Geochemical constraints on the modes of carbonate precipitation in peridotites from the Logatchev Hydrothermal Vent Field and Gakkel Ridge     

Benjamin Eickmann  Wolfgang Bach  Martin Rosner  Jrn Peckmann 《Chemical Geology》2009,268(1-2):97-106

The ultramafic-hosted Logatchev Hydrothermal Field (LHF) at 15°N on the Mid-Atlantic Ridge and the Arctic Gakkel Ridge (GR) feature carbonate precipitates (aragonite, calcite, and dolomite) in voids and fractures within different types of host rocks. We present chemical and Sr isotopic compositions of these different carbonates to examine the conditions that led to their formation. Our data reveal that different processes have led to the precipitation of carbonates in the various settings. Seawater-like ⁸⁷Sr/⁸⁶Sr ratios for aragonite in serpentinites (0.70909 to 0.70917) from the LHF are similar to those of aragonite from the GR (0.70912 to 0.70917) and indicate aragonite precipitation from seawater at ambient conditions at both sites. Aragonite veins in sulfide breccias from LHF also have seawater-like Sr isotope compositions (0.70909 to 0.70915), however, their rare earth element (REE) patterns show a clear positive europium (Eu) anomaly indicative of a small (< 1%) hydrothermal contribution. In contrast to aragonite, dolomite from the LHF has precipitated at much higher temperatures (~ 100 °C), and yet its ⁸⁷Sr/⁸⁶Sr ratios (0.70896 to 0.70907) are only slightly lower than those of aragonite. Even higher temperatures are calculated for the precipitation of deformed calcite veins in serpentine–talc fault schists form north of the LHF. These calcites show unradiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.70460 to 0.70499) indicative of precipitation from evolved hydrothermal fluids. A simple mixing model based on Sr mass balance and enthalpy conservation indicates strongly variable conditions of fluid mixing and heat transfers involved in carbonate formation. Dolomite precipitated from a mixture of 97% seawater and 3% hydrothermal fluid that should have had a temperature of approximately 14 °C assuming that no heat was transferred. The much higher apparent precipitation temperatures based on oxygen isotopes (~ 100 °C) may be indicative of conductive heating, probably of seawater prior to mixing. The hydrothermal calcite in the fault schist has precipitated from a mixture of 67% hydrothermal fluid and 33% seawater, which should have had an isenthalpic mixing temperature of ~ 250 °C. The significantly lower temperatures calculated from oxygen isotopes are likely due to conductive cooling of hydrothermal fluid discharging along faults. Rare earth element patterns corroborate the results of the mixing model, since the hydrothermal calcite, which formed from waters with the greatest hydrothermal contribution, has REE patterns that closely resemble those of vent fluids from the LHF. Our results demonstrate, for the first time, that (1) precipitation from pure seawater, (2) conductive heating of seawater, and (3) conductive cooling of hydrothermal fluids in the sub-seafloor all can lead to carbonate precipitation within a single ultramafic-hosted hydrothermal system.  相似文献   

Influence of dissolution on the mechanical behaviour of saturated deep argillaceous rocks     

Adrien Haxaire  Irini Djeran-Maigre 《Engineering Geology》2009,109(3-4):255-261

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酸不溶物对碳酸盐岩风化壳发育程度的影响   总被引：3，自引：0，他引：3  

