小秦岭西段驾鹿金矿田矿物地球化学特征及找矿标志   总被引：1，自引：0，他引：1  

高珍权  刘继顺  陈德兴 《矿物岩石》2001,21(2):78-83

本文在总结驾鹿金矿田有关石英脉主要金属矿物地质产状、物性特征的基础上，系统对比性研究了蚀变岩和石英脉两类金矿床中产状、粒级、晶形、破碎程度不同的各世代黄铁矿中微量元素的含量、组合、比值特征及演化和不同世代撤离铅矿、地表褐铁矿、软锰矿的含金性，建立了两类金矿的找矿矿物学标志。  相似文献   

Characterisation of tobelite (NH4)Al2[AlSi3O10](OH)2 and ND4-tobelite (ND4)Al2[AlSi3O10](OD)2 using IR spectroscopy and Rietveld refinement of XRD spectra     

D. E. Harlov  M. Andrut  B. Pöter 《Physics and Chemistry of Minerals》2001,28(4):268-276

Tobelite (NH₄) Al₂ [AlSi₃O₁₀] (OH)₂, the ammonium analogue of muscovite, and its deuterated form ND₄-tobelite (ND₄) Al₂ [AlSi₃O₁₀] (OD)₂ have been synthesised at 600?°C and 200 and 500 Mpa using a well homogenised, stoichiometric SiO₂-Al₂O₃ oxide mix with Al₂O₃ in excess of 5 mol% and a 25% NH₃ solution whose relative abundance was such that the amount of NH₄ ⁺ stoichiometrically available was in excess of 50%. Characterisation of both tobelite and ND₄-tobelite using IR-spectroscopy, Rietveld refinement of X-ray powder diffraction data, and electron microprobe analysis indicate that, similar to K⁺ in muscovite, the NH₄ ⁺ or ND₄ ⁺ molecule occupies the interlayer site. IR absorption bands caused by NH₄ ⁺ and ND₄ ⁺ can be explained, to a very good approximation, on the basis of T_d symmetry. Nevertheless, substantial line broadening and the occurrence of shoulders indicate a deviation from ideal T_d symmetry. However, even at 77?K, no discrete splitting of the degenerate states could be confirmed. The OH stretching frequencies observed for synthetic tobelite are quite similar to those for muscovite, indicating that the replacement of K⁺ by NH₄ ⁺ has no effect. The low FWHH of the OH bands indicate that the hydroxyl groups are well ordered within the structure. Rietveld refinement of tobelite and ND₄-tobelite indicates that all samples synthesised consist of the 3 different mica polytypes which are typical of muscovite – namely 1M (C2/m), 2M ₁ (C2/c) and 2M ₂ (C2/c). Tobelite and ND₄-tobelite synthesised at 500 Mpa principally contain the 1M polytype, whereas the principle polytype for ND₄-tobelite synthesised at 200 Mpa, is 2M ₂. Rietveld refinement of X-ray diffraction spectra for tobelite synthesised at 200 Mpa was problematic due to the very broad FWHH of the X-ray peaks indicating poor crystallinity. In comparision to synthetic muscovite, the cell dimensions observed for tobelite and its deuterated analogue are quite similar except for the lattice constant c. Due to the larger radius of NH₄ ⁺ or ND₄ ⁺ compared to K⁺ cation, the c-direction is expanded form 10.275 Å in muscovite to approximately 10.540 Å in tobelite and ND₄-tobelite.  相似文献   

莱州湾地区10万年以来沉积环境变化   总被引：11，自引：0，他引：11  

彭子成  韩有松 《地质论评》1992,38(4):360-367

本文用热释光测年和地球化学标志法研究了莱州湾地区沉积环境的变化。石英的375℃热释光峰作为测年基础。岩芯样品的测定结果、反映了自全新世(1.2万年)至晚更新世(11万年)地层的年代特点。实验中来用了Sr/Ba、Rb、Mn/Fe和CaO作为地球化学标志,所得数据经Sheppard方程和Fisher判别处理。在得到的沉积环境变化曲线和大洋δ~(18)O曲线对比中可以看出,本区在十万年以来出现过三次海陆相地层变化序列,其中在距今11—7万年和深度为43.5—60m处,在距今4.6—2.1万年和深度为23—35m处,以及在距今1.1—0.6万年和深度为8—11m处出现过三次海相地层,分别与沧州、献县和黄骅海侵事件相应,并同时受到全球气候变化的控制。  相似文献   

