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101.
西宝山耐火黏土矿为沉积型矿床,目前揭露1个耐火黏土矿矿层,赋存于石盒子群万山组底部“B”层黏土岩的下部,厚度较稳定,勘查开发潜力较大。通过对其地质特征、矿层特征、矿石结构构造及矿床成因分析,提出了找矿方向。认为该耐火黏土矿受沉积地层控制,呈层状分布,分布较稳定。依据该区地层产出情况,在青龙山断裂与禹王山断裂之间及两侧均具有良好的找矿前景,这为下一步找矿工作奠定了基础。  相似文献   
102.
Groundwater arsenic (As) presents a public health risk of great magnitude in densely populated Asian delta regions, most acutely in the Bengal Basin (West Bengal, India and Bangladesh). Research has focused on the sources, mobilisation, and heterogeneity of groundwater As, but a consistent explanation of As distribution from local to basin scale remains elusive. We show for the Bengal Aquifer System that the numerous, discontinuous silt‐clay layers together with surface topography impose a hierarchical pattern of groundwater flow, which constrains As penetration into the aquifer and controls its redistribution towards discharge zones, where it is re‐sequestered to solid phases. This is particularly so for the discrete periods of As release to groundwater in the shallow subsurface associated with sea level high‐stand conditions of Quaternary inter‐glacial periods. We propose a hypothesis concerning groundwater flow ( S ilt‐clay layers I mpose H ierarchical groundwater flow patterns constraining A rsenic progression [SIHA]), which links consensus views on the As source and history of sedimentation in the basin to the variety of spatial and depth distributions of groundwater As reported in the literature. SIHA reconciles apparent inconsistencies between independent, in some cases contrasting, field observations. We infer that lithological and topographic controls on groundwater flow, inherent to SIHA, apply more generally to deltaic aquifers elsewhere. The analysis suggests that groundwater As may persist in the aquifers of Asian deltas over thousands of years, but in certain regions, particularly at deeper levels, As will not exceed low background concentrations unless groundwater flow systems are short‐circuited by excessive pumping.  相似文献   
103.
A computational framework is presented for dynamic strain localization and deformation analyses of water‐saturated clay by using a cyclic elasto‐viscoplastic constitutive model. In the model, the nonlinear kinematic hardening rule and softening due to the structural degradation of soil particles are considered. In order to appropriately simulate the large deformation phenomenon in strain localization analysis, the dynamic finite element formulation for a two‐phase mixture is derived in the updated Lagrangian framework. The shear band development is shown through the distributions of viscoplastic shear strain, the axial strain, the mean effective stress, and the pore water pressure in a normally consolidated clay specimen. From the local stress–strain relations, more brittleness is found inside the shear bands than outside of them. The effects of partially drained conditions and mesh‐size dependency on the shear banding are also investigated. The effect of a partially drained boundary is found to be insignificant on the dynamic shear band propagation because of the rapid rate of applied loading and low permeability of the clay. Using the finer mesh results in slightly narrower shear bands; nonetheless, the results manifest convergency through the mesh refinement in terms of the overall shape of shear banding and stress–strain relations. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
104.
A bounding surface model is formulated to simulate the behavior of clays that are subject to an anisotropic consolidation stress history. Conventional rotational hardening is revisited from the perspective of thermodynamics. As the free energy cannot be accumulated infinitely upon critical state failure, the deviatoric back stress must vanish. This requires the rotated yield surface to be turned back to eventually align on the hydrostatic axis in the stress plane. Noting that most of the previous propositions violate this restriction, an innovative rotational hardening rule is formulated that is thermodynamically admissible. The bounding surface framework that employs the modified yield surface is applied to simulate elastoplastic deformations for overconsolidated clays, with which the overprediction of strength on the “dry” side can be greatly improved with reasonable results. Other important features, including contractive or dilative response and hardening or softening behavior, can also be well-captured. It has been shown that the model can simulate three types of reconstituted clays that are sheared with initial conditions over a wide range of anisotropic consolidation stress ratios and overconsolidation ratios under both triaxial undrained and drained conditions. Limitations and potential improvement of the model regarding the fabric anisotropy at critical state have been discussed.  相似文献   
105.
Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ2H and δ18O of soil water isotope ratios.  相似文献   
106.
