三种类型烃-烃不混溶包裹体组合的特征和热力学条件的计算     

刘斌 《岩石学报》2005,21(5):1416-1424

在自然界广泛分布着烃-烃不混溶体系中捕获的流体包裹体,由于这些包裹体具有复杂的组成和相态,因此不混溶包裹体组合的判别和热力学参数的计算常常难以进行。根据烃-烃不混溶体系中两个端员组分流体包裹体室温下的相态特征和在温度-压力平面图上等容线交点显示的位置,划分成三种类型流体包裹体组合,本介绍了三种类型流体包裹体组合特征,叙述了不混溶烃-烃包裹体组合的测定和判别方法,并且阐述均一化包裹体相态方程和气-液平衡常数原理和方法与此同时列举了自然界简单的三种类型不混溶烃-烃包裹体组合的测定、判别和计算的几个实例,利用相态方程和气-液平衡常数,不但精确地计算出包裹体均一压力,并且精确地计算出流体密度和体积等热力学参数。最后,利用均一成气相和液相的两种包裹体在 p-T 平面图上等容线交点同样计算出流体包裹体组合的捕获温度和压力。  相似文献   

水气两相流系统K-S-P模型参数反演的最优估计   总被引：1，自引：0，他引：1       下载免费PDF全文

薛强  冯夏庭  梁冰  刘建军 《水科学进展》2005,16(4):488-493

应用渗流力学和参数反演辨识最优化理论,建立了水气两相流控制方程,给出了控制两相流系统K-S-P模型参数之间的本构关系,并对其中的相关参数进行数值反演辨识,得出待求参数的最优估计值。对不同质地土壤的实验测试值进行对比分析,其结果吻合较好,验证了模型的适定性和可靠性,解决了实验数据处理以及结果对初值的敏感性问题,并且该数值方法可通过多组初值参数进行数值实验,结合实验结果来满足实际工程的需求。这不仅对非饱和带内污染物传输、气藏工程试井计算、填埋气体的释放以及挥发性有机污染物的去污分析中两相流数值计算提供基础,而且对K-S-P本构关系之间参数的确定提供了可靠的理论依据。  相似文献   

单频GPS整周模糊度动态快速求解的研究   总被引：2，自引：1，他引：2  

刘立龙  刘基余  李光成 《武汉大学学报(信息科学版)》2005,30(10):885-887

提出了一种动态快速求解整周模糊度的方法,即先对系数阵进行QR分解,然后通过矩阵变换使模糊度参数和位置参数分离,从而降低矩阵的维数,满足实时动态求解的要求,最后应用LAMBDA方法搜索模糊度。为验证该算法,用单频GPS接收机进行了静态定位和动态定位两种试验。结果表明,静态定位误差小于1cm,动态定位误差小于3cm。由此可见,该方法能够为动态用户快速而精确地实施GPS单频动态定位。  相似文献   

裂隙型单斜介质中弹性系数的计算及波的传播特性研究   总被引：3，自引：1，他引：3  

王德利  何樵登 《吉林大学学报(地球科学版)》2002,32(2):181-186

根据Hudson等关于裂隙介质弹性系数计算的扰动理论及Bond变换矩阵原理，给出了各向同性介质中含多组垂直裂隙时等效弹性系数的计算方法。计算了含两组斜交的垂直裂隙形成的单斜各向异性介质中的等效弹性系数，并根据Christoffel方程推导、得出水平面内平面波传播的相速度和群速度随方位变化的特性。  相似文献   

An automated strategy for calculation of phase diagram sections and retrieval of rock properties as a function of physical conditions   总被引：9，自引：0，他引：9  

J. A. D. Connolly  K. Petrini 《Journal of Metamorphic Geology》2002,20(7):697-708

We formulate an algorithm for the calculation of stable phase relations of a system with constrained bulk composition as a function of its environmental variables. The basis of this algorithm is the approximate representation of the free energy composition surfaces of solution phases by inscribed polyhedra. This representation leads to discretization of high variance phase fields into a continuous mesh of smaller polygonal fields within which the composition and physical properties of the phases are uniquely determined. The resulting phase diagram sections are useful for understanding the phase relations of complex metamorphic systems and for applications in which it is necessary to establish the variations in rock properties such as density, seismic velocities and volatile‐content through a metamorphic cycle. The algorithm has been implemented within a computer program that is general with respect to both the choice of variables and the number of components and phases possible in a system, and is independent of the structure of the equations of state used to describe the phases of the system.  相似文献   

Gold Occurrence and Ore Genesis,Yata Micro—Disseminated Gold Deposit,Guizhou,Southwest China     

朱笑青  王中刚 《中国地球化学学报》2002,21(4):370-373

The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations.  相似文献   

Structure sismique du socle paléozoı̈que du bassin des Doukkala,Môle côtier,Maroc occidental. Indication en faveur de l'existence d'une phase éo-varisqueSeismic structure of the Doukkala basin,Palaeozoic basement,western Morocco: a hint for an Eovariscan fold-and-thrust belt     

Hassan Echarfaoui  Mohamed Hafid  Abdallah Aı̈t Salem 《Comptes Rendus Geoscience》2002,334(1):13-20

Seismic profiles and well data from the Doukkala basin unravel the structure of the Palaeozoic basement and suggest that this coastal zone of western Morocco was affected by a compressive phase during the Frasnian. This resulted in the formation of upright, plurikilometric folds associated with reverse faults (North Doukkala), and of asymmetrical folds associated with mostly west verging ramps (South Doukkala). Folding involved all pre-Upper Frasnian formations and caused partial or total hiatus of Upper Frasnian–Strunian strata. This event can be correlated with the orogenic phase reported from more internal domains of the Morocco Hercynian belt, where it is referred to as the ‘Bretonne’ or ‘Eovariscan’ phase. To cite this article: H. Echarfaoui et al., C. R. Geoscience 334 (2002) 13–20  相似文献   

Simulation of artificial random field considering the temporal-spatial variation     

倪永军  朱晞 《地震学报(英文版)》2002,15(4):425-430

Introduction For the seismic design of special structures such as nuclear power station, marine platform, long-span bridge and dam, generally the time-history response analysis of the structure under seismic excitation is imperative, which was coded in most seismic design codes. The earthquake records suitable for the seismic situation and site condition are necessary to be used as the seismic input in the dynamic analysis of structures. As a result of the limited observational condition of st…  相似文献   

Screening model for volatile pollutants in dual porosity soils     

Mohamed M. Hantush  Rao. S. Govindaraju  Miguel A. Marioand Zhonglong Zhang 《Journal of Hydrology》2002,260(1-4):58-74

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.  相似文献   

Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa     

Pierre Hudon  In-Ho Jung  Don R. Baker 《Physics of the Earth and Planetary Interiors》2002,130(3-4):159-174

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献