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51.
Twenty thousand metres of diamond drill core representing a 14 km cross-section from weakly to intensely altered Roxby Downs Granite through the Olympic Dam Breccia Complex, host to the Olympic Dam iron-oxide–copper–gold–uranium deposit in South Australia, was analysed using the HyLogger-3 spectral scanner. Thermal and shortwave infrared spectroscopy results from 30 drill holes provide insight into the spatial relationships between quartz, orthoclase–microcline, albite–oligoclase and progressively changing sericite and chlorite compositions. The relative proportions of quartz, feldspars and phyllosilicates were mapped with thermal infrared spectroscopy. Variations in the chemistry of sericite and chlorite were extracted by proxy from their shortwave infrared spectral response, together with their relative spatial distribution. HyLogger scanning has revealed four deposit-scale mineralogical trends, progressing from least-altered Roxby Downs Granite into mineralisation where most of the feldspar has been replaced by sericite + hematite + quartz: (1) a progressive Al–OH wavelength shift of 2205 nm to 2210 nm for sericite, followed by a spatially rapid reversal corresponding to lower phengite/muscovite abundance ratios; (2) progressive Mg/Fe–OH wavelength shift of 2248 nm to 2252 nm reflecting an increase in the Fe:Mg ratio of chlorite; (3) increasing ratio of microcline to orthoclase followed by a rapid decrease; and (4) slightly decreasing ratio of albite to oligoclase followed by plagioclase destruction prior to albite replacement by sericite. The HyLogger feldspar results support recent petrographic evidence for hydrothermal albite and K-feldspar at the Olympic Dam deposit, not previously reported. The spectral results from continuous HyLogger scans also show that the microscopic observations and proposed feldspar replacement reactions are not locally isolated phenomena, but are applicable at the deposit and regional-scale. A modified quartz–K-feldspar–plagioclase ternary diagram utilising mineralogy interpreted from HyLogger thermal infrared spectra (QAPTIR) diagram along with supporting data on the abundance ratios of orthoclase/microcline and albite/plagioclase, and the wavelength shifts in characteristic absorption features for sericite and chlorite, can be used as empirical vectors towards mineralisation within the Olympic Dam mineral system, with potential application to other IOCG ore-forming systems. Intrusion of Gairdner Dyke Swarm dolerite dykes into sericite ± hematite altered Roxby Downs Granite results in retrograde albite–chlorite–magnetite alteration envelopes (up to tens of metres thick) overprinting the original sericite ± hematite alteration zone and needs to be carefully evaluated to ensure that such areas are not falsely downgraded during exploration.  相似文献   
52.
在西藏班戈县德庆区纳木错西岸则弄群火山岩剖面中一段流纹质熔结凝灰岩岩石,西藏堆龙德庆县门堆乡帕那组火山岩剖面三段流纹质晶屑玻屑凝灰岩,以及西藏林周县强嘎乡帕那组火山岩剖面二段流纹质熔结凝灰岩中,发现了多硅白云母捕虏晶。多硅白云母捕虏晶的矿物成分分析结果显示其Si阳离子数为3.294~3.485,Al阳离子数为2.024~2.419,属于比较典型的高压/超高压岩石中常见的白云母。这一特征暗示早白垩世与始新世拉萨地块南北下地壳应该存在高压变质岩或发生过强烈构造挤压导致的高压变质作用。  相似文献   
53.
Ruby-bearing marbles from Nangimali, in the Azad-Kashmir, Pakistan, contain, besides phengite, different mica intergrowths: paragonite, phlogopite and aspidolite (sodium phlogopite). Both phlogopites, intimately linked and coexisting with paragonite, are fluorine rich, contrary to phengite and paragonite. F-enriched aspidolite is described for the first time. Phengite is either associated with phlogopite or could be isolated. The presence of aspidolite in the ruby-bearing marbles, together with other arguments such as salt solid inclusions and presence of anhydrite, suggest the implication of evaporites in the genesis of gem corundums. To cite this article: V. Garnier et al., C. R. Geoscience 336 (2004).  相似文献   
54.
