Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates     

Philippe E. Raison  Regis Jardin  Daniel Bouëxière  Rudy J. M. Konings  Thorsten Geisler  Claudiu C. Pavel  Jean Rebizant  Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.  相似文献   

Optical spectrum based measurement of flotation slurry contents   总被引：1，自引：1，他引：0  

Olli Haavisto  Jani Kaartinen  Heikki Hytyniemi 《International Journal of Mineral Processing》2008,88(3-4):80-88

Monitoring and control of a flotation circuit is mainly based on the information gained by assaying the process slurry lines. In flotation plants, usually an X-ray fluorescence analyzer is used to obtain the on-line assays. This article introduces the visual and near-infrared reflectance spectroscopic analysis of the process slurries as a supplementary method which complements the on-line assay information available from an X-ray fluorescence analyzer. It is shown that the spectral information can be used to accurately predict the element contents in the slurry in between successive XRF analyses. Since the spectral measurements can be taken with high frequency as opposed to the sparse X-ray fluorescence analysis, a practically continuous on-line estimate of the slurry contents is reached. These estimates can be used in the plant control to improve the overall performance of the circuits and to yield also economical savings. Additionally, the frequent monitoring of the grades can provide means to eliminate rapid disturbances in the circuits, thus improving the stability of the process.  相似文献   

The spatial implications of the functional proximity deriving from air passenger flows between European metropolitan urban regions     

Malcolm C. Burns  Josep Roca Cladera  Montserrat Moix Bergadà 《GeoJournal》2008,71(1):37-52

Until recently the traditional spatial configuration of the European geography was based upon the core-periphery model. The ‘pentagon’, broadly defined as lying between London, Paris, Milan, Munich and Hamburg, was seen as the core area characterised by having the highest concentration of economic development in the European Union (EU), with the remainder of the European territory viewed as peripheral, albeit to varying degrees. In a number of cases such peripheral areas equated with clear regional disparities. The elaboration of the European Spatial Development Perspective (ESDP) (CEC, European spatial development perspective, towards balanced and sustainable development in the territory of the European Union, 1999) challenged this core-periphery model. European spatial planning policies, aimed at encouraging social and economic, and with ever increasing importance, territorial cohesion, seek amongst other aspects to encourage the development of a balanced and polycentric urban system. This paper adopts a network analysis approach to the analysis of air passenger flows between some 28 principal European metropolitan urban regions. The evaluation of these flows contributes to an enhanced comprehension of the spatial dynamics of the European metropolitan territory which goes beyond that deriving from the more standard analyses of the individual components of the urban system. Several indicators are used, deriving from gravitational modelling techniques, to analyse the complexity of the air passenger flows. A multidimensional scaling (MDS) technique is introduced in order to interpret and visualise the resulting spatial configuration and positioning of the different metropolitan centres within the conceptual European ‘space of air passenger flows’, thereby contrasting with the more traditional map-based geographical image of Europe, based upon Cartesian coordinates.

Malcolm C. BurnsEmail:

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Influence of Structural Non-Stationarity of Surface Roughness on Morphological Characterization and Mechanical Deformation of Rock Joints   总被引：2，自引：2，他引：0  

N. Fardin 《Rock Mechanics and Rock Engineering》2008,41(2):267-297

Summary Structural non-stationarity of surface roughness affects accurate morphological characterization as well as mechanical behaviour of rock joints at the laboratory scale using samples with a size below the stationarity threshold. In this paper, the effect of structural non-stationarity of surface roughness is investigated by studying the scale dependence of surface roughness and mechanical behaviour of rock joints. The results show that the structural non-stationarity mainly affects the accurate characterization of the surface roughness of the fracture samples. It also controls the amount and location of the contact areas during shear tests, which in turn affects the mechanical properties and asperity degradation of the samples. It is concluded that for accurate determination of the morphological and mechanical properties of rock joints at laboratory and field scales, samples with size equal to or larger than the stationarity threshold are required. Author’s address: Nader Fardin, Rock Mechanics Group, Department of Mining Engineering, Faculty of Engineering, University of Tehran, P.O. Box: 11365/4563, Tehran, Iran  相似文献   

