水合物地层低热固井水泥浆用相变微胶囊的制备及应用          下载免费PDF全文

杨国坤  汪爱明  尹舒婷  代天  刘天乐  蒋国盛 《探矿工程》2021,48(3):118-124

当深海固井遇到天然气水合物地层时,由于水泥浆水化放热,导致水合物的相变平衡条件发生改变,诱发水合物分解,引起二界面胶结质量下降等问题。为提高水合物地层固井质量,可向水泥浆中添加具有吸热控温作用的相变微胶囊,可有效降低固井水泥浆的水化升温。基于此,以配比石蜡为控温芯材、碳酸钙为壁材,利用自组装法制备了一种使用于深水水合物地层固井水泥浆控温微胶囊。由于固井水泥浆在达到水合物地层的过程中,外界温度环境复杂,单一相变温度的控温芯材极易失效。为扩展控温区间,选用切片石蜡与白油作为混合芯材,控温区间达到14.8~39.8 ℃。研究表明,该微胶囊表观形态良好、彼此无团聚,在热循环过程中,不易发生泄漏。与水泥浆复配后,对水泥浆流变性能无明显影响。在低掺加量时,微胶囊主要起降低水泥浆峰值温度的效果,并提升水泥石整体力学强度;高掺加量时,微胶囊既可以有效降低水泥浆峰值温度,也可以明显地延缓水泥浆放热速率。  相似文献   

物探技术在布敦乌拉隐伏矿产勘查中的应用效果     

刘永祥  刘福胜  王欣  韩晓阳  谢磊 《中国煤炭地质》2021,(3):60-63

内蒙古西乌珠穆沁旗布敦乌拉矿区多为第四系覆盖。在该矿区多金属勘查中,依据土壤地球化学圈定的矿化异常布置激电中梯测量,圈定1处激发极化率异常区,长度约890m,宽度约520m,位于已知断层F 1与推断断层F 2之间。采用可控源音频大地电磁测深剖面对该激电异常进行探测,解释视充电率多峰异常与反演电阻率高低跳跃对应区域为矿致异常区。通过钻探验证,发现银多金属矿床资源储量523.93万t,取得了良好的地质找矿效果。  相似文献   

Geological characteristics and ore genesis of Houfangzi graphite deposit in Northwestern Hebei Province     

ZHANG Xingkang  FAN Yupeng  JIN Song  JIA Zhenghai 《中国地质调查》2021,7(6):20-26

Houfangzi graphite deposit is located in the middle of the graphite metallogenic belt in the northern margin of North China Block in Hebei Province, which belongs to regional metamorphic type graphite deposit. In this paper, through rock-mineral determination, IP ladder sections and exploratory trench survey, the authors have discussed its metallogenic geological characteristics and ore body characteristics, and analyzed its ore genesis. The research results show that the ore bodies are mainly in the graphitic marble of Dongjingzi Formation of Hongqiyingzi Group, which are stratified and controlled by layers, with NE trend and NNW inclination. The IP anomaly shows that Houfangzi graphite deposit is characterized by low resistance and high polarization. Ore bodies are stable and of big scale, and their fixed carbon content ranges from 1.42% to 3.28%, which has the potential to be a large graphite deposit. The ore-forming material came from granulite and graphite marble, while the regional metamorphism is the main mineralization of Houfangzi graphite deposit, with the enrichment and increasement caused by late magmatic activity and migmatization.  相似文献   