Chemical data for 139 natural paragonite-muscovite (Pg-Ms) pairs illustrate the effects of ferromagnesian components on the P-T-X topology of the Pg-Ms solvus. The pairs were selected on the basis of: reasonably accurate knowledge of the P-T conditions of formation; evidence for close approach to equilibrium at peak metamorphic conditions; exclusion of pairs in which paragonite contains more than 5 mol% margarite; and exclusion of pairs from polymetamorphic rocks that contain more than one set of cogenetic Pg-Ms pairs. Graphical analysis reveals considerable scatter in the data; nevertheless, it is evident that the muscovite limb of the solvus shifts markedly toward end-member muscovite with increasing pressure from approximately 7 kbar to 21 kbar. This shift is attributed to a pressure-induced increase of the ferromagnesian content of muscovite, which increases the size of the XII alkali site - to the effect that K is more readily accommodated than Na. The data also suggest that the paragonite limb of the solvus migrates slightly toward end-member paragonite with increasing pressure. Broadening of the Pg-Ms solvus with increasing pressure reflects increasingly nonideal Na-K mixing as the phengite content of muscovite increases. Due to the wide scatter of data for Pg-phengitic-Ms pairs, it is concluded that, at the present time, Pg-Ms solvus thermometry is only viable for quasibinary Pg-Ms pairs.  相似文献   
55.
Is metamorphism and its causative tectonics best viewed as a series of punctuated events or as a continuum? This question is addressed through examination of the timing of exhumation of the Cycladic Blueschist Belt (CBB). The cause of scatter beyond analytical error in Rb–Sr geochronology was investigated using a suite of 39 phengite samples. Rb–Sr ages have been measured on phengite microsamples drilled from specific microstructures in thin sections of calcschists and metabasites from the CBB on Syros. The majority are from samples that have well‐preserved blueschist facies mineral assemblages with limited greenschist facies overprint. The peak metamorphic temperatures involved are below the closure temperature for white mica so that crystallization ages are expected to be preserved. This is supported by the coexistence of different ages in microstructures of different relative age; in one sample phengite from the dominant extensional blueschist facies fabric preserves an age of 35 Ma while post‐tectonic mica, millimetres away, has an age of 26 Ma. The results suggest that micro‐sampling techniques linked to detailed microstructural analysis are critical to understanding the timing and duration of deformation in tectonometamorphic systems. North of the Serpentinite Belt in northern Syros, phengite Rb–Sr ages are generally between 53 and 46 Ma, comparable to previous dates from this area. South of the Serpentinite Belt phengite in blueschist facies assemblages associated with extensional fabrics linked to exhumation have ages that range from 42 Ma down to c. 30 Ma indicating that extensional deformation while still under blueschist facies conditions continued until 30 Ma. No age measurements on samples with unambiguous evidence of deformation under greenschist facies conditions were made; two rocks with greenschist facies assemblages gave phengite ages that overlap with the younger blueschist samples, suggesting blueschist facies phengite is preserved in these rocks. Two samples yielded ages below 27 Ma; one is from a post‐tectonic microstructure, the other from a greenschist in which the fabric developed during earlier blueschist facies conditions. These ages are consistent with previous evidence of greenschist facies conditions from c. 25 Ma onwards. The data are consistent with a model of deformation that is continuous on a regional scale.  相似文献   
56.
苏鲁三清阁榴辉岩中柯石英的发现及其地质意义探讨   总被引:1,自引:0,他引:1  
在苏鲁三清阁多硅白云母榴辉岩中发现了柯石英包体,该榴辉岩与超高压含菱镁矿大理岩共生。石榴石中存在的柯石英残晶和多晶石英假相包体表明榴辉岩的变质压力超过2.8 GPa。运用石榴石–单斜辉石Fe2+–Mg温度计和多硅白云母压力计估算结果表明,矿物核部的平衡压力为3.1~3.5 GPa(T =650~689℃),边部的平衡压力为2.9~3.3 GPa(T=652~671℃)。与石榴石伴生的绿辉石普遍发育石英出溶结构。在磷灰石中观察到金属硫化物出溶体。磷灰石富含OH,F,Cl和S等挥发份,这些挥发性组分的深循环对地壳和地幔之间的相互作用研究具有重要意义。通过磷灰石,苏鲁—大别俯冲带能够将大量(~80 000 Mt)OH,F和Cl携带到地幔深处。  相似文献   
57.
