湘中锡矿山锑矿床成矿物质来源的同位素示踪   总被引：14，自引：0，他引：14  

彭建堂  胡瑞忠  邹利群  刘建雄 《矿物学报》2002,22(2):155-159

本文利用放射成因同位素（Pb、Sr)和轻稳定同位素（C、O）对锡矿山超大型锑矿床的成矿物质来源进行了示踪，从物源角度揭示了其在规模成矿、元素发生超常富集的原因。研究表明，锡矿山锑矿床的成矿物质不可能是来自赋矿围岩；深部地幔和基底都卷入了该矿的成矿作用；富Sb的交代型地幔和富Sb的元古界基底为其大规模成矿提供了充足的矿源，两者是形成锡成山超大型锑矿床的前提条件。  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Determining Q of near-surface materials from Rayleigh waves     

Jianghai Xia  Richard D. Miller  Choon B. Park  Gang Tian 《Journal of Applied Geophysics》2002,51(2-4)

High-frequency (≥2 Hz) Rayleigh wave phase velocities can be inverted to shear (S)-wave velocities for a layered earth model up to 30 m below the ground surface in many settings. Given S-wave velocity (V_S), compressional (P)-wave velocity (V_P), and Rayleigh wave phase velocities, it is feasible to solve for P-wave quality factor Q_P and S-wave quality factor Q_S in a layered earth model by inverting Rayleigh wave attenuation coefficients. Model results demonstrate the plausibility of inverting Q_S from Rayleigh wave attenuation coefficients. Contributions to the Rayleigh wave attenuation coefficients from Q_P cannot be ignored when Vs/V_P reaches 0.45, which is not uncommon in near-surface settings. It is possible to invert Q_P from Rayleigh wave attenuation coefficients in some geological setting, a concept that differs from the common perception that Rayleigh wave attenuation coefficients are always far less sensitive to Q_P than to Q_S. Sixty-channel surface wave data were acquired in an Arizona desert. For a 10-layer model with a thickness of over 20 m, the data were first inverted to obtain S-wave velocities by the multichannel analysis of surface waves (MASW) method and then quality factors were determined by inverting attenuation coefficients.  相似文献   

红板岩材料隐式本构模型的建立及其应用研究     

邹光华  朱建明 《工程地质学报》2003,11(3):258-262

针对红板岩材料在岩土工程中所表现的大量模糊的和不确定的因素等特点,基于人工神经网络的学习能力,借助于室内岩石力学试验,进行了对该材料的力学本构特性进行了神经网络模拟研究,提出了隐式本构模型的思想和方法,并通过该方法对该岩石的流变试验结果进行学习,获得了以网络权值结构保存的力学特性知识,由此得到了表征红板岩应力应变本构关系的隐式本构模型。应用结果表明,该方法对岩土类材料本构关系的模拟研究具有很好的应用前景。  相似文献   

地下管线探测工程的资料自动化整理   总被引：1，自引：0，他引：1  

阎金梅 《化工矿产地质》2003,25(4):240-242,250

地下管线探测工程一般分为野外探测和室内资料整理两阶段。内业整理包括成果表的编制、管线综合分布平面图和管线数据库。由于管线探测工程数据多,为了充分利用外业探测成果,应用Visual Basic 6.0(VB6)开发了一套地下管线管理信息系统(UTMIS),该系统实现了地下管线探测工程内业整理的自动化,极大地提高了工作效率数据精确度。  相似文献   

A Metallogenic Model of Gold Deposits of the Jiaodong Granite-Greenstone Belt   总被引：34，自引：0，他引：34  

DENG Jun  YANG Liqiang  SUN Zhongshi  WANG Jianping  WANG QingfeiXIN Hongbo  LI Xinjun Key Laboratory of Lithospheric Tectonics  Exploration. China University of Geosciences  Ministry of Education  Beijing  Institute of Geology  Geophysics  Chinese Academy of Sciences  Beijing Faculty of Earth Sciences  Jilin University  Changchun  Jilin 《《地质学报》英文版》2003,77(4):537-546

An analysis of trace elements and isotopic geochemistry suggest that the ore-forming materials of gold deposits in the Jiaodong granite-greenstone belt have multiple sources, especially the mantle source. Seismic wave, magnetic and gravity fields show that the crust-mantle structure and its coupling mechanism are the fundamental dynamic causes for the exchange and accumulation of materials and energy in the metallogenic system. Considering the evolution history of the structural setting, the tectono-metallogenic dynamics model of the area can be summarized as follows: (1) occurrence of the greenstone belt during the Archean-Proterozoic-the embryonic form of Au-source system; (2) stable tectonic setting in the Paleozoic-an intermittence in gold mineralization; (3) intensive activation and reformation of the greenstone belt in the Mesozoic-tectono-mineralization and tectono-diagensis; (4) posthumous structural activity in the Cenozoic-destruction of orebodies in the later stage. In the middle and late Ind  相似文献   

多孔结构矿物（岩石）及其环境修复材料的实用性   总被引：12，自引：1，他引：12       下载免费PDF全文

尹琳 陆现彩胡欢  赵连泽赵波 《岩石矿物学杂志》2003,22(4):405-408

具有多孔结构的矿物(岩石)作为一类特殊的工业原材料，在环境修复领域的应用前景正在成为研究热点。本文从微孔的尺度、结构、形态、成分等表面固体特征出发，概括性地论述了凹凸棒石、海泡石、蒙脱石、沸石、硅藻土等十几种多孔结构矿物(岩石)在环境修复工程中用作过滤材料、吸附剂、离子交换剂和催化剂等材料时的基本特征和使用时应注意的问题。  相似文献   

Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses   总被引：9，自引：0，他引：9  

Stephen M. Eggins 《Geostandards and Geoanalytical Research》2003,27(2):147-162

A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis.  相似文献   

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1     

William J. Chazey III  Clive R. Neal  Jinesh C. Jain  William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).  相似文献   

Generalized Coarse Graining Procedures for Flow in Porous Media     

Sabine Attinger 《Computational Geosciences》2003,7(4):253-273

This paper focuses on heterogeneous soil conductivities and on the impact their resolution has on a solution of the piezometric head equation: owing to spatial variations of the conductivity, the flow properties at larger scales differ from those found for experiments performed at smaller scales. The method of coarse graining is proposed in order to upscale the piezometric head equation on arbitrary intermediate scales. At intermediate scales large scale fluctuations of the conductivities are resolved, whereas small scale fluctuations are smoothed by a partialy spatial filtering procedure. The filtering procedure is performed in Fourier space with the aid of a low-frequency cut-off function. We derive the partially upscaled head equations. In these equations, the impact of the small scale variability is modeled by scale dependent effective conductivities which are determined by additional differential equations. Explicit results for the scale dependent conductivity values are presented in lowest order perturbation theory. The perturbation theory contributions are summed up with using a renormalisation group analysis yielding explicit results for the effective conductivity in isotropic media. Therefore, the results are also valid for highly heterogeneous media. The results are compared with numerical simulations performed by Dykaar and Kitanidis (1992). The method of coarse graining combined by a renormalisation group analysis offers a tool to derive exact and explicit expressions for resolution dependent conductivity values. It is, e.g., relevant for the interpretation of measurement data on different scales and for reduction of grid-block resolution in numerical modeling. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献