CINRAD-SA双偏振雷达资料在降水估测中的应用初探   总被引：2，自引：0，他引：2  

陈超  胡志群  胡胜  张扬  李珊珊 《气象》2019,45(1):113-125

对基于水平反射率ZH和差分传播相移率K_(DP)的降水估测综合法R(C)进行了改进,并对广州S波段双偏振雷达2016年2次飑线和2次台风降水过程的Φ_(DP)使用小波分析进行滤波处理,在此基础上使用变距最小二乘法拟合得到K_(DP)的值。分别使用R(C)和R(Z_H)法对2次飑线和2次台风降水过程进行降水估算,将估算结果和雨量计小时雨量进行了对比,并将两种方法的评估结果进行了对比。结果表明:(1)对于飑线类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度要好于R(Z_H)法,且降水率越大,R(C)法优势越明显,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均相对误差(RE)降低了17. 2%,平均绝对误差(AE)减少了1.89 mm,平均均方根误差(RMSE)减少了1.66 mm;(2)对于台风类型降水,R(C)法对5 mm·h~(-1)以上的降水估测精度也好于R(Z_H)法,当降水率≥20 mm·h~(-1)时,两次过程R(C)法比R(Z_H)法的平均RE降低了33. 19%,平均AE减少了3. 95 mm,平均RMSE减少了4.05 mm;(3)对于飑线和台风两种类型降水R(C)法都明显改善了降水率较大时的R(Z_H)法低估问题,但R(C)法在降水率10 mm·h~(-1)时也存在低估,可能是由雨滴谱资料观测误差导致拟合的系数偏小或雷达硬件造成的观测偏差等造成的。  相似文献   

论直流激发极化法的视电阻率参数          下载免费PDF全文

赵聚林  涂明  冯军  王忠  吕旭红 《甘肃地质》2007,16(4):85-87

直流激发极化法,计算视电阻率的一次场采集于供电方波的末端时间,从而包含了被激发形成的二次场。在高极化率地质体上,得到的视电阻率将削弱其低阻特性或放大高阻特性。为此,建议在野外工作中,应对所采集的一次场作适当的处理后,再计算视电阻率,以降低这种影响。  相似文献   

A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater     

Jian Ma  Dongxing Yuan  Ying Liang  Minhan Dai 《Journal of Oceanography》2008,64(3):443-449

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.  相似文献   

IP电话应用的发展现状与趋势分析     

胡萍  黄永峰 《中国海洋大学学报(自然科学版)》2008,(Z1)

分析IP电话的国内外发展状况,探讨IP电话的发展趋势,研究中国政府及IP电话运营商应采用的应对策略,通过研究和分析,为IP电话下一步发展战略提供参考作用。  相似文献   

校园网IP地址绑定系统的研究与设计     

陈玉民  代成琴  王海洁 《中国海洋大学学报(自然科学版)》2008,(Z1)

IP地址绑定和IP用户管理是校园网管理员的主要工作,作者介绍哈尔滨工业大学校园网IP地址绑定和IP用户管理系统的设计思路及实现技术,该系统是采用J2EE技术和Struts+Hibernate框架实现的B/S结构WEB应用系统,用于校园网用户的IP地址分配I、P地址绑定及IP用户管理等方面。该系统的实现与应用大大提高了网络管理员的工作效率、避免了操作失误、改善了对用户的服务质量。  相似文献   

编队卫星InSAR系统的相位同步分析   总被引：1，自引：0，他引：1  

汤晓涛  楼良盛  刘志铭 《地球信息科学学报》2008,10(6):798-801

编队卫星InSAR系统属多基雷达系统,依靠编队卫星构型形成干涉所需的基线。一发多收工作模式下的编队卫星InSAR高程测量系统,协同工作的雷达间必须建立时间同步、相位同步和空间同步,其同步精度将影响InSAR系统的功能与性能。三大同步中,相位同步误差直接影响SAR复影像的相位误差,从而影响系统的高程测量精度。本文根据编队卫星条件下SAR成像的要求,对相位同步的要求进行了分析,并给出了由于相位不同步所引起的相位误差对InSAR高程测量精度影响。分析结果表明,编队卫星InSAR系统对于相位同步的要求包含两个方面:一是为保证被动雷达能够对回波实现相参成像,在整个合成孔径时间内,主动和被动两个雷达在载波相位上必须保持确定和可知的关系,且其差值随系统距离向分辨率的不同必须限定在一定范围内;二是在整个干涉数据的录取时间里,主动和被动两个雷达载波相位同步误差不能超过高程测量的精度要求所允许的误差。  相似文献   

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献