湘黔地区下寒武统黑色岩系中镍-钼矿床黄铁矿的成因     

江永宏  李胜荣 《地质通报》2010,29(2)

重点研究了贵州遵义中南村和湖南张家界三岔镍-钼多金属矿床的黄铁矿,矿床成因为热水喷流沉积型.黄铁矿样品S/Fe比值的平均值为2.0093-2.048,成分特征均属于铁亏损型,说明其形成温度低.Co/Ni变化范围为0.077~4.5,均值为2.197.据Co/Ni的比值可以判断本区的黄铁矿主要为热液成因,矿化物质来源为热水喷流体系内的热液.成分图解标型显示,黑色岩系中高ω(Co+Ni)/ω(Fe)的黄铁矿和高ω(As+Se+Te)/ω(S)的黄铁矿均大量出现,可能与热水喷流沉积的温差变化范围较大有关.而并非正常沉积的产物.S/Se比值为950.8-1059.9,说明生成环境均一程度较高,而且海水温度比较高.由中南村镍-钼矿床的Se/Te值也能判明其为热液成因.关于黄铁矿的研究对本区镍-钼矿床的寻找有重要意义.  相似文献   

攀西宁南地区上震旦统灯影组麦地坪段C、O同位素特征和震旦系/寒武系界线的划分   总被引：1，自引：0，他引：1  

余光模  梁斌  钟长洪 《地质通报》2010,29(6):901-906

对上震旦统灯影组麦地坪段的C、O同位素组成进行了分析,并根据δ13C值在剖面上的变化特征,讨论了该地区震旦系/寒武系的界线。结果表明,麦地坪段白云岩δ13C值在-3.19‰～2.86‰之间,平均值为0.10‰;δ18O值在-10.75‰～-5.17‰之间,平均值为-7.82‰。在剖面上δ13C值出现了有规律的变化,剖面下部2～21层,δ13C值均为正值,在0.04‰～1.68‰之间,平均值为0.92‰;上部23～32层,δ13C值均为负值,在-3.19‰～-1.42‰之间,平均值为-2.13‰,δ13C值存在一个显著的负漂移,变化高达4‰。麦地坪段白云岩δ13C值的变化特征与国内外同期地层非常相似,具有全球可对比性,可作为震旦系/寒武系划分的地球化学标志。  相似文献   

Tracing dissolved organic matter cycling in the eastern boundary of the temperate North Atlantic using absorption and fluorescence spectroscopy     

《Deep Sea Research Part I: Oceanographic Research Papers》2014

Apparent oxygen utilization (AOU), dissolved organic carbon (DOC), coloured dissolved organic matter (CDOM) absorption spectra, and CDOM fluorescence characteristic of aromatic amino acids (excitation/emission 280 nm/320 nm; F(280/320)) and marine-humic like substances (320 nm/410 nm; F(320/410)) were measured in full depth during a cruise in the temperate Eastern North Atlantic (ENA). An optimum multi-parameter (OMP) inverse method was run to calculate water mass proportion-weighted average (archetypal) concentrations of these chemical parameters for all water masses and samples. Archetypal concentrations retain the variability due to water mass mixing and basin scale mineralization from the water mass formation sites to the study area. Conversely, the difference between measured and archetypal concentrations, retain the variability due to dissimilarities in mineralization processes within the study area. Our analysis indicates that DOC supported 26±3% of the AOU in the dark temperate ENA and that basin scale processes occurring at and from the formation area of the water masses explained 63% of the total DOC variability. Our data also suggests that DOC remineralized at the basin scale was of lower molecular weight, and with a lower proportion of fluorescent aromatic amino acids than found within the study area. The relationship between the absorption coefficient at 254 nm (a_CDOM(254)) and AOU indicates that a_CDOM(254) was consumed during organic matter remineralization in the dark ocean, with 55% of the variability being explained by basin scale processes. The relationships of F(320/410) with AOU and DOC confirmed that marine humic-like substances are produced by microbial degradation processes, at a rate of 6.1±0.9×10⁻³ mg equivalents of QS mol AOU⁻¹. Our results also indicate that basin-scale remineralization processes account for 85% of the total variability of F(320/410), emphasizing that large scale processes control the formation of humic-like substance in the dark ENA.  相似文献   

