过硫酸铵氧化容量法测定矿石中锰方法的改进   总被引：5，自引：1，他引：5  

范福南 《岩矿测试》2005,24(3):235-236

采用过硫酸铵氧化容量法测定锰时,可在低酸度(0.18mol/LH2SO4、0.29mol/LH3PO4)和大体积(300mL)溶液中氧化Mn2 至Mn7 。所测得的结果十分稳定,回收率为100%。采用管理样分析验证方法,其结果与铋酸钠容量法结果一致。对于w(Mn)=11.36%的试样进行10次分析测定,RSD=0.33%。方法可测定w(Mn)≥0.01%的常见矿种样品。  相似文献   

冲绳海槽玄武岩中中酸性残余熔体研究及其岩石学意义   总被引：1，自引：0，他引：1  

陈小明  王汝成赵明 倪培赵广涛  李巍然 《岩石学报》2005,21(1):158-168

与洋壳有关的酸性岩由于对了解幔源岩浆的演化以及判别古老蛇绿岩套及其构造位置的重要意义而倍受岩石学家和构造地质学家的关注。本对发现于冲绳海槽玄武岩基质中的中酸性到酸性残余熔体进行了详细研究，它们提供了幔源玄武岩浆结晶分异形成酸性岩浆的直接证据。在细小的基质矿物间分布有一种玻璃质的残余熔体，其成分随距冷凝边距离(L)的增加而越来越酸性。在SiO2对Na2O K2O图解上，残余熔体的投影点从玄武岩到英安岩均有分布，反映了一个连续的演化系列。在AFM图解上，残余熔体表现出与Thingmuli火山岩系列类似的拉斑玄武岩系列的演化趋势。我们的研究表明：残余熔体的演化受结晶分异作用控制。在早期结晶阶段，辉石的结晶起主导作用，结果造成残余熔体中SiO2、Al2O3，Na2O的迅速增加，FeO、MgO、CaO迅速降低。在晚期结晶阶段，斜长石成为主导结晶相，导致残余熔体中Al2O3，Na2O的迅速消减。Al2O3、Na2O从增加到降低的转变出现在SiO2=62％左右。在L=27．5mm处，85～90％的基质岩浆已发生了结晶作用，导致残余熔体中SiO2含量达到69～70％，而且此处还新出现了一种富FeTi的氧化物。该玄武岩中残余熔体和基质矿物的成分及演化特征分别与Thingmuli火山岩系列中酸性端元的组成相似，在也佐证了Thingmuli火山岩系列是幔源岩浆结晶分异的产物.  相似文献   

浅覆盖区土壤化学成分与基岩化学成分的关系及其意义——以大兴安岭北部地区为例   总被引：3，自引：3，他引：3       下载免费PDF全文

郝立波  陆继龙马 力 《中国地质》2005,32(3):477-482

以大兴安岭北部地区为例，研究了浅覆盖区土壤与基岩化学成分的关系。指出浅覆盖区残积型土壤主要造岩元素组合继承了基岩元素组合特征；在岩石风化成土过程中，元素再分配和迁移使土壤中大多数元素（氧化物）含量产生明显的“均一化”。在此基础上，对土壤地球化学异常的识别与评价问题进行了讨论并提出了建议。  相似文献   

绿片岩三轴流变力学特性的研究(Ⅰ):试验结果   总被引：17，自引：4，他引：17  

徐卫亚  杨圣奇  杨松林  谢守益  邵建富  王义锋 《岩土力学》2005,26(4):531-537

为了解锦屏一级水电站坝基绿片岩的流变力学特性，采用岩石全自动流变伺服仪对绿片岩进行了三轴压缩流变试验。基于试验结果，研究了绿片岩在不同围压作用下的轴向应变以及侧向应变随时间的变化规律，讨论了流变特性对岩石应力一应变曲线的影响，探讨了不同应力水平下的轴向以及侧向流变速率变化趋势，分析了不同围压下流变的破裂机制，掌握了绿片岩三轴流变的基本规律，从而为该水电站工程流变数值分析时参数的辨识提供了可靠的依据。  相似文献   