We have estimated the timescale of material circulation in the Sanbagawa subduction zone based on U–Pb zircon and K–Ar phengite dating in the Ikeda district, central Shikoku. The Minawa and Koboke units are major constituents of the high‐P Sanbagawa metamorphic complex in Shikoku, southwest Japan. For the Minawa unit, ages of 92–81 Ma for the trench‐fill sediments, are indicated, whereas the age of ductile deformation and metamorphism of garnet and chlorite zones are 74–72 Ma and 65 Ma, respectively. Our results and occurrence of c. 150 Ma Besshi‐type deposits formed at mid‐ocean ridge suggest that the 60‐Myr‐old Izanagi Plate was subducted beneath the Eurasian Plate at c. 90 Ma, and this observation is consistent with recent plate reconstructions. For the Koboke unit, the depositional ages of the trench‐fill sediments and the dates for the termination of ductile deformation and metamorphism are estimated at c. 76–74 and 64–62 Ma, respectively. In the Ikeda district, the depositional ages generally become younger towards lower structural levels in the Sanbagawa metamorphic complex. Our results of U–Pb and K–Ar dating show that the circulation of material from the deposition of the Minawa and Koboke units at the trench through an active high‐P metamorphic domain to the final exhumation from the domain occurred continuously throughout c. 30 Myr (from c. 90 to 60 Ma).  相似文献   
58.
Blueschist-bearing Osayama serpentinite melange develops beneath a peridotite body of the Oeyama ophiolite which occupies the highest position structurally in the central Chugoku Mountains. The blueschist-facies tectonic blocks within the serpentinite melange are divided into the lawsonite–pumpellyite grade, lower epidote grade and higher epidote grade by the mineral assemblages of basic schists. The higher epidote-grade block is a garnet–glaucophane schist including eclogite-facies relic minerals and retrogressive lawsonite–pumpellyite-grade minerals. Gabbroic blocks derived from the Oeyama ophiolite are also enclosed as tectonic blocks in the serpentinite matrix and have experienced a blueschist metamorphism together with the other blueschist blocks. The mineralogic and paragenetic features of the Osayama blueschists are compatible with a hypothesis that they were derived from a coherent blueschist-facies metamorphic sequence, formed in a subduction zone with a low geothermal gradient (~ 10°C/km). Phengite K–Ar ages of 16 pelitic and one basic schists yield 289–327 Ma and concentrate around 320 Ma regardless of protolith and metamorphic grade, suggesting quick exhumation of the schists at ca 320 Ma. These petrologic and geochronologic features suggest that the Osayama blueschists comprise a low-grade portion of the Carboniferous Renge metamorphic belt. The Osayama blueschists indicate that the 'cold' subduction type (Franciscan type) metamorphism to reach eclogite-facies and subsequent quick exhumation took place in the northwestern Pacific margin in Carboniferous time, like some other circum-Pacific orogenic belts (western USA and eastern Australia), where such subduction metamorphism already started as early as the Ordovician.  相似文献   
59.