Soil erosion susceptibility assessment and validation using a geostatistical multivariate approach: a test in Southern Sicily   总被引：2，自引：0，他引：2  

Christian Conoscenti  Cipriano Di Maggio  Edoardo Rotigliano 《Natural Hazards》2008,46(3):287-305

A certain number of studies have been carried out in recent years that aim at developing and applying a model capable of assessing water erosion of soil. Some of these have tried to quantitatively evaluate the volumes of soil loss, while others have focused their efforts on the recognition of the areas most prone to water erosion processes. This article presents the results of a research whose objective was that of evaluating water erosion susceptibility in a Sicilian watershed: the Naro river basin. A geomorphological study was carried out to recognize the water erosion landforms and define a set of parameters expressing both the intensity of hydraulic forces and the resistance of rocks/soils. The landforms were mapped and classified according to the dominant process in landsurfaces affected by diffuse or linear water erosion. A GIS layer was obtained by combining six determining factors (bedrock lithology, land use, soil texture, plan curvature, stream power index and slope-length factor) in unique conditions units. A geostatistical multivariate approach was applied by analysing the relationships between the spatial distributions of the erosion landforms and the unique condition units. Particularly, the density of eroded area for each combination of determining factors has been calculated: such function corresponds, in fact, to the conditional probability of erosion landforms to develop, under the same geoenvironmental conditions. In light of the obtained results, a general geomorphologic model for water erosion in the Naro river basin can be depicted: cultivated areas in clayey slopes, having fine-medium soil texture, are the most prone to be eroded; linear or diffuse water erosion processes dominate where the topography is favourable to a convergent or divergent runoff, respectively. For each of the two erosion process types, a susceptibility map was produced and submitted to a validation procedure based on a spatial random partition strategy. Both the success of the validation procedure of the susceptibility models and the geomorphological coherence of the relationships between factors and process that such models suggest, confirm the reliability of the method and the goodness of the predictions.  相似文献   

Effect of Inter-Column Spacing on Soil Stresses due to Vibro-Installed Stone Columns: Interesting Findings   总被引：1，自引：0，他引：1  

Hesham Elshazly  Mohamed Elkasabgy  Azza Elleboudy 《Geotechnical and Geological Engineering》2008,26(2):225-236

This paper reveals the interesting relation between the inter-column spacing and the corresponding alteration of soil state of stresses due to the vibro-installation technique. This relation is inferred from analyses for load settlement records of various field load tests, performed for stone columns arrangements with different inter-column spacing values. In order to have adequate confidence in the findings, a well-documented case history, involving three columns patterns along with their relevant field and laboratory test results, is utilized for this study. Moreover, a well-tested finite element model, capable of simulating both elasto-plastic and time dependent soil deformations as well as pore water pressure building and dissipation, is employed in the analysis. Instead of determining the soil response to the test load, based on known initial soil stresses and material properties, the analysis is inversely posed to determine the soil initial stresses, based on the recorded settlements and the post-installation material properties. The alteration in the soil state of stress is represented by the increase in the post-installation horizontal to vertical stress ratio, K*, as a function of the inter-column spacing. It is found that this alteration experiences a systematic decrease in its magnitude as the inter-column spacing increases.  相似文献   