抽水引起的含水层水平应变──地裂缝活动新机理   总被引：13，自引：0，他引：13  

王庆良  刘玉海  陈志新  王文萍 《工程地质学报》2002,10(1):46-50

基于Darcy -Gersevanov广义渗流关系式 ,本文首先导出了单井定流量抽水引起的泰斯承压含水层水平运动和应变解析表达式 ,并据此提出了抽水诱发地裂缝活动的含水层水平应变新机理 ,其主要观点为 :受井栅的约束阻挡作用 ,抽水活动将在含水层内部形成近井径向挤压区和远井径向拉张区两个应变区域 ,随着抽水时间的增长 ,近井径向挤压区将逐渐向外扩展 ;当地裂缝及其下伏断层或裂隙位于抽水活动引起的径向拉张应变区域时 ,地裂缝将出现加速活动 ;反之 ,当地裂缝处于抽水活动引起的径向挤压应变区域时 ,地裂缝活动反而受到抑制。上述地裂缝活动机理通过大同机车工厂现场抽水实验得到了初步证实。  相似文献   

Pseudodynamic tests on rubber base isolators with numerical substructuring of the superstructure and strain‐rate effect compensation     

F. J. Molina  G. Verzeletti  G. Magonette  Ph. Buchet  V. Renda  M. Geradin  A. Parducci  M. Mezzi  A. Pacchiarotti  L. Federici  S. Mascelloni 《地震工程与结构动力学》2002,31(8):1563-1582

A pseudodynamic testing procedure has been applied by which the seismic response of a base‐isolated building is obtained by using as specimen the isolators, while the superstructure is numerically simulated. The procedure also takes advantage of the continuous pseudodynamic testing capabilities of the ELSA laboratory, which increase the accuracy of the results and reduce the strain‐rate effect of the rubber bearings. A simple proportional correction of the measured forces compensates the remaining strain‐rate effect due to the unrealistic speed of the test. The correction factor is obtained by means of a characterizing test on the specific rubber isolators. The developed method has been successfully applied to the prediction of the seismic response of a base‐isolated four‐storey building submitted to several specified accelerograms. The results for those earthquakes as well as the effects of some changes of the parameters of the system are discussed. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

An experimental study of grain scale melt segregation mechanisms in two common crustal rock types   总被引：3，自引：0，他引：3  

C. W. Holyoke  III    T. Rushmer 《Journal of Metamorphic Geology》2002,20(5):493-512

Creation of pathways for melt to migrate from its source is the necessary first step for transport of magma to the upper crust. To test the role of different dehydration‐melting reactions in the development of permeability during partial melting and deformation in the crust, we experimentally deformed two common crustal rock types. A muscovite‐biotite metapelite and a biotite gneiss were deformed at conditions below, at and above their fluid‐absent solidus. For the metapelite, temperatures ranged between 650 and 800 °C at P_c=700 MPa to investigate the muscovite‐dehydration melting reaction. For the biotite gneiss, temperatures ranged between 850 and 950 °C at P_c=1000 MPa to explore biotite dehydration‐melting under lower crustal conditions. Deformation for both sets of experiments was performed at the same strain rate (ε.) 1.37×10^?5 s^?1. In the presence of deformation, the positive ΔV and associated high dilational strain of the muscovite dehydration‐melting reaction produces an increase in melt pore pressure with partial melting of the metapelite. In contrast, the biotite dehydration‐melting reaction is not associated with a large dilational strain and during deformation and partial melting of the biotite gneiss melt pore pressure builds more gradually. Due to the different rates in pore pressure increase, melt‐enhanced deformation microstructures reflect the different dehydration melting reactions themselves. Permeability development in the two rocks differs because grain boundaries control melt distribution to a greater extent in the gneiss. Muscovite‐dehydration melting may develop melt pathways at low melt fractions due to a larger volume of melt, in comparison with biotite‐dehydration melting, generated at the solidus. This may be a viable physical mechanism in which rapid melt segregation from a metapelitic source rock can occur. Alternatively, the results from the gneiss experiments suggest continual draining of biotite‐derived magma from the lower crust with melt migration paths controlled by structural anisotropies in the protolith.  相似文献   

