In situ time resolved synchrotron powder diffraction study of thaumasite     

Annalisa Martucci  Giuseppe Cruciani 《Physics and Chemistry of Minerals》2006,33(10):723-731

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.  相似文献   

The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl     

Geraldo Magela da Costa  Gabriel de Oliveira Polli  Márcio A. Kahwage  Eddy de Grave  Antônio Claret Soares Sabioni  Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   

Construction Problems on the Karstified Limestone Tuffs of Condeixa, Central Portugal: A Case Study     

M. Quinta Ferreira  J. L. Velho 《Geotechnical and Geological Engineering》2006,24(1):101-116

During the excavations for the foundations of a three storey building on the limestone tuffs of Condeixa, Central Portugal, a large dissolution fissure and smaller dissolution voids were found. Since the area has never been the subject of engineering geology investigation, it was decided to evaluate the risk associated with the construction of the building. These limestone tuffs were formed in a continental environment by the precipitation of calcite carried by the water coming from the large limestone body in the east. The precipitated calcite mixed with the terrigenous materials and around trunks and leaves of plants, originating a very heterogeneous and porous ground, which is characteristic of limestone tuffs. The study started with a detailed geological survey followed by a large number of destructive drillings, located essentially under the pad foundations. The results revealed several karstic cavities with serious problems for the building foundations and the structure, and many smaller dissolution cavities, often filled with clayey soils. The ground treatment solutions used included, dental cleaning, filling with concrete or granular material the dissolution structures accessible at the level of the foundation, reinforcement of the footing and the structure of the building and adding a continuous foundation beam to hold the foundations together. The cost of the engineering geology study, site investigation, ground treatment, and the reinforcement of the foundation and building, increased the total construction cost from 2%, at the design stage, to 4.8%.  相似文献   

桩锚支挡体系在广西寨-任二级公路高边坡治理工程中的应用   总被引：3，自引：0，他引：3  

胡华敏  胡杰刚  俞敏  全洪波  兰高 《中国地质灾害与防治学报》2006,17(3):150-153

(六)寨-(水)任二级公路施工后,滑坡、坍塌、崩塌现象甚多,边坡治理迫在眉睫。桩锚支挡体系是一项主动性加固边坡技术,具结构轻巧、用材合理、施工简单、工期短、费用低等特点。论文通过其在(六)寨-(水)任二级公路K56段高边坡治理工程中的应用,对桩锚支挡体系的设计及施工要点作了介绍。  相似文献   

Effect of heat treatment on tourmaline from Brazil   总被引：4，自引：0，他引：4  

Cristiane Castañeda  Sigrid G. Eeckhout  Geraldo Magela da Costa  Nilson F. Botelho  Eddy De Grave 《Physics and Chemistry of Minerals》2006,33(3):207-216

The crystal-chemical behaviour of tourmaline from Araçuaí, Minas Gerais state, Brazil, when subjected to heating in air atmosphere has been studied by several techniques, including EMPA, UV–Vis, TGA, and Mössbauer spectroscopy. The tourmaline samples are typically intermediate members of the elbaite-schorl series. The origin of colour and of its change after treatment has been discussed in terms of local disorder, presence of metal transition elements, oxidation of ferrous iron at the octahedral site, and simultaneous trap of the excess electron. These findings may be used to enhance the colour in tourmaline crystals or generate wanted colour changes.  相似文献   

旧供水井化学处理方法介绍--以加德满都市旧供水井修复为例   总被引：1，自引：0，他引：1  

章伟民 《水文地质工程地质》2005,32(6):100-101,107

本文以加德满都市旧供水井修复项目为例,针对因滤水管缝隙被化学物质堵塞,导致井出水量逐年减少的旧供水井。通过井下电视摄像系统检查,采用六偏磷酸钠、氨基黄酸等有机酸,结合刷洗、高压喷射等机械方法进行处理,使旧供水井出水量得到明显提高。  相似文献   

生物膜处理技术的研究进展   总被引：3，自引：0，他引：3  

吴会中  单欣  赵琛琛 《中国勘察设计》2005,(11):52-54

本文综述了生物膜技术的发展概况及其传质理论,并且对各种类型生物膜反应器的应用和发展作了简要论述,最后提出了生物膜技术的发展方向。  相似文献   

基于立体补偿的遥感立体像对压缩方法     

李飞鹏  马国锐  秦前清  李德仁 《遥感学报》2005,9(2):195-203

提出研究遥感立体像对的压缩问题。主要讨论了左右影像的视差补偿和辐射补偿。针对遥感立体像对视差分布不均以及左右影像存在辐射差的特点,提出了一种基于立体补偿的遥感立体像对压缩算法。该算法以左片为基准图像,采用自适应视差估计计算出右片的视差矢量,结合辐射校正和重叠块视差补偿技术得到平滑的右片的预测图像,以右片减去预测图像得到残差图像,然后采用小波压缩算法对残差图像进行压缩。实验结果表明,该算法能显著提高遥感立体像对的压缩性能。  相似文献   

五道梁地区总辐射的年际变化   总被引：10，自引：4，他引：10  

李韧  季国良  杨文 《高原气象》2005,24(2):173-177

利用实测的太阳总辐射通量密度及地气温差资料，建立了月平均地气温差与月平均太阳总辐射通量密度的回归方程，并用该回归方程计算了五道梁地区1980-1993年共14年的月平均总辐射通量密度，分析了该地区总辐射通量密度的年际变化，发现该地区总辐射通量密度具有较明显的6～7年的振荡周期。20世纪后10年年平均总辐射通量密度有增大的趋势。  相似文献   

青藏高原云-辐射-加热效应和南亚夏季风--1985年与1987年对比分析   总被引：4，自引：0，他引：4  

王可丽  吴国雄  江灏  刘平 《气象学报》2002,60(2):173-180

文中首先利用NCEP NCAR再分析的风场资料 ,分析了南亚夏季风的时空特征 ,选取了有代表性的典型强、弱夏季风年 ,继而利用ISCCP C2、ERBE S4卫星观测资料和NCEP NCAR再分析资料 ,对比分析了强、弱夏季风前期青藏高原地区的云—辐射—加热状况及其在海、陆差异中的作用。分析结果表明 ,南亚夏季风强或弱 ,其前期青藏高原地区的云—辐射—加热效应有明显的差异。在强 (弱 )南亚夏季风的前期 ,青藏高原大部分地区为相对少 (多 )云区 ,其云量变化不仅表明了此区的云—辐射—加热效应的不同 ,更重要的是与此同时出现的海、陆之间云量分布的“跷跷板”现象 ,进一步改变了海、陆之间的热力差异。而且 ,在强南亚夏季风年 ,这种热力差异不但开始得早 ,而且持续时间长、作用范围大 ,从而对南亚夏季风的形成和变化产生重要的影响  相似文献