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71.
E. Ovando-Shelley 《Geotechnical and Geological Engineering》1995,13(1):1-16
Summary This paper presents results of static and cyclic direct shear tests performed on undisturbed and remoulded samples of Mexico City clays, including results of soil-on-interface tests. Experiments show that the static adhesion coefficient depends on the soils' liquidity index and that it diminishes due to the effect of repeated dynamic loads. Dynamic overstrength effects were not apparent, as has been observed when testing this clay in other apparatus. Interface strength in remoulded clays is initially less than half the strength of interfaces with undisturbed materials but it increases with time. At least in the materials tested in this research, it did not equal the strength of interfaces with undisturbed materials. Correction factors derived from experimental data can be used to modify the adhesion coefficient to account for dynamic and remoulding effects. 相似文献
72.
73.
Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l-1 and from 1.4 to 11.3 nmol m-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m-2 d-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m-2 d-1, respectively. 相似文献
74.
W. Kirchner F. Welter A. Bongartz J. Kames S. Schweighoefer U. Schurath 《Journal of Atmospheric Chemistry》1990,10(4):427-449
A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO3 (0.01), N2O5 (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored. 相似文献
75.
Franco Tassi Orlando Vaselli Elena Lognoli Fabrizio Cuccoli Barbara Nisi Elena Ramaldi Sandro Moretti Luca Lombardi Bruno Capaccioni 《中国地球化学学报》2006,25(B08):70-71
Mt. Amiata (Southern Tuscany, Central Italy) is an extinct Quaternary volcano located in an area still marked by high heat-flow that is caused by deep seated (6-10 km) hot masses related to Pliocene magmatic activity. The anomalous geothermal gradient gives rise, within the Mesozoic limestone formation (Tuscan series), to geothermal systems that fed the Ca-SO4 thermal springs characterizing this area. Besides of thermal fluids, several cold, dry CO2-rich gas emissions seep out on the NE flank of the volcano. These gas vents mostly consist of large sub-circular craters at variable depth and diameter (5-15 m and 10-50 m, respectively), and represent a serious hazard for the local population, as testified by the several asphyxia casualties that have been repeatedly occurred within these morphological depressions. In this work, the chemical and isotopic compositions of the Mt. Amiata "CO2-rich gas vents" and the estimation of both the CO2 flux from the soil and the CO2 distribution in air of their surroundings, has been carried out in order to: (1) assess the origin of gases, (2) recognize the mechanism of formation for these gas emissions and their relationship with local tectonics, and (3) to evaluate the CO2 hazard in the high flux emanations. The chemical composition of the gases is largely dominated by CO2 (up to 98 % by vol) and shows relatively high concentrations of N2, CH4 and H2S (up to 1.1%, 0.9% and 3.9 % by vol, respectively). These features, coupled with the carbon and nitrogen isotopic signatures, suggest that the origin of the main gas compounds may be related to the contribution of deep (i.e., thermometamorphic processes on carbonate formations for CO2) and shallow (i.e. thermal decomposition of organic material for CH4, N2 and H2S) sources. 相似文献
76.
Yuchun WANG Jun ZHU Congqiang LIU 《中国地球化学学报》2006,25(B08):161-162
Damming is a common anthropogenic intervention along the course of rivers, which is defined as "artificial-lake effect", both in China and across the world. Today as many as 48000 dams and/or reservoirs are in operation in the Changjiang River (Yangtze River) drainage area, and more are being constructed. While damming is well known to affect riverbome nutrient loads, and thus the riverine ecosystems owing to removal of carbon fixation, and removal of particles in reservoir sediments, there is limited information on the detailed early diagenesis of sediments in reservoirs including the regeneration processes of nutrients deposited in sediments and exchange flux across the sediment-water interface, which is important for mass balance of riverbome nutrients. In the present study, two large-size reservoirs, Wujiangdu Reservoir (WJDR) and Dongfeng Reservoir (DFR), located on the main steam of the Wujiang River and with uniformity hydrography and discrepancy biogeochemical activity (e. g. primary production), were selected for a comparative study on the detailed processes of nutrient regeneration. Water, pore water and sediment were sampled from these two reservoirs and dissolved organic carbon (DOC), NH4^+, NO3^-, PO4^3-, dissolved silica (DSi) in the overlying water and pore water, and total organic matter in sediments were determined. The results of correlation analysis suggested that in these two reservoirs, processes of nutrient regeneration near the sediment-water interface were significantly different. As a result of rapid decomposition of algae-derived "labile" organic matter in upper sediments, nutrient regeneration processes and upward fluxes in WJDR are dramatically stronger than those of DFR. NH4^+ upward flux from sediment in WJDR was about 17 times higher than that in DFR. PO4^3- flux in WJDR is about 13 times above that in DFR. DOC flux in WJDR is larger that in DFR by 5 times, and DSi by 1 time. 相似文献
77.
