浙江西沪港重金属铜的配位容量和形态分析   总被引：3，自引：2，他引：3       下载免费PDF全文

吕海燕  王正方  傅和芳  冯旭文 《海洋学报》2003,25(3):47-52

根据2000年6月10～14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25～9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%.  相似文献   

Distribution of dissolved organic carbon in and near the Prydz Bay, Antarctica     

Qiu Yusheng  Chen Min  Huang Yipu  Liu Guangshan 《海洋学报(英文版)》2003,22(4):547-556

INTRODUCTIONDissolvedorganiccarbon (DOC)makesupthesecondlargestofthebioactivepoolsofcar bonintheocean ,secondtothelargestpoolofdissolvedinorganiccarbon .Theglobaldissolvedorganiccarbonpoolisestimatedtobe 6 85Gt,avaluecomparabletothemassofCO2 intheat mosphere (Hedges,1 992 ) .Thesizeofthereservoir,aswellasitsdynamics ,indicatesthatDOCplaysacentralroleintheoceancarboncycle .AsitrelatestogreenhousegasessuchasCO2 andassociatesclimatecycle ,oceanicDOCbiogeochemicalcycleshavebeenoneoftheh…  相似文献   

对虾养殖生态系中有机碳的初步研究本研究由   总被引：1，自引：0，他引：1  

游奎  马甡 《中国海洋大学学报(自然科学版)》2002,32(1):51-55

对于围隔养殖对虾生态系中有机碳的变动进行了研究 ,结果表明 :溶解有机碳 (DOC)含量波动在 5 .2 99～ 13.39mg/ L之间 ,平均为 8.5 3mg/ L± 2 .2 5 mg/ L;颗粒有机碳 (POC)含量波动在0 .6 5～ 6 .6 3mg/ L之间 ,平均为 3.2 5 mg/ L± 1.76 mg/ L;总有机碳 (TOC)含量波动在 6 .92～ 2 0 .0 2mg/ L之间 ,平均为 11.78mg/ L± 3.82 mg/ L ;其中 DOC∶ POC∶ TOC为 0 .72∶ 0 .2 8∶ 1。各种有机碳组分的含量明显高于自然海水中各种有机碳的含量 ;各种有机碳组分的含量在养殖期间总体上呈上升的趋势 ;其变化与 DCOD的变化呈显著线性正相关的关系。  相似文献   

台湾海峡中北部上升流区各种形态磷的化学特性   总被引：4，自引：0，他引：4       下载免费PDF全文

陈水土 《海洋与湖沼》1993,24(6):664-670

根据１９８８年７月调查资料讨论了台湾海峡中北部海域夏季上升流区各种形态磷的分布特征。结果表明，上升流中心区（即海坛岛东侧一带水域）具有低温、高盐、低溶解氧；ＤＩｐ，ＴＤＰ，ＰＰ，ＴＰ较高；ＤＯＰ较低（０．２７）；及ＤＩＰ／ＤＯＰ比值（约为１）较高的特性。ＤＯＰ是该海域磷的主要形态（占ＴＰ的４９．２％），其含量分布及其形态转化与生物活动直接相关，是该海域生物生产力高的体现。  相似文献   

Local remineralization patterns in the mesopelagic zone of the Eastern North Atlantic, off the NW Iberian Peninsula     

C.G. Castro  M. Nieto-Cid  X.A. lvarez-Salgado  F.F. Prez 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1925-1940

The short-time-scale variability of the remineralization patterns in the domain of Eastern North Atlantic Central Waters (ENACW) off the NW Iberian Peninsula is studied based on biogeochemical data (oxygen, nutrient salts, total alkalinity, pH, dissolved organic matter and fluorescence of dissolved humic substances) collected weekly between May 2001 and April 2002. The temporal variability of inorganic variables points to an intensification of remineralization during the summer and autumn, with an increase of nutrients, total inorganic carbon and fluorescence and a decrease of oxygen. During the subsequent winter mixing, there is a biogeochemical reset of the system, with lower nutrients, total inorganic carbon and fluorescence and higher oxygen. In contrast to inorganic variables, the levels of dissolved organic matter in the ENACW seem to respond to short-term events probably associated with fast sinking particles, where solubilisation of organic matter prevails over remineralization. Applying a previously published stoichiometric model, we observed a vertical fractionation of organic-matter remineralization. Although there is a preferential remineralization of proteins and P compounds in the entire domain of ENACW, the percentage was higher in the upper ENACW (σ<27.10 kg/m³) than in the lower; the percentage of N and P compounds in the oxidised organic matter was >80% for the upper ENACW and 63% for the lower. Likewise, the redissolution of calcareous structures contributes about 6% and 13% to the carbon regenerated in the upper and lower layers of ENACW, respectively.  相似文献   

Vertical Distribution of Meiobenthos in Bathyal Sediments of the Eastern Mediterranean Sea: Relationship with Labile Organic Matter and Bacterial Biomasses     

Roberto  Danovaro  Mauro  Fabiano  Giancarlo Albertelli  Norberto Della  Croce 《Marine Ecology》1995,16(2):103-116

Abstract. Quantitative information on the vertical distribution of meiofaunal abundances and biomass were obtained from samples collected at 3 bathyal stations in the Eastern Mediterranean Sea located at the same depth but characterized by different food supply. Vertical distribution patterns of nieiofauna were investigated in relation to the biochemical composition of the sediment organic matter (proteins, carbohydrates, and lipids) and compared to benthic bacterial standing stocks. No significant relationship between bacteria and meiofauna was found, whereas a significant relationship between protein and lipid concentrations and total meiofauna density was observed. These data suggest that labile organic matter. considered as material readily aVdihbk to benthic consumers, may be an important factor regulating meiofaunal abundance and vertical distribution in deep-sea sediments.  相似文献   

Carbon Isotope Geochemistry of the Orinoco Basin     

F. C. Tan  J. M. Edmond 《Estuarine, Coastal and Shelf Science》1993,36(6)

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.  相似文献   

大鹏澳海域水体磷的形态及其分布特征     

彭云辉  王肇鼎 《热带海洋学报》1996,(2)

根据１９９２年１２月（冬季）和１９９３年７月（夏季）对大鹏澳海域２４ｈ定点连续观测和夏季大面调查，统计了该海域各种形态磷的变化范围和平均含量；计算了各种形态磷分别占总磷（ＴＰ）和总溶解磷（ＴＤＰ）的百分比；讨论了各种形态磷之间的相互关系；分析了影响ＴＰ和ＴＤＰ分布的环境因素。  相似文献   

Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection     

Martin Hassellv 《Marine Chemistry》2005,94(1-4):111

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.  相似文献   

Nitrogen forms and decomposition of organic carbon in the southern Bohai Sea core sediments   总被引：5，自引：0，他引：5  

Song Jinming  Ma Hongbo  L&#; Xiaoxia 《海洋学报(英文版)》2002,21(1):125-133

Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts -transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 × 10~(-3)a~(-1)and 4.79× 10~(-3)a~(-1) respective  相似文献