Fluid permeability of sedimentary rocks in a complete stress–strain process     

J. -A. Wang  H. D. Park   《Engineering Geology》2002,63(3-4):291-300

The permeability of sedimentary rocks during triaxial compression tests was investigated to relate it to the complete strain–stress process. It was found that the permeability was not constant, but varied with the stress and strain states in the rocks. Prior to the peak strength, the permeability decreases with increasing load. A dramatic increase in permeability occurs during the strain softening period. In the present study, in situ measurements of fluid flow and pressure in floor strata was carried out in a double longwall mining face in the Yangzhuang colliery. These measurements show that both the strata pressure and the position with respect to the mining face influence the hydrogeologic properties. The permeability increased in the floor strata behind the mining face because those mining induced fractures opened as the strata pressure decreased. To better understand this change in hydraulic behavior around the mining faces, 3-D numerical modeling was carried out. The model provides the general picture of the stress distribution and failure zone both in the floor and roof strata. The field and model results demonstrate the importance of changes in the stress and strain states on the hydrogeology of a site.  相似文献   

地震前兆时空非均匀性指标Cv值的实验检验   总被引：1，自引：1，他引：1  

王凯英  马胜利  刘力强  马瑾 《地震学报》2002,24(1):82-89

在双向加载条件下，对两种构造和介质不同的岩石标本进行变形实验，测量了标本表面不同部位的应变．在此基础上，利用王晓青和陈学忠等提出的描述地震前兆非均匀分布的参量————Cv值，分析了标本变形失稳过程中应变异常的分布，以期从实验角度检验Cv值方法并探讨其物理意义．研究表明，Cv值的变化与岩石变形特征的变化有关，是描述前兆分布非均匀性的一种有效指标；Cv值在失稳发生前先异常上升，然后下降，并在Cv值恢复过程中或恢复后伴随着失稳事件的发生．因此，Cv值是一种有效的预报指标．   相似文献   

由GPS观测结果推导中国大陆现今水平应变场   总被引：45，自引：4，他引：45  

杨国华  李延兴  韩月萍  胡新康  巩曰沐 《地震学报》2002,24(4):337-347

以中国大陆及周边近400个GPS测站的水平运动速率为基础，给出了现今地壳水平应变场结果表明:①中国大陆水平应变为西强东弱，剪应变数值大于正应变数值(绝对值)，应变量级一般为10-8/a，局部区域达到10-7/a，但应变分布不均匀；②南北向应变最突出的部位为中国西南部西段的喜马拉雅条带、西北部的36N~42N段及柴达木断块的北缘；③东西向应变西边缘变化最大．此外，由西向东还具有正负交替的变化特征；④REN(东-北向剪切应变)与Rmax(最大剪切应变)数值较大的区域分别是喜马拉雅条带、西北部的36N～42N段、柴达木断块的西部、川滇菱形块体，以及阿拉善、祁连及塔里木断块的交界区；⑤青藏块体周边以面收缩为主，内部则以面膨胀为主．其以北的地区以面收缩为主．西界数值最大，东部数值最小(除燕山构造带外)；⑥西部西区主压应变为南北向，主张应变为东西向．西部东缘区主压应变为近东西向，主张应变为近南北向．川滇菱形块体主应变的方向发生了很大的变化，北部地区为东西压南北张，南部地区则恰好相反；⑦中国大陆的应变模式可能是断块模式与连续模式的组合．此外，小尺度优势应变可能是剪切应变．造成上述结果除与印度板块的碰撞及边界耦合有关外，还与深部物质的活动及地壳介质的物性有密切的关系．必须指出，由于GPS测站在空间上分布的不均匀性，那么，由此而来的应变场，其应变尺度也不一样．   相似文献