Longevity of fluorine-bearing tremolite on Venus     

Natasha M. Johnson  Bruce Fegley Jr. 《Icarus》2003,165(2):340-348

There is a general belief that hydrous minerals cannot exist on Venus under current surface conditions. This view was challenged when Johnson and Fegley (2000, Icarus 146, 301-306) showed that tremolite (Ca₂Mg₅Si₈O₂₂(OH)₂), a hydrous mineral, is stable against thermal decomposition at current Venus surface temperatures, e.g., 50% decomposition in 4 Ga at 740 K. To further explore hydrous mineral thermal stability on Venus, we experimentally determined the thermal decomposition kinetics of fluorine-bearing tremolite. Fluor-tremolite is thermodynamically more stable than OH-tremolite and should decompose more slowly. However how much slower was unknown. We measured the decomposition rate of fluorine-bearing tremolite and show that its decomposition is several times to greater than ten times slower than that of OH-tremolite. We also show that F-bearing tremolite is depleted in fluorine after decomposition and that fluorine is lost as a volatile species such as HF gas. If tremolite ever formed on Venus, it would probably also contain fluorine. The exceptional stability of F-bearing tremolite strengthens our conclusions that if hydrous minerals ever formed on Venus, they could still be there today.  相似文献   

Fast iterative solution of large undrained soil‐structure interaction problems     

Kok‐Kwang Phoon  Swee‐Huat Chan  Kim‐Chuan Toh  Fook‐Hou Lee 《国际地质力学数值与分析法杂志》2003,27(3):159-181

In view of rapid developments in iterative solvers, it is timely to re‐examine the merits of using mixed formulation for incompressible problems. This paper presents extensive numerical studies to compare the accuracy of undrained solutions resulting from the standard displacement formulation with a penalty term and the two‐field mixed formulation. The standard displacement and two‐field mixed formulations are solved using both direct and iterative approaches to assess if it is cost‐effective to achieve more accurate solutions. Numerical studies of a simple footing problem show that the mixed formulation is able to solve the incompressible problem ‘exactly’, does not create pressure and stress instabilities, and obviate the need for an ad hoc penalty number. In addition, for large‐scale problems where it is not possible to perform direct solutions entirely within available random access memory, it turns out that the larger system of equations from mixed formulation also can be solved much more efficiently than the smaller system of equations arising from standard formulation by using the symmetric quasi‐minimal residual (SQMR) method with the generalized Jacobi (GJ) preconditioner. Iterative solution by SQMR with GJ preconditioning also is more elegant, faster, and more accurate than the popular Uzawa method. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Analytical solutions of one‐dimensional infiltration before and after ponding     

Jiann‐Mou Chen  Yih‐Chi Tan  Chu‐Hui Chen 《水文研究》2003,17(4):815-822

This paper is a continuation of previous research, which obtained a convenient solution for arbitrary surface fluxes before ponding. By means of Fourier Transformation this has been extended to derive analytical solutions of a linearized Richards' equation for arbitrary input fluxes after surface saturation. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Sea‐surface temperature and salinity changes in the northwest Pacific since the Last Glacial Maximum     

Tadamichi Oba  Masafumi Murayama 《第四纪科学杂志》2004,19(4):335-346

The oxygen isotope records of both benthic and planktonic Foraminifera in five piston cores, collected from the region between the Oyashio and Kuroshio Currents near Japan, clearly show the marked latitudinal shifts of these two currents during the past 25 kyr. Under the present hydrographic condition, a clear relationship between the sea‐surface temperature (SST) and oxygen isotope differences from benthic to planktonic Foraminifera is observed in this region. Using this relationship, we find decreased SSTs of 12–13°C (maximum 15°C) in the southernmost core site at the Last Glacial Maximum (LGM), indicating the Oyashio Current shifted southward. The SSTs at the southern two core sites abruptly increased more than 10°C at 10–11 ka, suggesting the Kuroshio Current shifted northward over these sites at 10–11 ka. In contrast, the northern two core sites have remained under the influence of the cold Oyashio Current for the past 25 kyr. With the reasonable estimate of bottom‐water temperature decrease of 2.5°C at the LGM, the SSTs estimated by this new method give exactly the same SST values calculated from Mg/Ca ratio of planktonic Foraminifera, allowing palaeosea‐surface salinities to be reconstructed. The result suggests that the ice volume effect was 1.0 ± 0.1‰ at the LGM. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Reliability assessment of serviceability performance of braced retaining walls using a neural network approach     

A. T. C. Goh  F. H. Kulhawy 《国际地质力学数值与分析法杂志》2005,29(6):627-642

In urban environments, one major concern with deep excavations in soft clay is the potentially large ground deformations in and around the excavation. Excessive movements can damage adjacent buildings and utilities. There are many uncertainties associated with the calculation of the ultimate or serviceability performance of a braced excavation system. These include the variabilities of the loadings, geotechnical soil properties, and engineering and geometrical properties of the wall. A risk‐based approach to serviceability performance failure is necessary to incorporate systematically the uncertainties associated with the various design parameters. This paper demonstrates the use of an integrated neural network–reliability method to assess the risk of serviceability failure through the calculation of the reliability index. By first performing a series of parametric studies using the finite element method and then approximating the non‐linear limit state surface (the boundary separating the safe and ‘failure’ domains) through a neural network model, the reliability index can be determined with the aid of a spreadsheet. Two illustrative examples are presented to show how the serviceability performance for braced excavation problems can be assessed using the reliability index. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Fresnel modeling of hematite crystal surfaces and application to martian hematite spherules     