冯志刚  王世杰  刘秀明  罗维均 《地质学报》2009,83(6):885-893

通过对贵州岩溶区（包括湘西）不同地层系统碳酸盐岩发育的红色风化壳、以及结合本区和处于同一气候带的邻区不同岩类红色风化壳的对比研究,结果表明：（1）碳酸盐岩红色风化壳的发育程度明显受基岩酸不溶物成分的控制,酸不溶物的风化成熟度越高,红色风化壳的发育程度一般也越强。由于不同地层系统碳酸盐岩的酸不溶物组成不同,在此基础上发育的红色风化壳的风化强度自然存在着差异;（2）风化壳相对于母岩的进一步风化潜力或空间,随着基岩酸不溶物风化成熟度的增大而降低,从而更容易达到风化平衡;（3）在碳酸盐岩风化壳突变的岩-土界面,伴随碳酸盐的充分淋失、酸不溶物的地球化学指标发生了突变。因此,碳酸盐的溶解不但未阻滞和延缓了硅酸盐组分的分解,而且促进其快速风化。（4）在达到高岭石化甚至弱红土化阶段的酸不溶物基础上,发育的风化壳比结晶岩类风化壳具有更高的风化起点,也就表现出更高的风化强度。因此,笼统地把碳酸盐岩风化壳看作是弱于玄武岩及花岗岩等结晶岩类风化壳发育程度的弱风化类型是不妥的。  相似文献   

Early Mesozoic unroofing pattern of the Dabie Mountains (China): Constraints from the U-Pb detrital zircon geochronology and Si-in-white mica analysis of synorogenic sediments in the Jianghan Basin   总被引：1，自引：0，他引：1  

Yuejun Wang  Guochun Zhao  Xiaoping Xia  Yanhua Zhang  Weiming Fan  Chao Li  Xianwu Bi  Sanzhong Li 《Chemical Geology》2009,266(3-4):240-250

This paper presents the results of an integrated U-Pb detrital zircon geochronology and Si-in-white mica analysis for synorogenic sediments in the Jianghan Basin to the south of the Dabie Orogen. The results provide an improved understanding of the provenance of these sediments and the unroofing pattern of the early Mesozoic Dabie Mountain. Si contents of detrital white micas range from 3.09 to 3.34 atoms pfu for the upper Triassic sandstones whereas 3.06 to 3.59 atoms pfu for the lower and middle Jurassic sandstones. The majority of detrital white micas in the lower Jurassic sandstones is phengitic and originated exclusively from the Dabie high- to ultrahigh- pressure rocks. The U-Pb dating results of the detrital zircons for seven samples suggest that these synorogenic sediments have a significant change of provenance from late Triassic to early and middle Jurassic. For the upper Triassic sandstone, the U-Pb age clusters of these zircons are characterized by ~ 420-450 Ma, ~ 750-820 Ma, ~ 1050-1200 Ma and ~ 2500 Ma with minor Luliangian (~ 1700–2000 Ma) components. In contrast, the zircon ages of the Jurassic sandstones are dominated by the Luliangian (~ 1700–2000 Ma) ages with only minor Caledonian (~ 420-450 Ma) and Greenville (~ 1050-1200 Ma) ages. In combination with other available geological data, it can be concluded that the Dabie HP-UHP rocks might initially be exposed to the surface at the beginning of early Jurassic (~ 190 Ma). The Jiangnan terrain (also named “Jiangnan old continental in Chinese) to the south of the Jianghan basin provided the predominant supply of upper Triassic sediments, whereas the Paleoproterozoic Yangtze crustal materials (overlying the present Dabie Complex at the time) were the important provenance of the Jurassic sediments in the Jianghan basin.  相似文献   

New data of typomorphic features of diamonds from placers in North Timan     

G. K. Khachatryan  M. B. Kopchikov  V. K. Garanin  M. V. Chukichev  N. N. Golovin 《Moscow University Geology Bulletin》2009,64(2):102-110

The morphological and spectral-optical properties of diamond crystals from placers in North Timan rivers have been studied with IR-spectroscopy and cathode luminescence methods. As a result, correlation between external characteristics of diamonds (size and degree of mechanical damage) and number of optically active centers has been revealed. The habit and the type of distribution of structural defects in diamond crystals studied are comparable with those in diamonds from the Archangelsk Region and North Timan’s placers. Based on the obtained data, origin issues and possible primary sources of diamonds from North Timan’s placers are discussed.  相似文献   

