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81.
Analysis of fly-ash particles in lake sediments has become increasingly important in studies of environmental pollution and lake acidification history. Most fly-ash studies have concerned black spheroidal carbonaceous particles (SCP)(>5 m) produced from oil and coal combustion. This review paper provides a summary of this technique and its application, and focusses on our investigations in Sweden between 1979 and 1993. It consists of five parts: i) preparation and analysis methods, ii) historical trends in atmospheric deposition, iii) geographical surveys of atmospheric deposition, iv) sediment dating, and v) studies of sedimentation processes in lakes. Methods for preparation and analyses of SCP have been developed and applied to investigations using sediment, soil and snow samples. Stratigraphic trends of SCP concentrations in lake-sediment cores reflect the consumption history of fossil fuels. A characteristic temporal SCP pattern, with a marked concentration increase beginning after the 1940's and a peak in the early 1970's, has been recognized in most Swedish lakes and elsewhere in Europe. A survey of SCP concentrations in surface sediments of >100 lakes covering Sweden demonstrated that polluted areas in southern Sweden had >100 times higher SCP concentrations than clean areas in the north. The spatial distribution of SCP over Sweden is similar to the deposition pattern of long-range transported airborne pollutants, such as excess sulphate monitored by network stations. SCP also accumulate in soils, and soil analyses can be used for determining the integrated historical deposition of SCP at the local or regional scale. Finally, SCP have been used for indirect dating of sediment cores and as a marker to assess sediment distribution patterns within lake basins. 相似文献
82.
镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口,也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同:蛇绿岩以产出铬铁矿床为特征,阿拉斯加型岩体主要赋含铂族元素(PGE)矿床,大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关,但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程,而极少关注流体作用。近年来,实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用,同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为,刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素,已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题,总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录,提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用,强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。 相似文献
83.
钻遇莫霍面是人类一直以来的梦想。深海海底是地球上离莫霍面最近的地方,目前有研究推测南海是世界上莫霍面深度最浅的海域之一,但缺乏足够的直接证据。深反射地震探测可以直接揭示岩石圈的构造形态,是莫霍面探测的重要手段。本文基于长达15000 km的深反射多道地震剖面的解释、处理、制图和分析,结合前人的研究,形成了南海海盆区莫霍面反射特征和空间分布的初步认识。① 南海东部次海盆南部早期经历了较快速扩张,岩浆供应充足,受扩张停止后岩浆活动影响较小,基底平坦,地质构造相对简单,同时洋壳地震速度结构不存在异常,且有较强的广角莫霍面反射波和可识别的地幔顶部折射波,具备莫霍面钻探的基本条件。② 南海海盆不同区域的莫霍面反射强度存在较大差异。其中东部次海盆莫霍面反射最为强烈且清晰,西北次海盆次之,西南次海盆仅有零星出现的清晰莫霍面反射且可信度不高。③ 识别南海海盆区莫霍面地震反射长度超过3500 km,首次形成了海盆区深度域莫霍面地震反射空间分布图。与重力反演的莫霍面深度相比,利用深反射多道地震计算的莫霍面深度细节更为丰富,并且可以在垂向上清晰刻画莫霍面的结构。整体上,南海海盆区莫霍面地震反射强烈和可信度高的区域中,深度较浅的区域之一是东部次海盆南部,最浅处仅约9. 5 km,其中水深4. 01 km,洋壳厚度仅5. 54 km。综合判断,东部次海盆南部是南海重要的莫霍面钻探备选区,这对南海莫霍面钻探选址具有重要意义。 相似文献
84.
梅世蓉 《地震学报(英文版)》1995,(3)
Onthephysicalmodelofearthquakeprecursorfieldsandthemechanismofprecursors'timespacedistribution──originandevidencesof thestron... 相似文献
85.
Treatment of high fluoride concentration wastewater by layered double hydroxides: Mechanism studies 总被引:1,自引:0,他引:1
Liang LU Jing HE 《中国地球化学学报》2006,25(B08):160-161
An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides (LDHs) are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China. 相似文献
86.
CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174
Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition. 相似文献
87.
A numerical procedure is described for the analysis of the vertical deformation and the stress distribution of the strip footings
on layered soil media. Three layers of soil with different stiffness are considered with the middle soil layer the thinnest
and most stiff layer. The soil media is discretized and using the theory of elasticity, the governing differential equations
are obtained in terms of vertical and horizontal displacements. These equations along with appropriate boundary and continuity
conditions are solved by using the finite difference method. The vertical and horizontal displacements, strains and stresses
are found at various nodes in the soil media. Parametric studies are carried out to study the effect of the placement depth
of the middle soil layer, the relative ratios of the moduli of deformation of the soil layers on the vertical displacement
of the footing and the vertical stress distribution. These studies reveal that the middle thin but very stiff layer acts like
a plate and redistributes the stresses on the lower soft soil layer uniformly. The displacement on the top and bottom of the
middle soil layer is almost the same showing that the compression of the middle layer is negligible as it is very stiff. 相似文献
88.
Thomas O. Graff 《The Professional geographer》2006,58(1):54-64
The three largest discount chains, Kmart, Target, and Wal‐Mart, have adopted the supercenter format for expansion. This article examines the locations of and the competition among these supercenters. Wal‐Mart has the greatest number of supercenters and is driving the expansion of the supercenter format. Both Kmart and Target have clustered their supercenters in a small number of metropolitan markets. In contrast to Wal‐Mart and Kmart, Target has focused on a middle‐class rather than a blue‐collar clientele. Now Kmart is struggling following a declaration of bankruptcy. Wal‐Mart has largely defeated its supercenter competitors and now is confronting the major grocery chains for grocery sales. 相似文献
89.
90.
Fred J. Anderson 《Environmental Geology》2006,49(7):1034-1042
Several unfavorable environmental and engineering geologic conditions exist in Fargo, North Dakota. Dominantly, the behavior
of smectitic clays within the proglacial Lake Agassiz sediments of the Sherack and Brenna Formations creates subsoil instability
beneath engineered structures in the Fargo area and slope instability within cutbank meanders of the Red River of the North.
Unfavorable engineering geologic conditions encountered include: the elastic deformation of clayey glaciolacustrine soils,
shrink-swell properties, inadequate bearing capacities, and mass movements. These conditions are responsible for structural
failures including the Fargo Grain Elevator in 1955 and the Northern Pacific railroad grade. Bank failures along the Red River
are common due to the inherent instability of Brenna Formation smectitic clays which are subject to plastic deformation in
the subsurface, with resultant block failure of overlying Sherack Formation. Recent alluvial sediments due to typical fluvial
action and the continued seasonal saturation of cutbank meanders within the floodplain also add to soil instability. 相似文献