Habib Ben Hassine 《Comptes Rendus Geoscience》2006,338(5):329-340
The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca++, Mg++ and K+ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006). 相似文献
78.
Xinbin FENG Shaofeng WANG Guangle QIU Yamin HOU Shunlin TANG 《中国地球化学学报》2006,25(B08):243-244
Guizhou is located in the Circum-Pacific Global Mercuriferous Belt, and mercury concentrations in soil in this area are enriched. In-situ total gaseous mercury (TGM) exchange fluxes between air and soil surface were intensively measured at four sampling sites in Guiyang from 21 May to 16 June, 2003, and five sites in the Lanmuchang mercury mining area in December 2002 and May 2003, respectively. The in-situ Hg flux measurement was conducted with a dynamic flux chamber (DFC) of quartz. Overall, net emissions were obtained from all sampling sites. Soil mercury concentration and solar radiation have been proved to be the two most important parameters to control mercury emissions from soil. Meanwhile, rain events can enhance mercury emission rate significantly. 相似文献
79.
Georg Schettler Jens Mingram Jörg F. W. Negendank Liu Jiaqi 《Journal of Paleolimnology》2006,35(2):271-288
Palaeovariations of the atmospheric 210Pb flux in Northeast China (Long Gang area, Jilin province), quantified by high resolution 210Pb measurements on seasonally laminated sediments of Lake Sihailongwan are presented on decadal scale. The mean flux of unsupported
210Pb between 1790 and 1970 for the centre of the lake basin is 517 Bq m−2 yr−1 with maximum deviations between −23% and +27% of this value. Flux rates above this average were found between 1783 and 1813,
around 1836, and between 1860 and 1901. The mean 210Pbexc flux rates derived were clearly lower around 1821, 1908, 1930, and 1953. The 210Pbexc flux reached its minimum of 344 Bq m−2 yr−1 during the period 1977–1982. The atmospheric flux of unsupported 210Pb is correlated with the precipitation frequency during the summer monsoon and shows coinciding variability with geochemical
proxies that document the groundwater inflow into the lake. Al2O3-rich dust of remote provenance scavenged by wet-deposition in the rainy season is the major carrier of the atmospheric 210Pbexc flux. 相似文献
80.
Georg Schettler Qiang Liu Jens Mingram Jörg F. W. Negendank 《Journal of Paleolimnology》2006,35(2):239-270
The varved sediments of the dimictic Lake Sihailongwan (Long Gang mountain area, Jilin Province, Northeast China) represent
a palaeoclimatic archive which documents the local precipitation frequency during the summer monsoon, and variations in the
aeolian flux of dust with their remote sources in the arid and semi-arid regions of inner Asia. Based on a detailed discussion
of sediment genesis in Lake SHL, dust flux rates and palaeohydrological conditions were reconstructed on a decadal scale over
the past 220 years. The aeolian influx by dry and wet deposition was quantified and characterised in its chemical composition.
Photosynthetic production in the lake is positively correlated with the inflow of nutrient-rich groundwater. The groundwater
discharge largely reflects the strength of the summer monsoon. Net accumulation rates for biogenic silica were determined
for annually laminated sediments from the centre of the U-shaped lake basin based on sediment data. In a Si-balance model
of the modern lake, the depositional flux of biogenic silica could be independently quantified on the base of hydrochemical
monitoring data. Comparison of the both estimates allowed to asses the focussing of the particle flux in the lake. Though
water retention in Lake SHL is rather high (ca. 30 years), changes in the hydrological conditions are sensitively recorded
in the sediments because (i) nutrient-rich groundwater discharges into the productive zone of the lake, (ii) a substantial
proportion of the total dissolved Si-inventory of the mixed lake (ca. 30%) is annually consumed by diatom growth, and (3)
sediment accumulation is substantially focussed towards the flat bottom of the lake basin. The bulk siliciclastic sediment
fraction (ca. 75 wt.%) largely originates from influx of dust of remote provenance. In sediment thin-sections, the dry-deposited
dust fraction is microscopically identifiable as seasonal silt layer. Aeolian input by wet-deposition shows a distinctly higher
variability than the influx of dust by dry-deposition. As diatom production, wet-deposition of dust is positively correlated
with the rainfall during the summer monsoon. The inferred positive correlation between rainfall and dust flux during the summer
monsoon implies that dust deposition is determined by the out-wash efficiency of mineral particles for a permanent high atmospheric
dust concentration over Northeast China in the last 220 years. 相似文献