Reactive transport impacts on recovered freshwater quality during multiple partially penetrating wells (MPPW-)ASR in a brackish heterogeneous aquifer     

《Applied Geochemistry》2016

The use of multiple partially penetrating wells (MPPW) during aquifer storage and recovery (ASR) in brackish aquifers can significantly improve the recovery efficiency (RE) of unmixed injected water. The water quality changes by reactive transport processes in a field MPPW-ASR system and their impact on RE were analyzed. The oxic freshwater injected in the deepest of four wells was continuously enriched with sodium (Na⁺) and other dominant cations from the brackish groundwater due to cation exchange by repeating cycles of ‘freshening’. During recovery periods, the breakthrough of Na⁺ was retarded in the deeper and central parts of the aquifer by ‘salinization’. Cation exchange can therefore either increase or decrease the RE of MPPW-ASR compared to the RE based on conservative Cl⁻, depending on the maximum limits set for Na⁺, the aquifer’s cation exchange capacity, and the native groundwater and injected water composition. Dissolution of Fe and Mn-containing carbonates was stimulated by acidifying oxidation reactions, involving adsorbed Fe²⁺ and Mn²⁺ and pyrite in the pyrite-rich deeper aquifer sections. Fe²⁺ and Mn²⁺ remained mobile in anoxic water upon approaching the recovery proximal zone, where Fe²⁺ precipitated via MnO₂ reduction, resulting in a dominating Mn²⁺ contamination. Recovery of Mn²⁺ and Fe²⁺ was counteracted by frequent injections of oxygen-rich water via the recovering well to form Fe and Mn-precipitates and increase sorption. The MPPW-ASR strategy exposes a much larger part of the injected water to the deeper geochemical units first, which may therefore control the mobilization of undesired elements during MPPW-ASR, rather than the average geochemical composition of the target aquifer.  相似文献   

滇西兰坪盆地金顶铅锌矿盐构造发育特征及其与成矿关系     

朱志军  郭福生 《大地构造与成矿学》2016,(2):344-353

滇西兰坪中新生代盆地广泛发育盐岩层系。通过对金顶超大型铅锌矿区的露天采厂和地下采坑的最新野外调查及大量钻孔资料的综合分析,研究区盐岩层系具有多期、多阶段运动的特点,厚度分布极不均一,它们作为区域推覆构造作用的滑脱层,对盐上层构造变形起着重要控制作用,形成一系列储矿构造。研究表明,矿区盐构造主要包括盐枕、盐背斜、盐焊接、盐穿刺、盐推覆、盐岩滑脱-断层相关褶皱组合等多种盐构造变形样式。这些盐构造的形成演化及变形机制主要受到推覆挤压缩短作用、基底断层作用和塑性流动汇聚作用、盐下和盐上层断裂滑脱作用等控制,主要沿推覆断裂构造带呈串珠状分布。金项矿区盐构造分为两个阶段:古新世–始新世挤压–拗陷层内变形阶段,形成盐枕、隆升较低的盐背斜等整合型盐构造;渐新世的逆冲推覆–盐岩滑脱阶段,受强烈的挤压推覆作用而形成盐墙、盐株等盐穿刺型构造。盐构造不同阶段的变形演化对金属元素富集成矿起到关键作用,其流动变形而形成的盐构造圈闭促使了金属聚集成矿。  相似文献   

降水井改造为原位生产井的工艺设计及应用     

吕士东  孙友宏  李强  郭威  周科  王思远 《世界地质》2016,35(4):1185-1194

为有效地扩大油页岩原位开采区域和节约油页岩原位开采的成本,需将废置的降水井改造成为原位生产井。根据降水井与原位生产井井身结构的相似性,对农安油页岩原位开采先导试验工程基地的降水井改造工艺进行了设计和优化。同时研发了偏心轮式套管割管装置及三爪式套管打捞装置用于拔管施工。工程实践证明,该工艺具有步骤简单、合理、高效以及价格低廉等特点。偏心轮式套管割管装置及三爪式套管打捞装置应用在降水井改造中,均取得理想的效果。  相似文献   

