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51.
52.
Calcimicrobialites across the Permian-Triassic boundary in Huayingshan (华蓥山) region were investigated using the fluorescence microscopic measurements to understand the occurrence of organic matter. The microbialites are composed of micrite matrix and coarse spar cement. Abundant rhombic or magnetic needle-like carbonate minerals were observed adrift within the cement. The fluorescence microscopic measurement indicates the micrite matrix in microbialites shows the most abundant organic matter, with the rhombic or magnetic needle-like carbonate minerals and coarse spar cement coming to the 2nd and the 3rd, respectively. Organic matter is mainly preserved in the space between the grains of the micrite minerals but almost evenly distributed in the rhombic or magnetic needle-like carbonate minerals. As one of the common diagenesis types, dolomitization is observed to occur in the microbialites in Huayingshan. However, the carbonate cement in microbialites still has high content of element Sr as shown by the microprobe analysis, reflecting that the dolomitization might have happened in a restricted environment. Observation under the fluorescence microscope shows that dolomitization just led to the redistribution of organic matter in the grain space of dolomite minerals, inferring that the diagenesis has a slight effect on the preservation, and thus on the content of organic matter in the microbialites. 相似文献
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54.
Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections (Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province) straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon (TOC), pyrite sulphur, and different species of Fe, including dithionite-extractable Fe (FED), pyrite Fe (FeP), HCl-extractable Fe (FeH), and total Fe (FeT), in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe (FeHR = FeD + FeP) and FeT, and the FeP/(FeP + FeH) ratio, known as the degree of pyritization (DOP). In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios (0.20-0.77; avg. 0.45), high DOP values (0.21-0.72; avg. 0.54), and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios (0.10-0.35; avg. 0.21), low DOP values (0.11- 0.40; avg. 0.28), and SIC values are clustering on the normal marine value (SIC = 0.36). The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios (0.32-0.49; avg. 0.41), high DOP values (0.46-0.68; avg. 0.53) and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters 相似文献
55.
逯向阳 《沉积与特提斯地质》2008,28(4):14-17
烃源岩有机质丰度的恢复具有重要的现实和理论意义。笔者在对比多种方法的基础上,对大民屯凹陷的烃源岩的有机质丰度进行了恢复。 相似文献
56.
包气带介质截留不同龄垃圾渗滤液中的有机污染物 总被引:1,自引:0,他引:1
从渗滤液场龄和包气带岩性两方面着手,研究了不同岩性包气带介质对不同场龄渗滤液中有机污染物的截留作用规律。结果表明:新渗滤液经过以细砂、亚粘土为介质的包气带后,细砂和亚粘土中有机物的质量分数分别从0.70%和0.87%增大至0.80%和1.00%以上,而老渗滤液使细砂和亚粘土中有机物的质量分数降至0.70%和0.50%以下。新渗滤液经过包气带后,包气带介质中有机物的含量增大,而老渗滤液使包气带介质中有机物的含量降低,亚粘土较细砂更容易受到渗滤液污染的影响。即渗滤液性质对包气带介质中有机物含量具有方向性的影响作用,而包气带介质亚粘土比细砂更容易放大这种作用效果。 相似文献
57.
封闭体系有机质与有机碳氢氮恢复动力学研究 总被引:3,自引:0,他引:3
在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。 相似文献
58.
金岭寺—羊山盆地北票组烃源岩特征 总被引:2,自引:0,他引:2
通过对采集的岩样进行地球化学综合分析,得出金羊盆地北票组为盆地主要烃源岩,为盆地油气生成提供了物质基础;北票组烃源岩有机质丰度不高,属差一中等烃源岩;干酪根类型以腐殖型为主,成烃母质为陆地高等植物:金羊盆地北票组烃源岩已经进入成烃门限.并处于成熟阶段中的低成熟到中成熟阶段。 相似文献
59.
A dynamic box model was applied to study the characteristics of biogeochemical cycling of PO_4-P,NO_3-N,AOU,POC and PON in the southern Taiwan Strait region based on field data of the"Minnan Taiwan Bank Fishing Ground Upwelling Ecosystem Study" during the period of Dec.1987-Nov.1988.According to the unique hydrological and topographical features of the region,six boxesand three layers were considered in the model.The variation rates and fluxes of elements induced by hor-izontal current,upwelling,by diffusion,sinking of particles and biogeochemical processes were estimatedrespectively.Results further confirmed that upwellings had important effects in this region.Thenearshore upwelling areas had net input fluxes of nutrients brought by upwelling water,also had high de-pletion rates of nutrients and production rates of particulate organic matter and dissolved oxygen.Theabnormal net production of nutrients in the middle layer(10-30m) indicated the important role of bacte-ria in this high production region.Th 相似文献
60.
Hollander DJ Sinninghe Damste JS Hayes JM de Leeuw JW Huc AY 《Organic Geochemistry》1993,20(8):1253-1263
Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2. 相似文献