Characteristics of Triassic epithermal Au mineralization at the Q prospect,Chatree mining area,Central Thailand     

Ladda Tangwattananukul  Daizo Ishiyama  Osamu Matsubaya  Toshio Mizuta  Punya Charusiri  Hinako Sato  Koichiro Sera 《Resource Geology》2014,64(2):167-181

The Chatree deposit is located in the Loei‐Phetchabun‐Nakhon Nayok volcanic belt that extends from Laos in the north through central and eastern Thailand into Cambodia. Gold‐bearing quartz veins at the Q prospect of the Chatree deposit are hosted within polymictic andesitic breccia and volcanic sedimentary breccia. The orebodies of the Chatree deposit consist of veins, veinlets and stockwork. Gold‐bearing quartz veins are composed mainly of quartz, calcite and illite with small amounts of adularia, chlorite and sulfide minerals. The gold‐bearing quartz veins were divided into five stages based on the cross‐cutting relationship and mineral assemblage. Intense gold mineralization occurred in Stages I and IV. The mineral assemblage of Stages I and IV is characterized by quartz–calcite–illite–laumontite–adularia–chlorite–sulfide minerals and electrum. Quartz textures of Stages I and IV are also characterized by microcrystalline and flamboyant textures, respectively. Coexistence of laumontite, illite and chlorite in the gold‐bearing quartz vein of Stage IV suggests that the gold‐bearing quartz veins were formed at approximately 200°C. The flamboyant and brecciated textures of the gold‐bearing quartz vein of Stage IV suggest that gold precipitated with silica minerals from a hydrothermal solution that was supersaturated by boiling. The δ¹⁸O values of quartz in Stages I to V range from +10.4 to +11.6‰ except for the δ¹⁸O value of quartz in Stage IV (+15.0‰). The increase in δ¹⁸O values of quartz at Stage IV is explained by boiling. P_H2O is estimated to be 16 bars at 200°C. The f_CO2 value is estimated to be 1 bar based on the presence of calcite in the mineral assemblage of Stage IV. The total pressure of the hydrothermal solution is approximately 20 bars at 200°C, suggesting that the gold‐bearing quartz veins of the Q prospect formed about 200 m below the paleosurface.  相似文献   

Chalcophile element partitioning between sulfide phases and hydrous mantle melt: Applications to mantle melting and the formation of ore deposits     

