Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

GPS天线相位中心校正对GRACE卫星精密定轨的影响     

陈梦  孟瑞祖  袁俊军 《大地测量与地球动力学》2019,39(1):20-24

使用GRACE卫星星载GPS观测数据,研究地面获取的先验PCV模型和利用残差法估计的在轨PCV模型对低轨卫星精密定轨的影响,并采用GFZ精密轨道对比和SLR检核手段对其进行评估。结果表明,使用先验PCV模型会降低GRACE卫星定轨精度,相反利用在轨PCV模型可以提高定轨精度,提升数量级可达mm级。  相似文献   

基于数字全息显微的海洋浮游生物三维形貌快速重建方法研究     

王添  于佳  郭卜瑜  刘惠萍  王姣姣  王金城 《中国海洋大学学报(自然科学版)》2019,(2):121-127

针对海洋浮游生物实时探测中,三维形貌特征难以快速获取的问题,本文提出了一种海洋浮游生物三维形貌快速重建的方法。基于离轴菲涅尔数字全息显微系统,通过改进相位恢复方法预消除相位畸变,直接得到正确的相位信息,进而对浮游生物三维形貌重建。该方法不需要进行后期复杂的相位补偿计算,就可以对浮游生物三维形貌进行快速重建,有利于对动态、微小尺寸的浮游生物进行实时探测及分析。论文对青岛近海岸浮游生物桡足类和夜光虫进行了三维形貌重建,分辨率可达到3.5μm。实验结果为离轴菲涅尔数字全息显微系统用于海洋浮游生物原位、实时探测的可行性提供了依据。  相似文献   

BDS静态精密单点定位模糊度固定解精度分析     

徐宗秋  丁新展  徐彦田  唐龙江  李磊  胡艳阳 《测绘科学》2019,44(7):30-34

针对BDS单系统未校准相位延迟(UPD)估计以及不同时长精密单点定位(PPP)模糊度固定对定位精度影响的问题,该文选取56个测站估计UPD,利用未参与UPD计算的8个测站进行不同时长BDS静态PPP模糊度固定实验。结果表明:BDS星间单差宽巷和窄巷UPD在连续时段内具有一定的稳定性,其估计精度满足用于PPP模糊度固定要求。时长越短模糊度固定率越低。以IGS周解为参考值,不同时长模糊度固定解较浮点解三维定位精度均提高12%以上,时长越短模糊度固定解精度提高越显著。因此,模糊度固定是提高BDSPPP定位精度的重要手段。  相似文献   

GNSS全自动解算软件研发及精度评估     

杨翼飞  陈香萍 《地理空间信息》2019,17(4):25-28,I0002

根据载波相位差分定位技术,利用待定点周边稳定的CORS站网形成的区域误差改正模型,对待定控制点观测数据的噪声进行自动剔除,对电离层、对流层和多路径进行差分改正,研发GNSS全自动解算软件,并利用广西卫星定位基准站与待定控制点的GNSS观测数据对软件进行测试。结果表明,GNSS全自动解算软件具有较好的内外符合精度,其解算的三维坐标精度满足D级以下等级控制点的要求,可为工程测量应用提供新的自动化解算方案。  相似文献   

海洋石油管线探测多波束剖面声纳设计     

王继胜  郭元曦  桑恩方  徐小卡 《海洋工程》2007,25(3):78-82

针对海洋石油管线探测多波束剖面声纳的高速、大容量的实时信号处理任务,以及声纳系统进一步扩展的需求,设计并实现了一种基于IP网络互连的、以并行DSP为处理节点的多波束剖面声纳系统.该系统应用于海底石油管线探测与定位,系统中的每个处理节点与数据采集转换部分采用TCP/IP网络连接,可以通过物理上添加一个或多个处理节点成倍的提高系统的信号处理能力,而在软件上无须大的改动.通过电联调与水槽试验,验证了系统的可行性和稳定性,该设计为高速水声阵列信号实时处理系统提供了一种全新的解决思路.  相似文献   

GeoInterface——现实世界与网络世界的接口     

陈子悦  李满春  赵博 《测绘科学》2009,34(4)

IP(Internet protocol),就是一台固定/移动终端在登陆网络世界的身份证。而该终端所处的地理空间,则是其在现实世界的定位。那么,是否存在这样的一种方式,可以把现实世界与网络世界匹配起来呢?本文详细分析IP地址的分配方式以及IP地址与空间地理实体的各种对应方式。基于这些对应方式并在借鉴了国内外一些成功的数据库经验的基础上,提出了一种新的数据库建库方式—GeoInterface,探讨将现实世界中的地理坐标和网络空间中的虚拟地址进行匹配的可能性.。文中对GeoInterface的数据获取方式、实现手段以及数据库的建立和维护程序都做了较详细的说明。  相似文献   

基于小波变换的周跳探测与修复   总被引：2，自引：1，他引：1  

张金华  胡伍生 《测绘工程》2009,18(4):24-27

探测和修复周跳一直是GPS定位中的关键问题。利用小波变换对相位减伪距观测量进行周跳探测。首先介绍小波变换周跳探测的一般方法,然后在此基础上提出改进。改进方法可以对周跳进行探测和直接修复,进而探测和修复多次周跳,同时有效地克服一般方法可能出现探测失误的缺点。这种改进方法的效果在实验中得到验证。  相似文献   

改进的Hough变换在机场跑道检测中的应用   总被引：2，自引：0，他引：2  

王永刚  李二森  王忠丰  陈密密 《测绘科学》2009,34(6)

提出了一种改进的Hough变换方法用于机场跑道的检测。传统Hough变换存在计算量大等缺陷,本文利用直线边缘的梯度相位信息把Hough变换中θ的取值限定在一个较小的范围内,同时减少用于计算的像素点数,大大降低了计算量。通过实验证明了本文方法切实可行。  相似文献   

A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater     

Jian Ma  Dongxing Yuan  Ying Liang  Minhan Dai 《Journal of Oceanography》2008,64(3):443-449

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.  相似文献