多金属结核中二氧化锰的测定   总被引：1，自引：0，他引：1  

夏月莲  毛海燕 《岩矿测试》1997,16(3):177-179

用过量的含有Ｈ２ＳＯ４的（ＮＨ４）２Ｆｅ（ＳＯ４）２溶液分解多金属结核的同时，还原了试样中的ＭｎＯ２，然后以Ｋ２Ｃｒ２Ｏ７标准溶液滴定测定了多金属结核中的ＭｎＯ２。就样品分解过程中的加热温度和时间对测定结果的影响及标准溶液的标定等问题进行了讨论，经多次测定，方法重现性好。应用此方法为新研制的多金属结核标准物质提供了ＭｎＯ２的定值数据，其结果与初定值相符，无剔除值，精密度（ＲＳＤ，ｎ＝８）小于０６％。  相似文献   

绵阳地区白垩系岩石风化过程的生态效应   总被引：1，自引：0，他引：1  

任杰  贾滨洋  李正积 《四川地质学报》1996,(4)

论述了四川绵阳地区白垩系七曲寺组砂岩、泥岩风化过程的信息动态及其对森林植被的生态效应，为长江上游水土保持防护林提供开发信息。  相似文献   

西菲律宾海沉积物稀土元素地球化学   总被引：7，自引：0，他引：7  

石学法  马建国 《矿物学报》1996,16(3):260-267

对取自西菲律宾海区3个沉积物柱样（WP1、WP2和WP40）的32个样品的稀土元素（REE）地球化学行为进行了系统的研究。区内沉积物表现出以下特征：①稀土元素含量及总量（ZREE）较低，WP1、WP2和WP40孔的ΣREE依次为72．91×10－6，54．15×10－6和54．18×10－6，REE在粘土粒级中得到了较大富集；②REE球粒陨石标准化的分布模式曲线表现为负斜率，富集轻稀土，WP1、WP2和WP40孔LREE／HREE比值平均值为37．36，26．33和17．16，页岩标准化曲线大致呈水平；③与球粒陨石和页岩相比，Ce都表现为强烈的亏损；以球粒陨石为标准，WP40孔表现为弱的Eu正异常，其他两孔表现为弱的Eu负异常；以页岩为标准，皆显示Eu正异常；④ΣREE纵向变化曲线与CaCO3旋回曲线有良好的对应关系。上述特征表明：①沉积物的来源复杂，有陆源、火山源、生物源和自生源，在所研究的三个孔中，WP1孔含有较多的陆源物质，WP2和WP40含有较多的火山物质；②被粘土吸附是本区REE重要的存在形式；③沉积物形成环境为氧化条件；④据ΣREE的纵向变化曲线与CaCO3旋回曲线，将本区沉积物自下而上划分为末次冰期亚间冰期沉积、冰期最盛期沉积和全新世沉积。  相似文献   

华南-古岩溶型铀矿床中有机质的热成熟异常及其矿床成因意义     

闽茂中  张祖还  刘兰忠 《矿床地质》1996,15(1):64-70

华南某层控铀矿床中有机质可分为原生沉积型、热液变质型和运移型三种类型，其母质类型为腐泥－腐殖型，主要来源于海相微体生物、藻类及少量源于陆相高等植物。根据镜质体反射率、饱和烃气相色谱和某些地球化学指标，表明矿石中有机质呈现异常热成熟特征，这对揭示该矿床热水叠造成矿机制具有指纹意义。本文还首次合理解释矿石中铀与有机碳含量间复杂关系的原因。  相似文献   

Geochemistry of the Jinman Vein—Type Copper Deposit,Western Yunnan Province,China——I.Element Geochemical Characteristics   总被引：3，自引：0，他引：3  

季宏兵  李朝阳 《中国地球化学学报》1996,15(2):172-184

The Jinman copper deposit,which is situated on the northern margin of the Lanping-Simao back-arc basin,western Yunnan Province,is a silver-bearing,high-grade vein-type copper deposit.Comprehensive element geochemical studies of the host rocks and hydrothermal minerals revealed the regularities in the distribution,mobilization and transport of elements from the host rocks to hydrothermal minerals.In conjunction with the fluid inclusion and isotope data,it is suggested that the ore-forming fluid was derived mainly from a deep source characterized by CO2 enrichment and reduction in nature.It is also suggested that the oreforming materials come largely from a deep source.although the contribution of the country rocks should not be ruled out.It is also found that some hydrothermal minerals are possessed of MREE-enrichment patterns.It is deduced that the REEs in the deep-source ore fluid were transported in the form of CO3^2- complexes and were deposited in a continental basin(or a hot-spring basin).  相似文献   