《Journal of Asian Earth Sciences》2014

Understanding the geochemical behavior of chalcophile elements in magmatic processes is hindered by the limited partition coefficients between sulfide phases and silicate melt, in particular at conditions relevant to partial melting of the hydrated, metasomatized upper mantle. In this study, the partitioning of elements Co, Ni, Cu, Zn, As, Mo, Ag, and Pb between sulfide liquid, monosulfide solid solution (MSS), and hydrous mantle melt has been investigated at 1200 °C/1.5 GPa and oxygen fugacity ranging from FMQ−2 to FMQ+1 in a piston-cylinder apparatus. The determined partition coefficients between sulfide liquid and hydrous mantle melt are: 750–1500 for Cu; 600–1200 for Ni; 35–42 for Co; 35–53 for Pb; and 1–2 for Zn, As, and Mo. The partition coefficients between MSS and hydrous mantle melt are: 380–500 for Cu; 520–750 for Ni; ∼50 for Co; <0.5 for Zn; 0.3–6 for Pb; 0.1–2 for As; 1–2 for Mo; and >34 for Ag. The variation of the data is primarily due to differences in oxygen fugacity. These partitioning data in conjunction with previous data are applied to partial melting of the upper mantle and the formation of magmatic-hydrothermal Cu–Au deposits and magmatic sulfide deposits.I show that the metasomatized arc mantle may no longer contain sulfide after >10–14% melt extraction but is still capable of producing the Cu concentrations in the primitive arc basalts, and that the comparable Cu concentrations in primitive arc basalts and in MORB do not necessarily imply similar oxidation states in their source regions.Previous models proposed for producing Cu- and/or Au-rich magmas have been reassessed, with the conclusions summarized as follows. (1) Partial melting of the oxidized (fO₂ > FMQ), metasomatized arc mantle with sulfide exhaustion at degrees >10–14% may not generate Cu-rich, primitive arc basalts. (2) Partial melting of sulfide-bearing cumulates in the root of thickened lower continental crust or lithospheric mantle does not typically generate Cu- and/or Au-rich magmas, but they do have equivalent potential as normal arc magmas in forming magmatic-hydrothermal Cu–Au deposits in terms of their Cu–Au contents. (3) It is not clear whether partial melting of subducting metabasalts generates Cu-rich adakitic magmas, however adakitic magmas may extract Cu and Au via interaction with mantle peridotite. Furthermore, partial melting of sulfide-bearing cumulates in the deep oceanic crust may be able to generate Cu- and Au-rich magmas. (4) The stabilization of MSS during partial melting may explain the genetic link between Au-Cu mineralization and the metasomatized lithospheric mantle.The chalcophile element tonnage, ratio, and distribution in magmatic sulfide deposits depend on a series of factors. This study reveals that oxygen fugacity also plays an important role in controlling Cu and Ni tonnage and Cu/Ni ratio in magmatic sulfide deposits. Cobalt, Zn, As, Sn, Sb, Mo, Ag, Pb, and Bi concentrations and their ratios in sulfide, due to their different partitioning behavior between sulfide liquid and MSS, can be useful indices for the distribution of platinum-group elements and Au in magmatic sulfide deposits.  相似文献   

群孔抽水试验与同位素分析在煤矿水文地质勘查中的应用     

来永伟  李本军  王志奇  齐荣贵 《中国煤炭地质》2014,(1):39-42

田庄煤矿主采煤层为石炭系太原组16上及17煤层,威胁煤层开采的地下水水源主要为十下灰、十三、十四灰和奥灰含水层。其中十三、十四灰含水层水力联系密切,可按同一含水层看待。十下灰岩水为16上煤的直接充水水源,十三、十四灰灰岩水和奥灰灰岩水为16上及17煤层的底板间接充水水源,在构造地段有可能转化为直接充水水源。在研究煤矿群孔放水试验的基础上,全面分析了氢氧同位素资料,结果表明井田内十下灰和奥灰含水层有各自的补、径、排系统,正常情况下水力联系较弱;十三、十四灰含水层与十下灰和奥灰含水层均发生着水力联系,在采掘及导水断层的影响下,其含水层间地下水联系变得更加密切。两种研究的结论基本一致,增加了成果的科学性和可信性。  相似文献   

花岗岩型热液铀矿床C、O同位素研究---以甘肃省龙首山芨岭矿区为例   总被引：3，自引：0，他引：3  

陈云杰 《地质与勘探》2014,50(4):641-648

龙首山地区是西北重要的花岗岩型热液铀矿产区之一,区内控矿条件复杂。研究选取甘肃省龙首山芨岭矿区内的矿床和部分矿点的热液碳酸盐样品并测定其C、O同位素组成：δ13C VPDB的值在-1.50‰～-6.33‰之间,δ18OSMOW值为-2.577～5.051‰之间。进一步研究结果表明,成矿流体中矿化剂ΣCO2主要来源于与区域深大断裂有关的幔源脱气作用,同时伴有海相碳酸盐来源;成矿同时期伴随的强烈流体脱气(CO2)作用对矿质沉淀至关重要。成矿热液的水源主要为岩浆热液与大气降水混合特征,但以大气降水形成为主。  相似文献   

