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41.
波浪作用下海床的有效应力分析 总被引:4,自引:0,他引:4
波浪作用下海床的稳定性分析是海洋工程地质评价的重要内容。海床的稳定性可通过计算分析其随时间变化的有效应力场来评估。本文建议了一个周期荷载作用下土体的本构模型 ,并用于计算波浪作用下海床的应力与变形。采用Biot固结理论和有限单元法 ,分析了海床的动态应力场与孔隙水压力场。波浪作用下两种渗透系数时有效应力的动态变化过程结果对比 ,反映了渗透消散作用对海床有效应力变化的影响 相似文献
42.
南海南部约30 ka来沉积有机质的生物输入特征 总被引:7,自引:4,他引:7
对位于南沙海区的1962柱状样中的有机质进行了热解色谱分析,估算了沉积有机质中水生生物输入和陆源生物输入的变化情况,得出了两种输入的高分辨率的堆积速率曲线,并依此探讨了有关的古海洋事件。发现Younger Dryas、Heinrich及Bond周期事件在本海区皆有表现,说明“西太平洋暖池”在末次冰期是不稳定的。 相似文献
43.
Quantum yield for the photochemical production of dissolved inorganic carbon in seawater 总被引:2,自引:0,他引:2
The direct photooxidation of coloured dissolved organic matter (CDOM) to dissolved inorganic carbon (DIC) may provide a significant sink for organic carbon in the ocean. To calculate the rate of this reaction on a global scale, it is essential to know its quantum yield, or photochemical efficiency. We have determined quantum yield spectra, φ(λ), (moles DIC/mole photons absorbed) for 14 samples of seawater from environments ranging from a turbid, eutrophic bay to the Gulf Stream. The spectra vary among locations, but can be represented quite well by three pooled spectra for zones defined by location and salinity: inshore φ(λ)=e−(6.66+0.0285(λ−290)); coastal φ(λ)=e−(6.36+0.0140(λ−290)); and open ocean φ(λ)=e−(5.53+0.00914(λ−290)). Production efficiency increases offshore, which suggests that the most highly absorbing and quickly faded terrestrial chromophores are not those directly responsible for DIC photoproduction. 相似文献
44.
氮磷营养盐与有机汞联合作用对微氏海链藻生长的影响 总被引:1,自引:1,他引:1
探讨在高营养盐(氮、磷、硅分别为浮游植物生长的营养盐阚值≥40、50、9倍)条件下,氮浓度及氮磷摩尔比值[n(N)/n(P)]变化、汞(甲基汞和乙基汞)对微氏海链藻(Thalassiosira weissflogii)生长的影响。结果表明,高营养盐区海链藻的生长遵循营养盐限制的唯一因子论;氮浓度和氮磷比提高促进生长,当n(N)/n(P)=64则呈抑制效应;生长初期,甲基汞和乙基汞均产生毒性抑制作用,生长中后期,适量甲基汞(浓度≤1.0μg/L)、乙基汞(浓度≤0.5μg/L)却呈兴奋效应,促进生长;汞形态不同,剂量-效应关系不同。氮和有机汞是海链藻生长的刺激因子。适度有机汞污染与氮富营养化对微氏海链藻的生长产生协同效应。 相似文献
45.
46.
Christopher L. Dupont James. W. Moffett Robert R. Bidigare Beth A. Ahner 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1961-1974
Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation. 相似文献
47.
Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas 总被引:3,自引:0,他引:3
The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (Ls), ranging from 19 to 93 pM with an average conditional stability constant (KHgLs) of 1028, and a weak class (Lw) ranging from 1.4 to 9.8 nM with an average KHgLs of 1023. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgClx, Hg(OH)x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters. 相似文献
48.
对氯甲烷的海洋生物地球化学循环的研究进展进行述评。介绍了氯甲烷在海洋环境中的来源、分布、去除、海-气通量、大气氯甲烷的源、汇估算及海水中氯甲烷的分析方法等方面,并提出在国内海域进行氯甲烷研究的几点设想。 相似文献
49.
波浪作用下孔隙海床-管线动力相互作用分析 总被引:1,自引:0,他引:1
波浪作用下海床中的孔隙水压力与有效应力是影响海底管线稳定性的主要因素。然而,在目前的海床响应分析中一般将管线假定为刚性,并不能合理地考虑海床与管线之间的相互作用效应,同时也没有考虑土体和管线加速度对海床动力响应的惯性影响,从而无法确定由此所引起的管线内应力。为此考虑管线的柔性,分别采用饱和孔隙介质的Biot动力固结理论和弹性动力学理论列出了海床与管线的控制方程,进而采用摩擦接触理论考虑海床与管线之间的相互作用效应,基于有限元方法建立了海床-管线相互作用的计算模型及其数值算法。通过变动参数对比计算讨论了管线几何尺寸、海床土性参数对波浪所引起的管线周围海床孔隙水压力和管线内应力的影响。 相似文献
50.