Timothy D. Glotch  Philip R. Christensen  Thomas G. Sharp 《Icarus》2006,181(2):408-418

The gray crystalline hematite at Meridiani Planum first discovered by the Mars Global Surveyor Thermal Emission Spectrometer (MGS-TES) instrument occurs as spherules that have been interpreted as concretions. Analysis of the TES and mini-TES spectra shows that no 390 cm⁻¹ feature is present in the characteristic martian hematite spectrum. Here, we incorporate the mid-IR optical constants of hematite into a simple Fresnel reflectance model to understand the effect of emission angle and crystal morphology on the presence or absence of the 390 cm⁻¹ feature in an IR hematite spectrum. Based on the results we offer two models for the internal structure of the martian hematite spherules.  相似文献   

Subtidal sea level and current variations in the northern reach of San Francisco Bay     

Roy A. Walters  Jeffrey W. Gartner 《Estuarine, Coastal and Shelf Science》1985,21(1):17-32

Analyses of sea level and current-meter data using digital filters and a variety of statistical methods show a variety of phenomena related to non-local coastal forcing and local tidal forcing in the northern reach of San Francisco Bay, a partially mixed estuary. Low-frequency variations in sea level are dominated by non-local variations in coastal sea level and also show a smaller influence from tidally induced fortnightly sea level variations. Low-frequency currents demonstrate a gravitational circulation which is modified by changes in tidal-current speed over the spring-neap tidal cycle. Transients in gravitational circulation induce internal oscillations with periods of two to four days.  相似文献   

The importance of oxygen isotope provenance in relation to solute content of bulk meltwaters at Imersuaq Glacier,West Greenland     

Jacob C. Yde  N. Tvis Knudsen 《水文研究》2004,18(1):125-139

Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s^?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ¹⁸O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), SO₄^2? and δ¹⁸O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl^? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ¹⁸O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ¹⁸O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

The Preboreal climate reversal and a subsequent solar‐forced climate shift     

J. van der Plicht  B. van Geel  S. J. P. Bohncke  J. A. A. Bos  M. Blaauw  A. O. M. Speranza  R. Muscheler  S. Bjrck 《第四纪科学杂志》2004,19(3):263-269

Accurate chronologies are essential for linking palaeoclimate archives. Carbon‐14 wiggle‐match dating was used to produce an accurate chronology for part of an early Holocene peat sequence from the Borchert (The Netherlands). Following the Younger Dryas–Preboreal transition, two climatic shifts could be inferred. Around 11 400 cal. yr BP the expansion of birch (Betula) forest was interrupted by a dry continental phase with dominantly open grassland vegetation, coeval with the PBO (Preboreal Oscillation), as observed in the GRIP ice core. At 11 250 cal. yr BP a sudden shift to a humid climate occurred. This second change appears to be contemporaneous with: (i) a sharp increase of atmospheric ¹⁴C; (ii) a temporary decline of atmospheric CO₂; and (iii) an increase in the GRIP ¹⁰Be flux. The close correspondence with excursions of cosmogenic nuclides points to a decline in solar activity, which may have forced the changes in climate and vegetation at around 11 250 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

The influence of macrophyte growth,typical of eutrophic conditions,on river flow velocities and turbulence production     

Pamela Naden  Ponnambalam Rameshwaran  Owen Mountford  Coralie Robertson 《水文研究》2006,20(18):3915-3938

The influence of emergent and submerged macrophytes on flow velocity and turbulence production is demonstrated in a 140 m reach of the River Blackwater in Farnborough, Hampshire, UK. Macrophyte growth occurs in patches and is dominated by Sparganium erectum and Sparganium emersum. In May 2001, patches of S. erectum were already established and occupied 18% of the channel area. The flow adjusted to these (predominantly lateral) patches by being channelled through a narrower cross‐section. The measured velocity profiles showed a logarithmic form, with deviations attributable to topographic control. The channel bed was the main source of turbulence. In September 2001, in‐stream macrophytes occupied 27% of the channel, and overhanging bank vegetation affected 32% of the area. Overall flow resistance, described by Manning's n, showed a threefold increase that could be attributed to the growth of S. emersum in the middle of the channel. Velocity profiles showed different characteristic forms depending on their position relative to plant stems and leaves. The overall velocity field had a three‐dimensional structure. Turbulence intensities were generally higher and turbulence profiles tended to mirror the velocity profiles. Evidence for the generation of coherent eddies was provided by ratios of the root mean square velocities. Spectral analysis identified deviations from the Kolmogorov ?5/3 power law and provided statistical evidence for a spectral short‐cut, indicative of additional turbulence production. This was most marked for the submerged vegetation and, in some instances, the overhanging bank vegetation. The long strap‐like leaves of S. emersum being aligned approximately parallel to the flow and the highly variable velocity field created by the patch arrangement of macrophytes suggest that the dominant mechanism for turbulence production is vortex shedding along shear zones. Wake production around individual stems of S. emersum close to the bed may also be important locally. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献