絮凝法强化大生活用海水一级处理研究   总被引：3，自引：0，他引：3  

张雨山  王静  寇希元  单科 《海洋技术学报》2002,21(4):57-60

研究了无机絮凝剂石灰、硫酸铝、聚合氯化铝、聚合硫酸铁和氯化铁单独使用及其与有机高分子絮凝剂聚丙烯酰胺（PAM）配合使用时强化大生活用海水一级处理的效果，结果表明，无机絮凝剂与有机絮凝剂配合使用时有很好的强化效果，COD去除率最高达61%，且对SS和BOD也有一定的去除效果。  相似文献   

天津港南部海区水体富营养化水平评价   总被引：1，自引：0，他引：1  

曹佳莲  刘宪斌  刘占广  聂利红  纪明航 《海洋湖沼通报》2007,(Z1)

根据2006年3月和7月的调查数据,对天津港南部海区海水的营养水平及动态变化进行了评价。考虑到水质状况和水体营养水平是水体中多项指标分析评价的综合结果.本文先通过单项指标评价法和营养指数法进行评价。然后又通过集对分析方法,选择化学需氧量(COD)、无机磷(DIP)、无机氮(DIN)、叶绿素a(Ch1—a)等作为评价指标,对该区海水富营养化水平进行了综合评价。评价结果表明集对分析方法更能反映海水的实际富营养化状况,计算结果显示天津港南部海域两期调查中除21,26.27和29站位在7月呈富营养化状态其余站位海水均在中营养(Ⅳ)及以下水平状况,未达到富营养化水平,水质状况较好。  相似文献   

长江口海水的密度   总被引：1，自引：1，他引：1  

陈国华  胡博路  张力军  季荣  金建成 《海洋与湖沼》1992,23(6):573-580

为了核对1980年国际海水状态方程应用于中国近岸海水的可靠性,高精度的磁力浮沉子密度计在15—25℃,盐度5—35,一个大气压条件下,测量了长江口附近海水及其人工稀释海水的相对密度。结果表明,海水密度直接测量值系统地偏高于状态方程计算值,二者之间的偏差随水样盐度值降低而增大,且与海水[Ca~(2+))/s比值成明显正相关关系。经计算机拟合,导出了长江口附近海水及其稀释海水的状态方程,该方程计算值与实验值的平均标准偏差为±3.9×10~(-3)kg/m~3。  相似文献   

胜利二号极浅海步行坐底式钻井平台防腐措施研究     

董韩扬 《海洋工程》1994,12(3):17-22

本文根据胜利二号极浅海步行坐底钻井平台的作业和工作环境特点，进行了防腐措施研究，设计了切合实际的防腐措施。该平台在海上作业近四年进坞修理，经观测防腐情况良好。  相似文献   

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO₂ levels     

Shane M. Ohline  Malcolm R. Reid  Shamus L.G. Husheer  Kim I. Currie  Keith A. Hunter 《Marine Chemistry》2007

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].  相似文献   

解决山东水资源短缺的对策   总被引：1，自引：0，他引：1  

刘洪滨 《海岸工程》1995,14(4):37-42

分析了山东省水资源现状和存在的主要问题，针对山东省水资源的严重短缺，提出了在传统用水、治水的基础上，实施人工增雨工程，直接利用海水和海水淡化与节约用水，建立节水型社会，调整水源结构，更新用水观念，开发新水源，综合用水，综合治水的路子，只有这样才能长久解决水危机。  相似文献   

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER     

张正斌  杨长春  刘莲生 《中国海洋湖沼学报》1992,(2)

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c  相似文献   

Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A     

Lui-Heung Chan  Jeffrey C Alt 《Earth and Planetary Science Letters》2002,201(1):187-201

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.  相似文献   

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS   总被引：6，自引：1，他引：6  

Alistair B. Jeffcoate  Tim Elliott  Alex Thomas  Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.  相似文献   

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)     

M. Roy-Barman  C. Jeandel  M. Souhaut  M. Rutgers van der Loeff  I. Voege  N. Leblond  R. Freydier 《Earth and Planetary Science Letters》2005,240(3-4):681-693

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.  相似文献