锚喷材料经时蠕变损伤本构方程   总被引：1，自引：0，他引：1  

李永和  葛修润 《岩土力学》1997,18(4):8-12

从以应力，湿度，温度和损伤诸函数的时间积分表示和自由能涵函出发，根据非平衡热力学定律，同时考虑了喷射混凝土老化效应及骨料因素，给出了锚喷材料损伤蠕变本构方程和损伤演化方程，养护时间及蠕变有效作用应力的定义，并用实验结果验证了该理论。  相似文献   

Suction-controlled experiments on Boom clay     

F. Bernier  G. Volckaert  E. Alonso  M. Villar 《Engineering Geology》1997,47(4):135-338

The understanding of the thermo-hydro-mechanical behaviour of a clay barrier is needed for the prediction of its final in situ properties after the hydration and thermal transient in a radioactive waste repository.

As part of the CEC 1990–1994 R&D programme on radioactive waste management and storage, the CEA (Fr), CIEMAT (Sp), ENRESA (Sp), SCK · CEN (B), UPC (Sp) and UWCC (UK) have carried out a joint project on unsaturated clay behaviour (Volckaert et al., 1996). The aim of the study is to analyse and model the behaviour of a clay-based engineered barrier during its hydration phase under real repository conditions. The hydro-mechanical and thermo-hydraulic models developed in this project have been coupled to describe stress/strain behaviour, moisture migration and heat transfer. A thermo-hydraulic model has also been coupled to a geochemical code to describe the migration and formation of chemical species.

In this project, suction-controlled experiments have been performed on Boom clay (B), FoCa clay (Fr) and Almeria bentonite (Sp). The aim of these experiments is to test the validity of the interpretive model developed by Alonso and Gens (Alonso et al., 1990), and to build a database of unsaturated clay thermo-hydro-mechanical parameters. Such a database can then be used for validation exercises in which in situ experiments are simulated.

The Boom clay is a moderately swelling clay of Rupellian age. It is studied at the SCK · CEN in Belgium as a potential host rock for a radioactive waste repository. In this paper, suction-controlled experiments carried out on Boom clay by SCK · CEN are described. SCK · CEN has performed experiments to measure the relation between suction, water content and temperature and the relation between suction, stress and deformation. The applied suction-control techniques and experimental setups are detailed. The results of these experiments are discussed in the perspective of the model of Alonso and Gens. The influence of temperature on water uptake was rather small. The measured swelling-collapse behaviour can be explained by the Alonso and Gens model.  相似文献   

旋喷固结体的物理力学性状研究     

周勇  徐进 《地质灾害与环境保护》1997,(3)

通过单轴抗压试验、剪切试验、变形试验及渗透性试验等方法，对旋喷固结体的物理力学性状和渗透性进行了研究。结果表明：旋喷固结体具有良好的物理力学性质和较低的渗透性，可完全改变天然土的性质。  相似文献   

一种新型自动开槽机及其控制     

靳建刚  王丽红 《中国煤田地质》2004,16(5):60-62

针对棒、管料开槽的问题，提出了一种新型全自动开槽机。介绍了该开槽机的结构和工作原理，建立全自动开槽机相适应的液压系统，搭建了开槽机继电器——控制器控制电路，实现了该设备的全自动过程控制。  相似文献   

多孔介质非饱和导水率预测的分形模型   总被引：6，自引：0，他引：6       下载免费PDF全文

刘建国  王洪涛  聂永丰 《水科学进展》2004,15(3):269-275

多孔介质非饱和导水率是地下水污染预测与评价的重要参数。根据分形几何的基本原理和方法,推导出了与Campbell经验公式在形式上完全一致的多孔介质非饱和导水率的预测公式。公式中的幂指数为介质孔隙分维和随机行走分维的函数,分别体现了多孔介质的静态性质与动态性质对其中水分运动的影响,但静态性质的影响是主要的,即导水率主要受多孔介质的结构控制。根据文献中报道的大量数据,利用笔者推导的预测公式计算得到的幂指数的统计值与试验测定的幂指数的统计值基本一致,说明推导的理论公式预测多孔介质非饱和导水率是较为可靠的。  相似文献