多接收器电感耦合等离子体质谱法测定镉标准溶液中镉的同位素组成   总被引：1，自引：1，他引：0  

高博  梁细荣  刘颖  胡光黔  曾文  涂湘林 《岩矿测试》2008,27(5):321-324

建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。  相似文献   

In situ strength measurements on natural upper-mantle minerals   总被引：1，自引：0，他引：1  

Junji Yamamoto  Jun-ichi Ando  Hiroyuki Kagi  Toru Inoue  Akihiro Yamada  Daisuke Yamazaki  Tetsuo Irifune 《Physics and Chemistry of Minerals》2008,35(5):249-257

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.  相似文献   

Artificial Upwelling of Deep Seawater Using the Perpetual Salt Fountain for Cultivation of Ocean Desert     

Shigenao Maruyama  Koutaro Tsubaki  Keisuke Taira  Seigo Sakai 《Journal of Oceanography》2004,60(3):563-568

Deep seawater in the ocean contains a great deal of nutrients. Stommel et al. have proposed the notion of a “perpetual salt fountain” (Stommel et al., 1956). They noted the possibility of a permanent upwelling of deep seawater with no additional external energy source. If we can cause deep seawater to upwell extensively, we can achieve an ocean farm. We have succeeded in measuring the upwelling velocity by an experiment in the Mariana Trench area using a special measurement system. A 0.3 m diameter, 280 m long soft pipe made of PVC sheet was used in the experiment. The measured data, a verification experiment, and numerical simulation results, gave an estimate of upwelling velocity of 212 m/day. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

基于规则波波形的超声波非接触测量有关问题探讨     

叶家玮  孙晓梅 《海洋工程》1996,(3)

波浪波形的非接触测量近年来获得广泛的应用。本文以规则波为讨论对象，针对介质为空气的超声波测量方式进行波形测量误差分析，并结合实验室和实船试验进行对比分析。理论分析表明：在规则波取为坦谷波和ＳＴＯＫＥＳ波的前提下，超声波技术几乎产生相同的最大误差。定量分析表明，在对测量精度限制的条件下，对文中提及的各项参数应作有效的控制  相似文献   

耗氧速率(OUR)测量方法的实验研究   总被引：4，自引：0，他引：4  

李冰  孙英兰  李玉瑛 《中国海洋大学学报(自然科学版)》2006,36(3):456-460

目前多采用分批实验法和呼吸测量仪测量耗氧速率,而耗氧速率的测量对于研究活性污泥数学模型中的动力学参数及废水特性鉴定具有重要意义。本文根据OUR测量方法的基本原理设计了1种简易的OUR测量装置,为检验测量装置的有效性,设计了相关实验进行验证。在内源呼吸实验中,测定了所用活性污泥的内源呼吸速率是5.1mgO2/L·h,污泥的衰减系数是0.0137h-1,比文献值略高。基质降解实验对人工配水(葡萄糖和淀粉)的耗氧速率进行了测定,实验结果显示有3个显著不同的耗氧速率,分别为35mg/L·h,13mg/L·h,6mg/L·h,它们各代表葡萄糖降解、淀粉降解和内源呼吸的速率。内源呼吸速率高于前1个实验是由于基质降解过程中污泥量增加所致。并计算出异养菌产率系数Kd为0.63mgVSS/mgCOD,Kd略低于文献值。实验结果证明,该装置能很好的实现测量目的。  相似文献   

Field measurements and monitoring of wastewater discharge in sea water     

Michele Mossa   《Estuarine, Coastal and Shelf Science》2006,68(3-4):509

This paper reports a study of the field measurements and monitoring of wastewater discharge in sea water at Bari East (Italy). A wastewater sea outfall system is an integral and fundamental part of each wastewater treatment with ultimate sink in the sea water. The design of a water treatment plant and wastewater outfall must take into account the use of the environmental water, the values of physicochemical parameters to be respected in order to safeguard the use itself and the quality of the environmental water where wastewater is issued. In the present study measurements of sea current velocity components were carried out with a VM-ADP (Vessel-Mounted Acoustic Doppler Profiler). Salinity, wind directions and velocities were assessed with, for one survey, the total faecal coliforms and other biochemical parameters. It was emphasized that the measurements necessary for monitoring cannot be concentrated in the wastewater outfall pipe zone only, but should be extended to a neighbouring area of the outfall pipe, with an extension depending on the wastewater discharge, the polluting charge and the magnitude of the sea currents and the winds typical of the zone of interest. The analyses presented in this paper confirm that the sea zones close to the wastewater outfall pipe are particularly sensitive and vulnerable. Such results must be considered in the planning of a wastewater outfall pipe.  相似文献   

A Moored Underwater Energy Conservation System for Profiling Measurement   总被引：3，自引：0，他引：3  