昆明盐矿三维建模及溶通性分析     

陈王慧子  朱杰勇 《矿产与地质》2016,(3):504-507

针对地下盐矿在开采过程中,随时可能会因为溶通状况的改变而发生坍塌地质灾害,本文利用矿山数字管理软件Quanty Mine,确定昆明盐矿的三维模型,以期监控盐矿开采不同阶段溶通的变化规律,为避免盐矿过度开采导致地质灾害的发生。  相似文献   

尕斯库勒盐湖中CO_2-卤水-盐岩相互作用模拟研究     

韩积斌  许建新  海擎宇  安朝  何天丽  马海州 《铀矿地质》2016,(1):54-59

利用PHREEQC软件模拟CO2侵入后,尕斯库勒盐湖中CO2-卤水-岩盐之间的相互作用。CO2侵入卤水层后,卤水中元素的化学形态种类和大小发生变化,特别是碳酸盐型的络合物形态增多。CO2侵入后,除了碳酸盐、石盐和硫酸盐矿物达到饱和被析出外,其余矿物的不饱和程度加剧,卤水的TDS增大,pH值减小。卤水中U的含量在CO2侵入后发生沉淀而减小。研究成果对深入评估区域内盐水层CO2地质封存的环境风险和利用CO2分离提取盐湖卤水中的铀元素提供理论依据。  相似文献   

深孔用高钢级绳索取心钻杆分区热处理工艺试验研究          下载免费PDF全文

彭莉  梁健  蔡纪雄  杨金东  孙环平  孙建华 《探矿工程》2016,43(9):14-19

为改善绳索取心钻杆受力工况,延长钻杆使用寿命,满足深孔及特深孔钻探施工要求,开展了对绳索取心钻杆体进行分区热处理工艺的试验研究。试验选用高钢级薄壁管材,通过对钻杆两端300 mm左右的区间内进行盐浴淬火及高温回火处理,保证了调质区域的机械性能,硬度和金相组织均匀性良好,同时热处理过渡带影响区域小。试制加工的特深孔绳索取心钻杆具有两端部螺纹连接段刚性强、杆体中部韧性好的特点。该钻杆在山东莱州西岭村矿区完成了2845.55 m深孔的钻进施工,使用情况良好。  相似文献   

白杨河矿区煤层气丛式井钻井难点及对策研究          下载免费PDF全文

毛志新  谢相军  汤建江 《探矿工程》2016,43(12):37-40

新疆阜康市白杨河矿区煤层气开发利用先导性示范工程是新疆第一个煤层气示范工程项目。白杨河矿区总体构造为向南倾斜的单斜构造,地层倾角大,煤层多且间距大。该示范工程开发方案主要井型为丛式井。经过多年钻井实践,丛式井钻井技术在鄂尔多斯盆地东缘煤层气区块已经非常成熟,初步形成了一套适合该地区煤层气开发的丛式井钻井技术。由于白杨河矿区地质条件与鄂尔多斯盆地东缘各区块相比差异大,特别是存在地层倾角大、煤层多且间距大等地质特点,因此不能完全照搬原有的丛式井钻井技术。本文依据白杨河矿区地质资料,分析了白杨河矿区煤层气丛式井钻井难点,对解决该区块钻井难点的技术对策和攻关思路进行了总结与阐述,初步形成了一套适合白杨河矿区大倾角厚煤层的丛式井钻井技术。  相似文献   

2001年秋季风对坦帕湾盐度平衡的影响     

韩树宗  朱君  范永斌  戚洪帅  王星驰 《海洋学报(英文版)》2016,35(9):67-73

利用三维高分辨率有限体积的近海海域模型FVCOM来分析2001年秋季期间风作用对坦帕湾区域盐度平衡的影响。为了区分风的影响,分别设计了两个实验：一个由潮汐和河流作为驱动,另一个由潮汐、河流以及风场共同驱动。结论如下：首先,风作用会使盐度产生变化,能够明显地使坦帕湾内的盐度增加,并导致水平和垂直方向上盐度梯度的减少;随后,本文分析了坦帕湾区域内的盐度平衡,主要的盐度平衡来自于全部（水平和垂直方向上）平流的盐度流量分歧以及除去海峡底部的垂直方向上盐度流量分歧;最后,对由风引起的盐度变化进一步进行分析,结果表明风作用不能改变盐度平衡地位的相对重要性,由风引起的盐度平衡改变高度依靠于特殊的地形,除此之外,全部平流盐度流量分歧和垂直散布盐度通量分歧能够抵消,并且两者都远大于水平散步盐度流量分歧。  相似文献   

