GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物   总被引：2，自引：2，他引：2  

何淼  饶竹  苏劲  黄毅 《岩矿测试》2007,26(2):101-104

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。  相似文献   

地幔流体的交代作用——来自碱性正长岩及其深源岩石包体的证据   总被引：2，自引：0，他引：2  

宋祥峰  刘显凡陶专卢秋霞  龙训荣 《岩石矿物学杂志》2007,26(4):310-314

滇西玉龙县小桥头硅化霓辉正长斑岩中,含有较多镁铁-超镁铁质深源包体岩石。经岩相学和电子探针及扫描电镜分析发现,伴随交代蚀变,寄主岩和各类镁铁-超镁铁质包体岩石中,普遍发育沿粒间和矿物晶体裂隙或解理纹贯入或穿插的黑色不透明物质,主要由微晶硅酸盐矿物和磁铁矿组成。本文研究认为,硅酸盐矿物与磁铁矿在背散射电子图像中表现为熔离特征,这种在透光显微镜下呈黑色不透明的微晶固体,是引发交代蚀变、具熔浆流体特点和超临界流体性质的地幔流体交代作用的一种微观表现。  相似文献   

凯里-麻江地区油苗与固体沥青的油源分析   总被引：15，自引：0，他引：15       下载免费PDF全文

张渠腾格尔  张志荣秦建中 《地质学报》2007,81(8):1118-1124

对黔南坳陷典型古油藏、残余油气藏的精细解剖对南方海相碳酸盐岩层系油气勘探研究具有重要意义。本文运用碳同位素、饱和烃色谱、饱和烃色质及芳烃色质等技术,对黔东南地区二叠系—寒武系油苗与固体沥青进行了地球化学特征研究和油源分析。研究表明,凯里地区虎庄47井原油、洛棉志留系砂岩油苗和麻江地区奥陶系红花园组固体沥青三者同源,主要来自下寒武统牛蹄塘组的优质烃源岩。而麻江地区早二叠世茅口组油苗与虎庄47井原油明显不同,主要源于下二叠统栖霞组的优质烃源岩。  相似文献   

Evaluation of Simultaneous Analyte Leaching/Vapour Phase Introduction for Direct Osmium Isotope Ratio Measurements in Solid Samples by Double-Focusing Sector Field ICP-MS     

Ilia Rodushkin  Emma Engström  Douglas C. Baxter 《Geostandards and Geoanalytical Research》2007,31(1):27-38

The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g^?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of ¹⁸⁷ Os/¹⁸⁸Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate ¹⁸⁷ Os/¹⁸⁸ Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g^?1 to > 100 ng g^?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations.  相似文献   

A computational method for approximating a Darcy–Stokes system governing a vuggy porous medium     

Todd Arbogast  Dana S. Brunson 《Computational Geosciences》2007,11(3):207-218

We develop and analyze a mixed finite element method for the solution of an elliptic system modeling a porous medium with large cavities, called vugs. It consists of a second-order elliptic (i.e., Darcy) equation on part of the domain coupled to a Stokes equation on the rest of the domain, and a slip boundary condition (due to Beavers–Joseph–Saffman) on the interface between them. The tangential velocity is not continuous on the interface. We consider a 2-D vuggy porous medium with many small cavities throughout its extent, so the interface is not isolated. We use a certain conforming Stokes element on rectangles, slightly modified near the interface to account for the tangential discontinuity. This gives a mixed finite element method for the entire Darcy–Stokes system with a regular sparsity pattern that is easy to implement, independent of the vug geometry, as long as it aligns with the grid. We prove optimal global first-order L ² convergence of the velocity and pressure, as well as the velocity gradient in the Stokes domain. Numerical results verify these rates of convergence and even suggest somewhat better convergence in certain situations. Finally, we present a lower dimensional space that uses Raviart–Thomas elements in the Darcy domain and uses our new modified elements near the interface in transition to the Stokes elements.  相似文献   

中国城市固体废弃物甲烷排放研究   总被引：2，自引：0，他引：2  

高庆先  杜吴鹏  卢士庆  Zhang Zhigang  Zhang Enchen  Wu Jianguo  Ren Zhenhai 《气候变化研究进展》2007,3(Z1):70-74

