁矿、黄铜矿、闪锌矿和云母等以塑性变形为主。再活化的黄铜矿、磁黄铁矿和少量闪锌矿呈脉和网脉穿插黄铁矿碎斑。实验结果表明,即使没有外来流体加入.构造动力作用所导致的流体包裹体破坏所释出的流体,就足以使成矿物质发生活化转移和再活化。  相似文献   
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