江苏潮滩沉积物激光粒度仪与移液管-筛析分析结果的对比     

仝长亮  高抒 《沉积学报》2008,26(1):46-53

激光粒度仪的广泛应用带来了与历史数据的对比问题,因此需要建立激光粒度仪与早期分析结果之间的关系。根据江苏海岸潮滩沉积物样品的激光粒度仪和移液管-筛析法分析,对粒度参数、粒度组分等进行了对比,对两种方法的差异进行了分析。结果表明,对于江苏潮滩沉积物粒度参数中平均粒径的激光粒度仪与移液管-筛析分析结果之间有良好的线性关系;筛分法测得的粗颗粒物质较激光法偏少,而移液管法法测得的细颗粒物质较激光法偏多;将样品分类之后再进行两种方法所获粒度参数的回归分析,相关性得以提高,说明不同粒度组成的沉积物对分析结果的对比有不同的影响。两种方法之间的换算关系不仅与研究区域有关,而且与沉积物本身的粒度组成有关。  相似文献   

藏南地区中生代硅质岩的地球化学特征及其成因意义   总被引：6，自引：1，他引：5  

周永章  付伟  杨志军  何俊国  聂凤军  李文  赵文霞 《岩石学报》2008,24(3)

藏南地区中生代硅质岩包括蛇绿岩套硅质岩(与蛇绿岩共生)和非蛇绿岩套硅质岩两大类.本文重点分析日喀则地区彭错林、夏鲁以及泽当地区的罗布莎、江孜盆地宗卓组及四个剖面的硅质岩.其中,彭错林、夏鲁和罗布莎硅质岩与蛇绿岩共生,江孜盆地宗卓组为非蛇绿岩套硅质岩.分析表明:(1)藏南地区硅质岩剖面地球化学特征鲜明,具有一致性和多样性特点;(2)与蛇绿岩共生的彭错林、夏鲁、罗布莎硅质岩普遍具有高Si、高Fe、低Al特征,大部分微量元素相对于克拉克值亏损,稀土元素总量低,经北美页岩标准化后,Ce异常明显或不明显,重稀土相对轻稀土富集.硅质泥岩的∑REE要明显高于硅质岩;(3)非蛇绿岩套宗卓组硅质岩SiO2含量稍低,Al2O3、TiO2则相反.V、Th、Hf、Ta等不相容元素上亏损程度较小,部分样品含量可接近克拉克值.稀土总量相对较高,页岩标准化配分模式上体现为弱Ce正异常,负Eu异常,轻重稀土分异不明显的平坦型曲线图;(4)地球化学特征指示了,藏南地区硅质岩多数具有明显的热水沉积成因属性,同时有正常陆源组分的加入.其中,夏鲁硅质岩的热水沉积地球化学特征较为典型,而宗卓组硅质岩则表现出受陆源物质加入的影响显著的地球化学特点.  相似文献   

三峡库区生基包滑坡监测及成果分析          下载免费PDF全文

赵重  李长明  李厚芝 《探矿工程》2008,35(7):32-34,37

生基包滑坡监测属于三峡库区奉节县三期地质灾害监测预警项目之一,该滑坡位于长江左岸,临近人口稠密的安坪乡集镇,地理位置重要。三峡水库175 m蓄水后,其变形破坏特征有何表现？对航道安全运营有无潜在威胁？是否会对滑坡体上的重要建筑及村民生产生活构成危害？针对这些问题,首先分析了滑坡的工程地质特征及主要的影响因素;其次,确立以4种监测手段为主、人工巡查为辅的监测方案;通过对大地变形GPS、深部位移、滑坡推力等几种监测方法的运用及对其成果进行分析研究,以实例说明其在滑坡监测中的应用;再次,结合宏观人工巡查进行对照分析,以充分说明大地变形、深部位移和滑坡推力监测在实际运用中的可行性;最后,根据监测结论提出对生基包滑坡防治的建议。  相似文献   

水平定向钻进非开挖铺管技术市场分析     

袁明昕 《探矿工程》2008,35(10):49-51

重点分析了近几年我国水平定向钻进铺管钻机和施工市场的发展趋势,结合国外的水平定向钻进市场发展分析,总结了我国水平定向钻进技术与市场的发展态势。  相似文献