华南-古岩溶型铀矿床中有机质的热成熟异常及其矿床成因意义     

闽茂中  张祖还  刘兰忠 《矿床地质》1996,15(1):64-70

华南某层控铀矿床中有机质可分为原生沉积型、热液变质型和运移型三种类型，其母质类型为腐泥－腐殖型，主要来源于海相微体生物、藻类及少量源于陆相高等植物。根据镜质体反射率、饱和烃气相色谱和某些地球化学指标，表明矿石中有机质呈现异常热成熟特征，这对揭示该矿床热水叠造成矿机制具有指纹意义。本文还首次合理解释矿石中铀与有机碳含量间复杂关系的原因。  相似文献   

红外,紫外及荧光分析在有机包裹体研究中的应用   总被引：1，自引：0，他引：1  

余孝颖  施继锡 《矿物学报》1996,16(2):212-217

本文利用红外，紫外及荧光分析方法，对岩石中吸附有机质和包裹体有机质进行了分析研究，红外分析结果表明，生油岩中的包裹体有机质有明显的石油峰，并且与吸附有机质的峰形有较大差别，紫外分析结果也表明，生油岩中两种有机质的光谱性质不一致，而非生油岩则相反，生油岩荧光光谱特征为：荧光强度大（〉４０），λｍａｘ在４５０ｎｍ左右，光谱位于蓝绿光区，演化程度属高成熟原油阶段，这些可作为评价生油潜力，演化程度的方法及  相似文献   

A Study on Organic Inclusions in Clastic Reservoir Rocks and Their Application to the Assessment of Oil and Gas Accumulations   总被引：5，自引：0，他引：5  

张文淮  张志坚等 《中国地球化学学报》1996,15(3):249-257

Terrigenous clastic reservoir rocks are widespread in China,and nearly all the industrial oil and gas accumulations in eastern China occur in the clastic rocks.The study shows that organic inclusions are mostly distributed in the secondary fissures and pores which were ormed in the process of oil-rock interaction,rather than in the cements or secondary enlargements. The organic inclusions are dominantly organic gas-rich or are composed of pure hydrocarbons.Homogenization temperatures range mainly from 120℃ to 130℃，which shows a relatively high maturity of organic matter.Vertical and horizontal temperature changes provide the grounds for the investigation of basin evolution and thermal fluid-kinetics-model.Fluorescence spectral characteristics o the organic inclusions indicate that oils and gases in the area studied probably have experienced two-stage or two-time migration.Micro-fluorescence rescearch is one of the effective approaches to oil/source correlation and oil migration-stage determination.The abundance and occurrence of organic inclusions is one of the indicators of oil and gas abundance and accumulation in rock layers.With the help of other informatio,organic inclusions can provide the basis for the prospective assessment of oil and gas in clastic reservoir rocks.  相似文献   

Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications   总被引：2，自引：0，他引：2  

沈忠民  周光甲等 《中国地球化学学报》1996,15(4):324-330

Organic matter was experimentally extracted by supercritical fluids(CO2 1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.  相似文献   

低温条件下有机酸对铁、铜的淋滤实验研究     

张海祥  王玉荣  梅厚钧 《矿床地质》1997,16(1):86-92

水／岩作用实验研究表明，在低温条件下柠檬酸、草酸和酒石酸对岩石中的铁、铜都有很高的淋滤率。这表明，在表生地质作用过程中有机酸对成矿元素有很强的活化能力。实验研究同时发现，有机酸对成矿元素的活化能力受其分解温度的限制，由于大部分有机酸的分解温度都在２５０℃以下，因而有机酸对成矿元素的活化仅限于低温条件。本次研究还显示，判断一种岩石能否成为矿源层，不能简单的以其中成矿元素的含量高低作为标准，其中更关键的因素是元素在岩石中的存在形式，如果成矿元素在岩石中难以活化的形式存在，那么含量再高也无法提供成矿物质  相似文献   

云南腾冲热泉金的有机地球化学研究——Ⅰ生物标志物浅析   总被引：1，自引：1，他引：1  

潘海祥等  陆元法 《矿物岩石》1997,17(2):84-88

本文主要通过对比分析研究热泉软泥中的金含量与有机质及含硫化合物的相关性。并测定泉水及软泥中含金量和软泥中有机碳含量，以及对抽提物中的饱和烃和芳烃族组分进行色谱—质谱分析，最后得出的结论：有机质的沉积环境为还原—强还原，有机质属于腐泥－腐殖型，接近和达到了成熟阶段。软泥中金含量与有机质的性质无明显相关关系，与有机碳含量也无明显相关关系，而与其成熟度相关密切。样品分析证实软泥中含硫化合物与金含量呈正相关性。对比分析了水及软泥中金含量，认为两者之间也无明显相关关系  相似文献   

Sediment—Hosted Gold Deposits in China_geochemistry and Prospecting   总被引：1，自引：0，他引：1  

杨蔚华  刘友梅 《中国地球化学学报》1997,16(3):202-212

Sediment-hosted gold deposits are the major type of gold resources in china,Concen trated mostly in the two“Triangle Regios“,they are generally hosted in fine-clastic turbidite,hydrothermal chet and marl ranging from cambrian to Triassic in age,structurally controlled by domes,anticlines and second-ordered faults.They are similar to the Carlin-type gold deposits in mineral assemblage and geochemical marks,with an element association closely comparable to those of modern springs and submarine hydrothermal sediments.Organic matter may have played an important role in mineralization .The ore solution may be hydrothermally altered meteoric water developed i areas of local geothermal anomaly.  相似文献   

广州珠江西航道,流溪河有机污染特征与感潮作用   总被引：6，自引：3，他引：6  

王新明  闵育顺 《地球化学》1997,26(3):54-59

珠江西航道和流溪河在广州市区上游，为广州市主要水源区。由于感潮作用，受市区严重污染的水体因涨潮上溯而上游传输。严重影响上游水质。因此，弄清感潮作用对广州水源区水质的影响程度和范围，对水源保护与利用有重要意义。本研究从下游到上游，对水源区底泥中有机物特征进行了分析，结果表明：（１）从上游到上游，受感潮作用影响逐渐减小，污染程度逐渐减轻；（２）水源区有机物特征呈有规律变化。从靠近城市的下游到远离城市的  相似文献   

临沧超大型锗矿床有机质与锗矿化的地球化学特征   总被引：10，自引：3，他引：10  

庄汉平  刘金钟 《地球化学》1997,26(4):44-52,T002

临沧锗矿床是一产于第三系含煤岩系中的超大型矿床。矿床的最初锗源与盆地西缘的二云母花岗岩有关。主矿体产于下煤组沉积旋回的早期地层中，每一沉积阶段早期形成的褐煤和碳质泥岩中富含锗，最高含量达１４７０×１０＾－６。褐煤和碳质泥岩在矿化过程中平均富集了１６４－１６９倍。根据锗含量，褐煤和碳质泥岩可分为锗含量小于１２×１０＾－６的低锗煤（泥岩）和大于９０×１０＾－６的高锗煤（泥岩）。高锗煤中有机质富含氧官能  相似文献   

The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks   总被引：1，自引：0，他引：1  

Zhaoyun Wang  Keming Cheng 《中国科学D辑(英文版)》1997,40(3):232-238

The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion pressure during the high evolution stage. Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”.  相似文献