西藏班公湖岛弧带含硫化镍超基性岩的源区性质与基底背景   总被引：5，自引：1，他引：4  

江军华  王瑞江  曲晓明  辛洪波 《矿床地质》2009,28(6):793-802

青藏高原班公湖一怒江成矿带上的超基性岩型硫化镍矿化是近年来在西藏地区发现的矿化新类型.文章根据成矿带西段班公湖地区含镍超基性岩体的岩石地球化学和Sr、Pb同位素分析结果,论述了含镍超基性岩浆的源区性质及生成条件,并根据锆石U-Pb LA-ICP-MS年龄测定结果,探讨了藏西北地区的基底背景.研究发现,班公湖地区的含镍超基性岩体以富集大离子不相容元素Rb、Th、U、Sr、Pb,亏损Ba、K为特点,高场强元素亏损Nb、Ti,富集Ta;稀士元素相对球粒陨石亏损强烈,但轻稀土元素相对富集.这些特点一致反映出含矿岩浆产生于受俯冲沉积物熔体交代的富集型岩石圈地幔源区.岩浆的生成深度较浅,为尖晶石二辉橄榄岩相,源区部分熔融程度较低,大体在10%左右.岩石中集中出现一批24.79亿年的残留锆石年龄,标志着当时班公湖中特斯洋盆沉积物的物源区较为单一,主要来自太古代末-元古代初的古老基底,并且推测太古代与元古代之交(25亿年)有可能是藏西北的一个古陆壳快速生长期.  相似文献   

鄂尔多斯盆地侏罗纪西界分析   总被引：6，自引：1，他引：5  

张珂  邹和平  刘忠厚  马占武 《地质论评》2009,55(1):761-774

鄂尔多斯盆地西界,特别是其早—中侏罗世盆地西界,由于不同期次、不同性质的构造相互叠加而模糊不清,究竟是在贺兰山以西还是现在银川盆地以东的问题,至今尚无共识,极大地影响着矿产资源的评价和找矿战略的部署。本文在前人工作的基础上,通过针对性的野外工作,分析和筛分了不同时期的古构造,探讨了晚侏罗世和早—中侏罗世盆地的西界。文章认为,鄂尔多斯盆地西部巨大的近南北向挤压构造形成于晚侏罗世,而东西向的挤压构造则出现于晚三叠世。两期方向截然不同的挤压构造相互叠加,构成了鄂尔多斯盆地西部复杂的叠加构造和不规则的盆地西界。晚期挤压构造较为清晰,表现为近南北向的逆冲推覆构造带和纵贯盆地南北的“古脊梁”,使盆地西界退缩到桌子山东麓断裂、横山堡—磁窑堡断褶带以及马儿庄冲断裂和崆峒山断裂以东。早期挤压构造受后期构造的叠加改造,断断续续,时隐时现。近东西向挤压构造受古亚洲域的影响,是印支运动的产物,近南北向挤压构造转受滨太平洋域的作用,是燕山运动的表现。在古亚洲域向太平洋域转换过程中的早—中侏罗世,鄂尔多斯盆地西部出现了近东西向的拉张伸展,在盆地内部表现为近东西向隆起凹陷的古地形,使盆地西缘波状弯曲,而非平直,“银川古隆起”和“汝箕沟—鄂尔多斯盆地”两者并存,并不矛盾。早—中侏罗世盆地西界可能远至阿拉善地块。上述中生代构造又经新生代构造改造,变得更加复杂多样,甚至面目全非。如不注意构造筛分,中生代构造乃至盆地边界的研究就会被误导,从而得出错误结论。  相似文献   