龚德俊陈永华  李思忍徐永平 姜静波 《中国海洋工程》2007,21(3):541-548

There is a need to obtain the hydrologic data including ocean current,wave,temperature and so on in the South China Sea.A new profiling instrument which does not suffer from the damage due to nature forces or incidents caused by passing ships,is under development to acquire data from this area.This device is based on a taut single point mid-water mooring system.It incorporates a small,instrumented vertically profiling float attached via an electromechanical cable to a winch integral with the main subsurface flotation.On a pre-set schedule,the instrument float with sensors is winched up to the surface if there is no ship passing by,which is defined by an on-board miniature sonar.And it can be immediately winched down to a certain depth if the sonar sensor finds something is coming.Since,because of logistics,the area can only be visited once for a long time and a minimum of 10 times per day profiles are desired,energy demands are severe.To respond to these concerns,the system has been designed to conserve a substantial portion of the potential energy lost during the ascent phase of each profile and subsequently use this energy to pull the instrument down.Compared with the previous single-point layered measuring mode,it is advanced and economica1.At last the paper introduces the test in the South China Sea.  相似文献   

Air-Sea Gas Transfer Velocity in Stormy Winter Estimated from Radon Deficiency     

Hitoshi Kawabata  Hisashi Narita  Koh Harada  Shizuo Tsunogai  Masashi Kusakabe 《Journal of Oceanography》2003,59(5):651-661

Thirteen vertical profiles of ²²⁶Ra and ²²²Rn in the near-surface water were obtained in the western North Pacific in winter, and the gas transfer velocities across the air-sea interface were estimated. The transfer velocities found by applying a steady state model varied widely from 2.1 to 30.2 m day⁻¹ with a mean of 9.4 m day⁻¹. The mean value is almost 5 times higher than that in summer in other oceans, and the maximum value is a record high for world oceans. This is partly due to the inadequacy of the steady state model, which overestimates when stronger winds blow in more recent days than the ²²²Rn half-life of about 4 days. In fact, a strong low pressure zone passed through the station about 2 days earlier, which was one of the low pressure zones that with a period of develop once a week or so in the northwestern North Pacific in winter. Instead of steady-state removal, if half of the radon removal occurred sporadically every 7 days, and the last removal took place two days before the observation, the transfer velocity would be 26 m day⁻¹. Our mean transfer velocity, which is less than 20% different from the steady state value including both overestimated and underestimated values, 9.4 ± 4.8 m day⁻¹, seems to represent the mean state of this region in winter. This suggests that the gas exchange fluxes under extremely rough conditions in the open ocean are larger than those estimated by using a transfer velocity equation with a linear or quadratic relationship with wind speed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

动态基准实时测量系统的开发与应用   总被引：3，自引：0，他引：3  

卫建东  徐忠阳  张良琚 《海洋测绘》2005,25(1):31-35

介绍了动态基准实时测量系统的硬件组成、站点上全站仪棱镜组合安装与检测方法、系统软件的开发及特点，最后对系统在广州地铁某地铁站结构变形自动监测中的应用情况进行了阐述。通过实际应用表明该系统能应用在自动化、高精度的变形监测领域。  相似文献   

冲绳海槽浮岩包裹体的测温试验   总被引：3，自引：2，他引：3  

翟世奎  张杰  张明书  于增慧 《海洋与湖沼》2001,32(1):67-73

对浮岩中斜长石斑晶中的包裹体及玻璃基质中的包裹体首先进行双面光薄片的镜下观察，然后进行了系统的均化法与爆裂法测温试验。观察与试验结果表明：(1)斜长石中的包裹体均为玻璃质+气泡的两相包裹体，未发现气—液包裹体。固化包裹体为玻璃质，非晶质的固化包裹体外即是大量的气泡，特别是基质当中气泡更为发育，说明熔浆中含有丰富的挥发性组分，同时也说明包裹体形成于较浅的地质条件下。(2)长石中包裹体的均化温度不受包裹体特征不同的影响，均化温度分布范围从910—1250℃，峰值明显，计算的均化温度为Tz=(1081.4±177.9)℃，但还存在有高于1250℃的均化温度峰。包裹体均化法测试结果说明浮岩中斜长石的形成过程至少有两个阶段：第一阶段的岩浆温度在1200—1300℃左右，在此温度下形成的是An值较高的基性斜长石，同时结晶的还有辉石等矿物，斜长石结晶第二个阶段时的熔浆温度在1100℃以下，这一阶段持续的时间长，跨越的温度范围大，应是岩浆在近地表和岩浆喷出过程中的岩浆快速冷却期，同时伴随有矿物大规模晶出。(3)包裹体中的气相部分均聚合成圆形或近圆形，说明温度下降速度较快。斑晶斜长石中部分包裹体与基质玻璃中包裹体的形成温度是连续变化的，这一事实应该与冲绳海槽特殊的地质条件有关  相似文献