Paratacamite from Gypsum Veins in Sandstones of the Kuqa Basin,Xinjiang, China: Implications for a New Epigenetic Cu Enrichment Mechanism          下载免费PDF全文

Yangtong Cao  Chenglin Liu  Pengcheng Jiao  Chunlian Wang 《Resource Geology》2016,66(2):114-126

The Kuqa Basin filled with Paleogene evaporite series is located in the northeast of the Tarim Basin, Xinjiang, China. It is famous for sandstone‐hosted Cu deposits formed by synsedimentary processes. However, our recent studies reveal that there has been another Cu mineralization mechanism in this basin. Field investigations show that there is a close relationship among faults, salt domes, and brine. Cu deposits are mainly located in two east–west‐trending anticlinal belts in the basin, adjacent to salt domes in the belts. Cu minerals in gypsum veins of the Jidike and Kangcun formations have been investigated by SEM, EDS, and X‐ray diffraction methods. The occurrence of paratacamite in gypsum veins has been reported to coexist with glauberite and halite in the joint planes of sandstones. In addition, it occurs accompanying residual crystal salt encrustation in limestone fractures, or in sandstones in dendritic form. These features indicate that the surface‐Cu enrichment in the Kuqa Basin might have originated from Cu‐bearing brine in the underlying evaporite units, which migrated upward along fractures. In addition, the presence of H₂S in the east–west fault belt in the Kuqa Basin, and the discovery of surface sulfur, calcium carbonate, and covellite, suggest thermochemical sulfate reduction near salt domes in the deeper parts of the rock units. This process resulted in the generation of reduced brine and provided a favorable environment for Cu enrichment. Therefore, the surface‐Cu mineralization near salt domes is interpreted to be the result of Cu‐bearing brine migrating upward to the surface along faults (or joints) following the intrusion of deep salt domes. The geological evidence indicates the presence of reducing brine and Cu‐bearing brine near the salt dome in the deeper rocks of the Kuqa Basin, thus making the intrusive contact zone of the salt dome a favorable site for the epigenetic enrichment of Cu. Our study demonstrates that Cu enrichment in the Kuqa Basin resulted not only from synsedimentary deposition but also through epigenetic enrichment associated with salt dome intrusion and brine‐rich fluids.  相似文献   

深部盐矿勘探钻井液研究与应用   总被引：2，自引：0，他引：2       下载免费PDF全文

黄河  乌效鸣  景龙  常林祯  刘超  李伟 《盐湖研究》2016,24(4):16-22

ZK001井钻遇地层为大段泥岩,部分地层为页岩、含盐泥岩、盐膏层。在泥页岩地层进行大口径全面钻进,钻速较快,固控设备能力有限,引起钻屑中粘土颗粒重复性膨胀、软化及裂解分散,最终可能造成粘土侵,对井内安全造成威胁。深部岩膏层易溶于水,从而导致盐层蠕变、井径扩大、井壁失稳等问题。以ZK001井为例,通过优化钻井液体系及现场施工工艺,解决了地层强造浆、盐层失稳等问题。通过岩石力学测试、阳离子交换容量测试、钻井液体系优选及性能测试,确定了上部地层采用聚合物钻井液体系,下部含盐层取芯钻进转换为饱和盐水钻井液体系。通过选用合适的钻井液密度、粘度、切力量、滤失量、含盐量等指标,可以有效控制上部泥岩井壁稳定、含盐层蠕变、井径扩大的问题。钻进过程中钻井液性能稳定且易于维护,从而保证了钻进工作安全、高效、顺利的进行。  相似文献