The multiple high‐pressure (HP), low‐temperature (LT) metamorphic units of Western and Central Anatolia offer a great opportunity to investigate the subduction‐ and continental accretion‐related evolution of the eastern limb of the long‐lived Aegean subduction system. Recent reports of the HP–LT index mineral Fe‐Mg‐carpholite in three metasedimentary units of the Gondwana‐derived Anatolide–Tauride continental block (namely the Afyon Zone, the Ören Unit and the southern Menderes Massif) suggest a more complicated scenario than the single‐continental accretion model generally put forward in previous studies. This study presents the first isotopic dates (white mica 40Ar–39Ar geochronology), and where possible are combined with PT estimates (chlorite thermometry, phengite barometry, multi‐equilibrium thermobarometry), on carpholite‐bearing rocks from these three HP–LT metasedimentary units. It is shown that, in the Afyon Zone, carpholite‐bearing assemblages were retrogressed through greenschist‐facies conditions at c. 67–62 Ma. Early retrograde stages in the Ören Unit are dated to 63–59 Ma. In the Kurudere–Nebiler Unit (HP Mesozoic cover of the southern Menderes Massif), HP retrograde stages are dated to c. 45 Ma, and post‐collisional cooling to c. 26 Ma. These new results support that the Ören Unit represents the westernmost continuation of the Afyon Zone, whereas the Kurudere–Nebiler Unit correlates with the Cycladic Blueschist Unit of the Aegean Domain. In Western Anatolia, three successive HP–LT metamorphic belts thus formed: the northernmost Tav?anl? Zone (c. 88–82 Ma), the Ören–Afyon Zone (between 70 and 65 Ma), and the Kurudere–Nebiler Unit (c. 52–45 Ma). The southward younging trend of the HP–LT metamorphism from the upper and internal to the deeper and more external structural units, as in the Aegean Domain, points to the persistence of subduction in Western Anatolia between 93–90 and c. 35 Ma. After the accretion of the Menderes–Tauride terrane, in Eocene times, subduction stopped, leading to continental collision and associated Barrovian‐type metamorphism. Because, by contrast, the Aegean subduction did remain active due to slab roll‐back and trench migration, the eastern limb (below Southwestern Anatolia) of the Hellenic slab was dramatically curved and consequently teared. It therefore is suggested that the possibility for subduction to continue after the accretion of buoyant (e.g. continental) terranes probably depends much on palaeogeography.  相似文献   
60.
In the lower main unit of the Attic‐Cycladic crystalline belt (Greece), white mica geochronology (Rb–Sr, K–Ar, 40Ar–39Ar) has established the timing of at least two metamorphic events: well‐preserved high‐pressure/low‐temperature (HP/LT) rocks yielded Eocene ages (c. 53–40 Ma) and their greenschist facies counterparts provided Oligocene–Miocene dates (c. 25–18 Ma). Marbles from Tinos Island contain high‐Si phengite with Rb–Sr (phengite–calcite) and 40Ar–39Ar white mica ages between 41 and 24 Ma. All Ar age spectra are disturbed and 40Ar–39Ar total fusion ages generally are 3–6 Ma older than corresponding Rb–Sr ages. Due to the polymetamorphic history, we consider inheritance from the HP stage as the most likely cause for the complex Ar age spectra and the older 40Ar–39Ar dates. This concept also suggests that the Rb–Sr system is more sensitive to modification during overprinting than the Ar isotope system, because resetting of the Sr isotope system can be accomplished more quickly by Sr exchange with other Ca‐rich phases, whereas lack of pervasive deformation and/or restricted availability of synmetamorphic fluids has favoured partial inheritance of the Ar isotope system. On Tinos, the lowermost part of the metamorphic succession has experienced a pervasive greenschist facies overprint. Si‐rich phengite from marbles representing this lithostratigraphic level yielded Rb–Sr ages of c. 24 Ma. If the earlier metamorphic history is not taken into account, such data sets may lead to the erroneous conclusion of Miocene HP metamorphism. This study indicates that this phengite experienced pervasive rejuvenation of the Rb–Sr isotope system during overprinting, without significant changes in Si content, due to bulk‐compositional constraints. This leads to the conclusion that in the absence of critical mineral assemblages the Si value of phengite is not a reliable indicator for metamorphic pressures in impure marbles. Recent studies have reported large displacements (>100 km) for detachment faults in the Aegean Sea. A critical parameter for such models is the age of HP metamorphism as deduced from white mica dating in the basal units of the Cyclades. We question the underlying idea of Miocene HP metamorphism and suggest, instead, that this age constrains the timing of the greenschist facies overprint and that the existence of mega‐detachments in the study area requires further investigation.  相似文献   
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