The greenhouse effect of methane (CH4) is only inferior to that of carbon dioxide (CO2). As an important anthropogenic emission source, the calculation of the emission amount of CH4 from waste treatment in landfills plays an important role in compiling greenhouse gases inventory and in estimating the climate change effects caused by increasing of greenhouse gases. Based on the previous work, and according to the sampling and analysis on municipal solid waste (MSW) in typical cities, the degradable organic carbon (DOC) percentile was identified in typical cities in recent years. According to the IPCC greenhouse gases inventory guideline and default method of CH4 emission from MSW landfills, and in light of MSW managing situation in different regions, the amount of CH4 emission was calculated. The results show that the amount of CH4 emission decreases geographically from east to west and it increases temporally from 1994 to 2004 in China.  相似文献   

采用复合单元法模拟裂隙多孔介质变饱和流动     

侯晓萍  陈胜宏 《岩土力学》2020,41(4):1437-1446

采用复合单元法建立了模拟裂隙多孔介质变饱和流动的数值模型。该模型具有以下特点：裂隙不需要离散成特定单元，而是根据几何位置插入到孔隙基质单元中形成复合单元；在复合单元中，分别建立裂隙流和孔隙基质流的计算方程，二者通过裂隙?基质界面产生联系并整合成复合单元方程；复合单元方程具有和常规有限单元方程相同的格式，因此，可以使用常规有限单元方程的求解技术。采用欠松弛迭代、集中质量矩阵以及自适应时步调节等技术，开发了裂隙多孔介质变饱和流动计算程序。通过模拟一维干土入渗和复杂裂隙含水层内的流动问题，验证了该模型的合理性和适用性。模拟结果为进一步认识非饱和裂隙含水层地下水流动特性提供了理论依据。  相似文献   

Comparison of Galerkin-type discretization techniques for two-phase flow in heterogeneous porous media   总被引：1，自引：0，他引：1  

Rainer Helmig  Ralf Huber 《Advances in water resources》1998,21(8):545

A comparison of Standard Galerkin, Petrov-Galerkin, and Fully-Upwind Galerkin methods for the simulation of two-phase flow in heterogeneous porous media is presented. On the basis of the coupled pressure-saturation equations, a generalized formulation for all three finite element methods is derived and analysed. For flow in homogeneous media, the Petrov-Galerkin method gives excellent results. But this method fails miserably for problems with heterogeneous media. This is because it is not able to capture correctly processes that take place at interfaces when, for instance, the capillary pressure-saturation relationship after Brooks and Corey is assumed. The Fully-Upwind Galerkin method is superior to the Petrov-Galerkin approach because it is able to give correct results for flow in homogeneous and heterogeneous media for the two models of van Genuchten and Brooks-Corey. The widely used formulation which is correct for the homogeneous case cannot be used for heterogeneous media. Instead the straightforward approach of gradp_c in combination with a chord-slope technique must be utilized.  相似文献   

全球水分布和气压变化对固体地球质心位置的影响   总被引：2，自引：0，他引：2  

周旭华 《天文学报》1998,39(1):61-66

根据IERS决议,国际地球参考系的原点是地球固体部分、海洋和大气的共同质量中心因此,地球上流体部分质量分布变化会改变固体地球质心相对于国际地球参考系原点的位置变化．空间技术如SLR和GPS的观测结果表明,固体地球质心可能有幅度达10毫米的位置变化,所以给出固体地球质心位置变化以及地球物理原因已成为重要问题.本文采用了全球4000多个地面气象台站从1949到1982年的月平均降水、温度和气压值,对水和大气的分布变化引起的固体地球质心位置变化进行了计算,得出水储量分布变化对固体地球质心运动比气压分布变化有更大的贡献,固体地球质心位置变化的最大值可达4毫米．  相似文献   

Velocities of elastic waves andv P/v S ratios in dry and water-saturated rock samples at high pressure     

M. P. Volarovich  V. A. Budnikov 《Pure and Applied Geophysics》1978,117(4):795-805

Elastic wave velocities and the ratiov _P/v _S were studied for dry and initially saturated samples of carbonate and crystalline rocks at pressures to 2 kbar. In initially saturated samplesv _P increases in crystalline rock, whereas in sedimentary rock it may either increase or decrease with increasing pressure. Under the same conditionsv _S remains approximately constant in crystalline rocks and decreases in sedimentary samples. The ratiov _P/v _S as a function of pressure increases in dry rocks and decreases in saturated ones. Saturated samples always have higherv _P/v _S ratios than dry ones. It appears that the geometry of the pore space influences the acoustic properties of saturated crystalline rocks.  相似文献