A detailed multiscale analysis is presented of the swelling phenomenon in unsaturated clay-rich materials in the linear regime through homogenization. Herein, the structural complexity of the material is formulated as a three-scale, triple porosity medium within which microstructural information is transmitted across the various scales, leading ultimately to an enriched stress-deformation relation at the macroscopic scale. As a side note, such derived relationship leads to a tensorial stress partitioning that is reminiscent of a Terzaghi-like effective stress measure. Otherwise, a major result that stands out from previous works is the explicit expression of swelling stress and capillary stress in terms of micromechanical interactions at the very fine scale down to the clay platelet level, along with capillary stress emerging due to interactions between fluid phases at the different scales, including surface tension, pore size, and morphology. More importantly, the swelling stress is correlated with the disjoining forces due to electrochemical effects of charged ions on clay minerals and van der Waals forces at the nanoscale. The resulting analytical expressions also elucidate the role of the various physics in the deformational behavior of clayey material. Finally, the capability of the proposed formulation in capturing salient behaviors of unsaturated expansive clays is illustrated through some numerical examples.  相似文献   
107.
Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
108.
This paper presents a granular computing approach to spatial classification and prediction of land cover classes using rough set variable precision methods. In particular, it presents an approach to characterizing large spatially clustered data sets to discover knowledge in multi-source supervised classification. The evidential structure of spatial classification is founded on the notions of equivalence relations of rough set theory. It allows expressing spatial concepts in terms of approximation space wherein a decision class can be approximated through the partition of boundary regions. The paper also identifies how approximate reasoning can be introduced by using variable precision rough sets in the context of land cover characterization. The rough set theory is applied to demonstrate an empirical application and the predictive performance is compared with popular baseline machine learning algorithms. A comparison shows that the predictive performance of the rough set rule induction is slightly higher than the decision tree and significantly outperforms the baseline models such as neural network, naïve Bayesian and support vector machine methods.  相似文献   
109.
何海军 《地质与勘探》2016,52(3):584-593
本文以南海北部湾SO-31沉积柱为研究对象,研究了14C年代学和粘土矿物学特征,并对部分全球气候事件进行了对比,为古环境、古气候的恢复提供基础资料,也为全球重大气候事件在该区域的响应提供信息。结果显示全新世以来地层沉积正常,平均沉积速率为0.57mm/a。粘土成分主要由蒙脱石、伊利石、高岭石和绿泥石组成,组合类型为蒙脱石-伊利石-高岭石-绿泥石型。全新世以来环境气候演变可划分为五个阶段:低温期阶段、干湿交替的寒冷气候阶段、逐渐升温阶段、干旱温暖气候阶段、湿热阶段。气候在每个阶段背景下还存在一些次级波动,总体趋势为干湿交替,温度逐渐上升。由于海域环境及矿物指标的影响,北部湾SO-31沉积柱粘土矿物记录的降温事件时间比其他指标记录的新仙女木降温事件发生时间滞后500~800a。  相似文献   
110.
连接扬子地块和华夏地块的江南造山带是华南前寒武纪最重要的构造单元,其形成和演化长期以来备受关注。在江南造山带的范围内广泛发育了新元古代岩浆岩,它们是探讨江南造山带构造演化的重要对象,但其成因和形成的构造背景却备受争论。本文系统收集和分析了江南造山带830~820 Ma花岗岩、800~780 Ma酸性岩和800~750 Ma基性岩的地球化学数据。研究表明,不同时间段的岩石成因类型存在系统差异,830~820 Ma的花岗岩主要为S型花岗岩,800~780 Ma的酸性岩主要为A型酸性岩,而800~750 Ma的基性岩以拉斑系列和碱性系列为主,并在构造判别图中显示了板内玄武岩(WPB)和洋中脊玄武岩(MORB)的特征。综合同位素年代学、岩石地球化学和沉积学等学科领域的研究成果我们认为:扬子北缘和西缘应先于东南缘在1000~900 Ma期间发生碰撞,而此时的东南缘仍为活动大陆边缘;直到~830 Ma,扬子地块与华夏地块沿江南造山带发生拼贴,但只是陆-弧-(微)陆之间的"软碰撞",而无山脉隆升和高级变质作用,各个块体之间处于"联而不合"的状态,大洋岩石圈拆沉之后的软流圈上涌和由拆沉所引起的拉张作用导致了上覆岩石圈和陆壳发生部分熔融,产生了江南造山带830~820 Ma的S型花岗岩;随着全球Rodinia超大陆的裂解,~820 Ma,华南裂谷盆地开启,并在随后的裂解过程中发育了大量与伸展有关的800~780 Ma A型酸性岩和基性岩脉/墙,而其明显高于同时代MORB源区的地幔潜能温度显示,导致Rodina超大陆裂解的地幔柱可能对该时期岩浆岩的地幔源区有一定影响;随着拉张作用的不断加强,出现了760~750 Ma碱性系列和具MORB特征的基性岩,此时的软流圈地幔既提供热量又有物质供应。  相似文献   
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