电感耦合等离子体质谱法(ICP-MS)测定水系沉积物中的铌钽锆铪   总被引：1，自引：0，他引：1  

胡家祯  于亚辉  吴娣  李小辉  吴葆存  刘春霞  钟盼 《矿产与地质》2016,(4):699-702

建立电感耦合等离子体质谱法(ICP-MS)测定水系沉积物中铌、钽、锆、铪四种元素的分析方法。将样品与氢氧化钠、过氧化钠混合物放入高温炉中,熔融分解完全,用热水提取,过滤后弃去滤液,将滤纸及沉淀用酒石酸-盐酸溶液溶解,稀释至刻度测定。方法检出限(3s)为:LD(Nb)=0.08μg/g,LD(Ta)=0.04μg/g,LD(Zr)=0.5μg/g,LD(Hf)=0.04μg/g,精密度(RSD%,n=6)为:0.84%~4.21%。该测定方法具有灵敏度高、精密度好、分析速度快、线性范围宽、操作性强等优势。采用该方法对国家一级标准物质进行测定表明,其结果与标准值吻合。此方法已在实际地质调查样品分析中得到应用。  相似文献   

显微荧光光谱技术在油气成藏研究中的应用——以塔里木盆地巴什托上古生界油气藏为例     

孙守亮  郭巍  李永飞  苏飞 《世界地质》2016,35(1):173-183

根据原油在紫外光的激发下产生荧光的特点,通过显微荧光光谱方法,对有机包裹体的荧光光谱进行定量化分析,利用其主峰波长与荧光强度、主峰波长与红/绿商的相关性,对塔里木盆地巴什托上古生界油气藏的成藏特征进行了初步研究。在研究区所采集的32块岩石样品中共获得64个荧光光谱数据。分析结果表明,巴什托上古生界油气藏存在3个油源,其主峰波长主要集中在439~443nm、469~472 nm和498~503 nm三个值段上,且为不同演化阶段的混源充注。前两者来自于寒武—奥陶系烃源岩,由下至上充注成藏;后一油源来自于石炭系巴楚组,随演化程度的变化同时向上、下两个方向充注。综合同期捕获不同主峰波长的有机包裹体,推测研究区至少存在4期油充注、1期天然气充注。  相似文献   

高压下天然菱铁矿的压缩性和电子结构研究     

高静  巫翔  秦善  张硕  杨科  李晓东 《岩石矿物学杂志》2016,35(2):276-282

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。  相似文献   

CO₂加富对塔玛亚历山大藻叶绿素荧光参数及产毒的影响   总被引：2，自引：2，他引：0  

徐金涛  庞敏  马新  毛雪薇  吴振兴  陈洪举  王燕  张学雷 《海洋与湖沼》2016,47(3):557-563

由大气中CO_2浓度升高引起的海洋酸化,是全球性的重大环境问题之一。本研究采用实验生态学的方法,以塔玛亚历山大藻(Alexandrium tamarense)为研究对象,分析其在CO_2加富条件下叶绿素荧光动力学参数及产毒特征的变化。调制叶绿素荧光结果显示,CO_2加富对塔玛亚历山大藻的PSⅡ最大光化学量子产量(Fv/Fm)、最大相对电子传递效率(r ETRmax)有显著影响(P0.05),且随着培养时间的增长Fv/Fm、r ETRmax均降低,对半饱和光强(Ik)、快速光曲线初始斜率(α)却无显著影响(P0.05)。结果说明CO_2加富能促进塔玛亚历山大藻的PSⅡ最大光化学量子产量,提高其最大光能转换效率和相对最大电子传递效率。高效液相色谱法分析结果显示,该株塔玛亚历山大藻主要产漆沟藻毒素1(GTX1)、漆沟藻毒素4(GTX4)、N-磺酰氨甲酰基毒素(C1)及N-磺酰氨甲酰基毒素(C2)四种PSTs毒素,CO_2加富不改变主要麻痹性贝毒(PSTs)的种类组成,但能显著提高氨基甲酸酯类毒素(GTX1、GTX4)产量(P0.05),而降低N-磺酰氨甲酰基类毒素(C1、C2)产量(P0.05),说明加富能使塔玛亚历山大藻所产毒素发生转化,进而影响藻细胞的整体毒性。  相似文献   

A novel method to estimate mineral compositions of mudrocks: A case study for the Canadian unconventional petroleum systems     