福建上杭紫金山铜金矿床地质简介   总被引：2，自引：0，他引：2  

姚金炎  彭振安 《矿产与地质》1992,6(2):89-94

以宏观角度介绍紫金山铜金矿床地质背景,论述了火山机构、次火山岩、隐爆角砾岩、围岩及围岩蚀变、矿化带及矿化特征,着重总结该矿床找矿标志,以期在地质找矿中得以借鉴。  相似文献   

Comparing performance indicators to characterize the water supply to the demands of the Guadiana River basin (Spain)     

Carla Palop-Donat  Javier Paredes-Arquiola  Abel Solera  Joaquín Andreu 《水文科学杂志》2020,65(7):1060-1074

ABSTRACT

Water indicators and indices are useful tools to assess river basin performance, that is, to measure whether the basin operates satisfactorily under a wide range of possible future demands and hydrological conditions. Spanish regulations assess the performance of water demands by using reliability indicators (RIs), established by law in 2008. This article raises the possibility of updating RIs by comparing them with sustainability indicators (SIs). SIs are widely used for the assessment of river basin performance and several policy scenarios. We applied a water allocation model to the Guadiana River basin in Spain to compare indicators under three scenarios. The study was framed within the science of socio-hydrology, combining the physical environment of a water system with its influence on social aspects. SIs gave better results than RIs when comparing future scenarios. We also propose the introduction of a vulnerability indicator into Spanish regulations.  相似文献   

Crystal chemistry of tremolite–tschermakite solid solutions     

J. Najorka  M. Gottschalk 《Physics and Chemistry of Minerals》2003,30(2):108-124

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.  相似文献   

可持续发展指标体系及综合评价研究评述   总被引：5，自引：0，他引：5  

邱茂慧  陈忠暖  蔡霞 《热带地理》2002,22(3):222-226

可持续发展指标体系研究和可持续发展综合评价研究是可持续发展进程的一部分,是连接可持续发展战略理论与战略实施的桥梁,文中对近年来国内外出现的有关研究做了简要概括,分析了各研究成果的优缺点,总结了研究的发燕尾服特点并展望了研究的前景。  相似文献   

Improving the efficiency of ant algorithms using adaptive refinement: Application to storm water network design     

M.H. Afshar 《Advances in water resources》2006

The ant algorithm is a new evolutionary optimization method proposed for the solution of discrete combinatorial optimization problems. Many engineering optimization problems involve decision variables of continuous nature. Application of the ant algorithm to the optimization of these continuous problems requires discretization of the continuous search space, thereby reducing the underlying continuous problem to a discrete optimization problem. The level of discretization of the continuous search space, however, could present some problems. Generally, coarse discretization of the continuous design variables could adversely affect the quality of the final solution while finer discretization would enlarge the scale of the problem leading to higher computation cost and, occasionally, to low quality solutions. An adaptive refinement procedure is introduced in this paper as a remedy for the problem just outlined. The method is based on the idea of limiting the originally wide search space to a smaller one once a locally converged solution is obtained. The smaller search space is designed to contain the locally optimum solution at its center. The resulting search space is discretized and a completely new search is conducted to find a better solution. The procedure is continued until no improvement can be made by further refinement. The method is applied to a benchmark problem in storm water network design discipline and the results are compared with those of existing methods. The method is shown to be very effective and efficient regarding the optimality of the solution, and the convergence characteristics of the resulting ant algorithm. Furthermore, the method proves itself capable of finding an optimal, or near-optimal solution, independent of the discretization level and the size of the colony used.  相似文献   

甘肃代家庄铅锌矿床地球化学异常特征   总被引：2，自引：0，他引：2       下载免费PDF全文

张忠平 《甘肃地质》2006,15(2):42-47

代家庄铅锌矿床是通过区域化探异常查证工作,在西秦岭地区发现的SEDEX型铅锌矿床。本文根据代家庄矿区水系沉积物、土壤和岩石剖面测量结果,对Pb、Zn等成矿元素的分布特征和组合关系进行了分析,初步总结了代家庄铅锌矿床的地质和地球化学异常特征,归纳出该矿床的地球化学找矿标志,提出了找矿方向。  相似文献   

金矿的地质地球化学找矿标志     

薛水根 《江苏地质》2007,31(1):7-9

地层和岩浆岩含金高丰度是金矿赋集的物质来源,断裂构造是容矿、储矿的空间。一般说来,金成矿物质越丰富,就越有利于形成大矿、富矿。以江西金矿找矿为例,阐述正确圈定金异常,合理布置探矿工程,获得找金成果新突破的实际意义。  相似文献