塔里木盆地塔中低凸起古构造演化与变形特征   总被引：14，自引：0，他引：14  

李本亮  管树巍  李传新  邬光辉  杨海军  韩剑发  罗春树  苗继军 《地质论评》2009,55(4):521-530

通过区域地质和构造地震精细研究,提出了塔里木南缘早古生代板块构造控制塔南—塔中从伸展到挤压盆地演化：寒武纪—早奥陶世板缘拉张控制了塔中北斜坡断陷构造;中奥陶世北昆仑洋盆关闭后塔中前缘隆起;晚奥陶世—晚泥盆世塔中前陆冲断与走滑构造变形。晚奥陶世塔南前陆冲断构造由东南向西北方向传播,形成塘北—塔中南—塔中5号断裂带等弧形断裂体系和塔中低凸起中西段与Ⅰ号断裂带小角度斜交的走滑断裂体系。冲断构造位移的传播受控于两个滑脱层：其一是沿寒武系内部膏盐岩的滑脱,形成弧形冲断构造,终止于塔中南缘断裂带;另一个是沿中地壳韧性变形带的滑脱,形成塔中1号断裂带东端的弧形构造带。塔中1号断裂带东段的构造变形方式主要为向北传播水平位移的断层传播褶皱和向南反向冲断的楔形构造。塔中低凸起的中西段右行走滑构造导致了向东收敛的扫帚状走滑断裂体系的形成,剖面发育花状构造。塔中低凸起的古构造演化与变形特征、构造变形样式、构造变形成因和断裂体系,是克拉通盆地内部叠合盆地深层的主要构造地质特征。  相似文献   

The Miduk porphyry Cu deposit,Kerman, Iran: A geochemical analysis of the potassic zone including halogen element systematics related to Cu mineralization processes   总被引：1，自引：0，他引：1  

Mohammad Boomeri  Kazuo Nakashima  David Richard Lentz 《Journal of Geochemical Exploration》2009

Miduk hypogene and supergene porphyry Cu–Mo mineralization occurs within the Miocene porphyritic quartz–diorite and host Eocene plagioclase–hornblende phyric andesitic pyroclastic and flow sequence. Both the host rocks were extensively altered by hydrothermal fluids to dominantly potassic, phyllic, and argillic with interstitial to distal propylitic types.  相似文献   

西藏西部与班公湖特提斯洋盆俯冲相关的火成岩年代学和地球化学   总被引：32，自引：1，他引：31  

曲晓明  王瑞江  辛洪波  赵元艺  樊兴涛 《地球化学》2009,38(6):523-535

对青藏高原西北部班公湖缝合带开展了野外地质调查,初步查明区内缝合带至少包含日土和狮泉河-改则两条蛇绿岩带。在两条蛇绿岩带北侧发现各有两期岛弧型岩浆岩发育,且形成时间严格对应。岩石地球化学分析表明,班公湖缝合带岛弧型岩浆岩的共同特征是富集大离子不相容元素Rb、Th、K和Pb;强烈亏损高场强元素Nb、Ta和Ti;Ba在微量元素蛛网图中总是相对亏损,这些特征说明班公湖地区存在两条俯冲带。从演化序列看,俯冲初期岩石属中钾钙碱性系列,之后岛弧岩浆作用向高钾钙碱性系列演变。锆石U—PbLA—ICPMS定年结果表明,北面的日土俯冲带洋壳俯冲从辉长岩墙开始,时代为（165．5±1．9）Ma（MSWD=1．16）,在159Ma时岛弧岩浆作用规模增大,形成小型的花岗岩基;南面的狮泉河-改则俯冲带一开始俯冲（（166．4±2．0）Ma,MSWD=3．0）就有较大规模的石英闪长岩体侵入,之后岩浆作用减弱,到159．4Ma时只有一些小体积的花岗斑岩和闪长玢岩侵入。根据岛弧岩浆作用规模,认为班公湖中特提斯洋盆的俯冲一开始是以狮泉河俯冲带为主,之后狮泉河俯冲带的俯冲作用逐渐减弱。到晚侏罗世初（159Ma）北面的日土俯冲带成为洋壳俯冲的主体。鉴于两条岛弧火成岩带在空间配置上都位于由基性-超基性岩构成的蛇绿岩带北侧,地球化学上显示陆缘弧特征,因此,认为班公湖中特提斯洋盆应该是在中侏罗世晚期（约166Ma）沿日土和狮泉河两条俯冲带同时向北俯冲,构造属性上可能不是一个统一的大洋,而是包含了多个局限性洋盆。  相似文献