康定杂岩Rb-Sr、Sm-Nd同位素系统及其意义   总被引：1，自引：0，他引：1  

陈岳龙  王忠  罗照华  李大鹏  赵俊香 《现代地质》2008,22(5)

通过对康定—冕宁地区出露的英云闪长岩、黑云角闪斜长片麻岩、角闪变粒岩全岩及其中所分离出的角闪石、黑云母、斜长石、钾长石的Rb-Sr、Sm-Nd同位素的系统测定,结合岩石的锆石U-Pb年龄结果,确定这些变质杂岩由于经历了复杂的形成过程与变质历史,Rb-Sr、Sm-Nd同位素体系难以确定其结晶年龄。由单矿物与全岩Rb-Sr、Sm-Nd体系拟合的~700 M a的等时线年龄反映了角闪岩相-高角闪岩相的变质作用年龄。Sm-Nd同位素体系由于在变质作用过程中的部分开放性,很容易给出无意义的较老的混合年龄。康定杂岩结晶后并没有经历麻粒岩相变质作用,区域上所含的麻粒岩透镜体可能是新元古代(773~721 M a)期间由Rod in ia超大陆裂解产生的新生洋壳向扬子克拉通陆块俯冲消减过程的变质产物。俯冲到一定深度后,由于板片被拉断,软流圈上涌导致变质洋壳板片岩石、先前底侵变质的镁铁质岩石及扬子陆块长英质基底岩石发生部分熔融,以镁铁质岩石熔融产生的熔浆为主(>70%),与长英质基底岩石熔融产生的熔浆混合形成w(Na2O)/w(K2O)>1的TTG组合。  相似文献   

塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪     

王东  王国芝  冉启贵  刘树根  胡九珍  张长俊 《现代地质》2008,22(4)

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。  相似文献   

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events     

FENG Chengyou  ZHANG Dequan  LI Daxin  SHE Hongquan  DONG Yingjun 《《地质学报》英文版》2008,82(4):826-837

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.  相似文献   

Soil-to-dwelling radon isotope ratio in the Baikal region     

B.P. Chernyago  A.I. Nepomnyashchikh  G.I. Kalinovskii 《Russian Geology and Geophysics》2008,49(12):971-977

Relations between indoor and soil gas radon were experimentally studied in villages of the Baikal region. On the basis of the obtained data, the soil-to-indoor radon ratio was calculated, which can be used for prediction of radon pollution in buildings of the same kind.  相似文献   

镭同位素示踪隆教湾的海底地下水排泄   总被引：10，自引：0，他引：10  

郭占荣  黄磊  刘花台  袁晓婕 《地球学报》2008,29(5):647-652

福建省漳州市隆教湾海水中镭同位素的研究,目的是评价海底地下水排泄量。在2007年6月的航次中,垂直于岸线的9km剖面上布置15个站位,每个站位用潜水泵采集表层海水样60L于塑料桶中。水样运回实验室后,立即用装有锰纤维的PVC管以虹吸的方式富集水样中的镭同位素,水通过PVC管的流速小于300ml/min。224Ra活度用连续射气法测定,测完224Ra后密封7d以上,然后用直接射气法测定226Ra活度。224Ra和226Ra活度都呈现自岸向海逐渐降低的规律,表明扩散控制镭同位素的分布,由224Ra获得68.83km2d-1的扩散系数,同时226Ra形成-0.963dpm100l-1km-1的活度梯度。用扩散系数和活度梯度建立的226Ra的离岸通量为6.62×1011dpmkm-2d-1,这个通量一定是得到SGD输入的镭支持,从而获得隆教湾的海底地下水排泄量是3.03×109m3km-2d-1。该排泄量包括陆源地下淡水排泄量和再循环海水排泄量,绝大部分可能是再循环海水,有待进一步研究。  相似文献   

攀枝花龙洞煤矿地下水运移的同位素研究     

王华  张远明  覃嘉铭  李强  杨琰 《地球学报》2008,29(6):725-728

攀枝花市西区龙洞煤矿经过十余年的生产,不但在地下形成了较大范围的采空区,而且通过影响地下水形成了较大范围的疏干,致使矿区内大部分泉点断流.因而,为确定矿山地下水长期疏干对龙洞泉流域的影响程度,笔者通过比较水库水、大气降水、地下水与渗漏水之间的同位素特征,区分出了地下水的补给来源,并为查明本区的水文地质条件及确定矿坑地下水疏干的影响范围提供科学依据.  相似文献   

Fluid Geochemistry as Indicator of Tectonically-Related,Deep Water Circulations in the Sardinian Rift-Campidano Graben (Italy): New Insights from Environmental Isotopes     

Elisa Sacchi  Gian Maria Zuppi  Luca Pizzino  Fedora Quattrocchi  Salvatore Lombardi 《Aquatic Geochemistry》2008,14(4):301-319

The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO₃ and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO₂ contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ¹³C_TDIC values suggest the presence of two distinct CO₂ sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO₂ and He indicates an increased mantle signature in uprising CO₂-rich fluids.  相似文献   

Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA   总被引：3，自引：1，他引：2  

Andrew J. Long  J. Foster Sawyer  Larry D. Putnam 《Hydrogeology Journal》2008,16(2):263-280

Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ¹⁸O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration.  相似文献   

Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain   总被引：1，自引：0，他引：1  

Elena Giménez Forcada  Ignacio Morell Evangelista 《Hydrogeology Journal》2008,16(3):547-557

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.  相似文献   

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA     

Mark A. Engle  Fraser Goff  David G. Jewett  Gregory J. Reller  Joel B. Bauman 《Hydrogeology Journal》2008,16(3):559-573

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

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