《Marine and Petroleum Geology》2016

The mineral composition of mudrocks is an essential attribute in controlling the reservoir quality of unconventional petroleum systems. The present study introduces a semi-quantitative method to estimate mineral phases of mudrocks in various Canadian unconventional hydrocarbon systems using total elemental analysis (inductively coupled plasma-mass spectrometry (ICP-MS)) and Rock-Eval data (total organic carbon (TOC) and mineral carbon (MinC)).This method involves statistical analysis based on a sound knowledge of hydrocarbon source rock inorganic geochemistry. The workflow can be divided into four steps: (i) converting major elements (Si, Al, Fe, K, Na, Ca, Mg, Ti, and P) to their oxides, (ii) inferring modes of occurrence of elements using statistical analysis of geochemical data (major elements, TOC, and MinC), (iii) identifying the mineral types (oxide, aluminosilicates, carbonates, sulfide, and phosphate) according to elemental occurrences and calculating mineral phase concentrations, and (iv) verifying the results by comparing to XRD data on selected samples. The results, especially for brittle minerals such as quartz, carbonates (e.g. calcite, dolomite, and ankerite), and pyrite, show that the estimated mineral compositions correspond closely and consistently with measured mineralogy obtained from XRD. This method takes advantage of bulk geochemical data already available for hydrocarbon potential and chemostratigraphic studies, without devoting additional samples and cost for XRD analysis.  相似文献   

高效液相色谱-离子阱质谱法测定海洋微藻藻粉中的8种脂溶性毒素   总被引：1，自引：0，他引：1  

高莉媛  王艳龙  陈军辉  王帅  史小星  石洪华  郑立 《海洋科学》2016,40(10):113-119

建立了利用高效液相色谱-电喷雾离子阱质谱(HPLC-ESI-IT-MS)测定海洋微藻藻粉中8种典型脂溶性毒素的分析方法。藻粉样品经超声细胞破碎后,采用超声波辅助提取法对藻毒素进行提取,用HPLC-ESI-IT-MS多反应离子监测(MRM)模式对各种毒素(包括大田软海绵酸(OA)、鳍藻毒素1(DTX-1)、扇贝毒素2(PTX-2)、虾夷扇贝毒素(YTX)、原多甲藻酸1(AZA1)原多甲藻酸2(AZA2)、罗环内酯毒素(SPX),米氏裸甲藻毒素(GYM))进行测定。8种脂溶性藻毒素均在线性范围内线性关系良好(R2均在0.991以上),检出限均介于0.085～1.315 pg之间,加标回收率在88.5%～111.4%之间,方法重复性相对标准偏差(RSD)在4.82%～10.17%范围。应用该方法对利玛原甲藻干藻粉中的毒素进行了测定,分析结果良好,说明本方法是海洋微藻藻粉中脂溶性藻毒素测定的有效方法。  相似文献   

锂光卤石X-ray衍射标准图谱          下载免费PDF全文

阳海棠  曾德文  唐垂云  李凯明  韩海军 《盐湖研究》2016,24(4):32-36

盐湖卤水提锂过程中需了解与掌握锂元素结晶析出与赋存状态,锂光卤石(LiCl·MgCl_2·7H_2O)作为重要的中间产物,其结构与种类均需鉴别,但由于缺乏锂光卤石的X-ray衍射标准图谱,使得常见的Xray衍射方法无法应用。利用相图原理,通过湿固相法制备高纯锂光卤石,然后对其进行X-ray衍射分析,从而提供锂光卤石X-ray衍射的标准图谱,为高镁锂比盐湖卤水提锂过程分析提供可靠的理论支撑。  相似文献   

粉末压片-X射线荧光光谱法测定盐湖样品中的主次元素          下载免费PDF全文

闵秀云  王德荣  高春亮 《盐湖研究》2016,24(2):32-36

采用粉末样品压片制样,利用波长色散X射线荧光光谱仪对盐湖样品中K、Ca、Na、Mg、Cl、SO_4~(2-)等6个主次元素(组分)含量进行测定。使用化学定值得到的样品作为人工标样,其值作为标准样品参考值,建立了X射线荧光光谱法测定盐湖样品中主次元素的方法。经验证,该分析方法的准确度完全能够满足化学分析的要求,其相对标准偏差RSD7%,分析元素结果与化学法结果的相对误差均小于5%。  相似文献   

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry          下载免费PDF全文

Wen Zhang  Liang Qi  Zhaochu Hu  Cunjiang Zheng  Yongsheng Liu  Haihong Chen  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(2):195-216

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.  相似文献   

阿尔金北缘岩石变形机制——来自X光组构分析的证据     

何江涛  陈柏林  王永  孟令通  吴玉  韩梅梅  王斌 《地质通报》2016,35(1):123-129

对阿尔金北缘地区变形蚀变花岗岩、花岗质糜棱岩、变形酸性火山岩和变形英安质凝灰岩中石英和绢云母2种矿物进行X光岩石组构分析,认为本区岩石变形比较明显,宏观面理近于东西向展布,绢云母变形较强,平行于面理定向排列;而石英以底面或近底面滑移为主,部分样品兼有柱面Ⅰ型滑移和柱面Ⅱ型滑移,反映本区岩石变形机制为中浅层次的脆-韧性变形(10~15km、250~350℃、0.25~0.40GPa)。通过岩石组构特征与宏观面理产状,推断本区韧性变形以右行运动为主,与板块碰撞在阿尔金北缘大平沟地区产生的韧性变形带特征一致。  相似文献