川北元坝地区长兴组白云石化作用机制及其对储层形成的影响   总被引：2，自引：2，他引：0  

孟万斌  武恒志  李国蓉  张小青  吕正祥 《岩石学报》2014,30(3):699-708

通过岩心观察和薄片鉴定,在岩石学和矿物学特征分析基础上,结合白云石有序度测定,碳、氧同位素、锶同位素和稀土元素组成及配分模式分析,详细研究了川北元坝地区长兴组白云石化作用的特征、机制及模式,结果表明长兴组发育微晶白云石(岩)、粉-中晶他形白云石、粉-中晶自形白云石和异形白云石等四种类型,它们的有序度由低变高;白云石的碳、氧同位素、锶同位素和稀土元素组成及配分模式特征表明,长兴组微晶白云石(岩)、粉-中晶他形白云石、粉-中晶自形白云石主要形成于浓缩海水环境、正常海水环境、或者与正常海水相似的地层水环境中,并遭受过热液地质作用的改造,从微晶白云石(岩)→粉-中晶他形白云石→粉-中晶自形白云石是一个沉积埋藏过程中多阶段白云石化作用的产物,异形白云石则由热液作用形成;根据长兴组白云石的矿物学和地球化学特征及白云石化作用与层序和沉积相之间的关系,分别可以用准同生期蒸发泵白云石化作用模式、准同生期渗透回流白云石化作用模式、成岩早期浅埋藏状态下地层水白云石化作用模式和成岩晚期热液白云石化作用模式来解释微晶白云石(岩),粉-中晶他形白云石、粉-中晶自形白云石和异形白云石的形成。白云石化作用是有利于长兴组储层形成的建设性成岩作用。  相似文献   

甘肃马坞金矿成矿流体特征及地质意义   总被引：1，自引：1，他引：0       下载免费PDF全文

刘坤  刘家军吴 杰杨尚松辛晓军李 渊 《中国地质》2014,41(5):1594-1607

位于西秦岭岷(县)—礼(县)成矿带西段的马坞金矿床,是近年发现的一个中型卡林型金矿床。矿体产出受NWW向断裂构造控制,其赋矿围岩为中泥盆统的千枚岩与灰岩。矿床流体包裹体研究表明,脉石矿物中主要发育CO2-H2O型和H2O溶液型包裹体;均一温度为135~389℃,盐度为4.4%~15.9%,为中-低温、中-低盐度流体;流体成矿压力为34.6~219.8 MPa,成矿深度为1.3~8.1 km。流体包裹体气相成分以H2O、N2为主,其次为CO2、O2,并含有少量CH4、CO等还原性气体;液相成分中阳离子以Ca2+、Na+为主,阴离子以Cl-和SO42-占主导地位,成矿流体为N2-H2O-Ca2+-Cl-体系。氢氧同位素测试结果表明,成矿流体的δ18O水为5.3‰~10.5‰,δD为-123‰~-93‰,成矿流体主要为热卤水。从流体性质及其演化来看,构造体制的转换使流体稳定体系发生改变与沸腾作用是造成金富集成矿的主要因素。  相似文献   

黑龙江乌拉嘎金矿成矿热力学参数研究     

尹淑苹  李永兵  田会全  刘善琪 《岩石矿物学杂志》2014,33(4):720-725

本文通过对前人工作的总结,在研究矿物共生关系的基础上将乌拉嘎金矿床的成矿作用过程划分为3个成矿阶段,然后利用热力学数据计算出了各个阶段的成矿热力学参数。第1阶段:黄铁矿-早期白色玉髓状石英阶段,Eh范围在-0.5~+0.3 V之间,处于弱还原环境,硫逸度应大于10~(-23);第2阶段:烟灰色玉髓状石英-多金属硫化物阶段,在低温时成矿环境为中酸性(pH=4),弱还原环境(Eh值为-1.0~-0.3 V),硫逸度范围应大于10~(-40),但不会超过10~0。同前一阶段相比,硫逸度下限降低;第3阶段:碳酸盐-石英阶段,碳酸盐矿物的出现预示着成矿已接近尾声,成矿介质的pH值逐步从酸性(pH=3)向中酸性(pH=5)转变,成矿Eh值也从弱还原(-0.5 V)向弱氧化(+0.3 V)过渡,硫逸度下限范围大约在10~(-23)左右,不超过10~0,而氧逸度范围在10~(-20)加左右。这对于深入探讨热液成矿作用过程具有重要参考价值。  相似文献