西藏喜马拉雅带稀有金属矿勘查与研究进展          下载免费PDF全文

张志  李光明  张林奎 《沉积与特提斯地质》2022,42(2):176-188

长期以来,西藏喜马拉雅带以发育较多金、金锑及铅锌多金属矿为显著特色,而稀有金属矿未曾列入主流找矿方向。近年来,该带由于铍、锂等稀有金属矿的重要找矿新发现而备受广大学者关注,其相应的成矿作用研究亦有较大进展。本文在喜马拉雅带已有地质找矿成果及科学研究资料的基础上,对该带新发现的稀有金属矿勘查与研究进展进行了总结。本文提出：喜马拉雅带主要发育有伟晶岩型锂-铍矿、锡石-硫化物型锡-铍矿、矽卡岩型铍-锡-钨矿、矽卡岩型铍-铌-钽矿、钠长石花岗岩型铍-铌-钽矿、热液脉型萤石-铍矿6种稀有金属矿化类型,其中伟晶岩型锂-铍矿及锡石-硫化物型锡-铍矿最具经济意义上的找矿价值。这些稀有金属成矿作用均与中新世淡色花岗岩浆活动密切相关,属于岩浆高度结晶分异的产物,是印度-亚洲大陆碰撞造山成矿作用中的新成员,并构成了喜马拉雅带与淡色花岗岩相关的稀有金属矿成矿系列。为指导找矿勘查,今后喜马拉雅稀有金属成矿作用研究应加强如下几方面：(1)高分异淡色花岗岩-伟晶岩岩相分带与相应的稀有金属分带;(2)锂-铍-铌-钽-钨-锡共生分离机制;(3)喜马拉雅式稀有金属矿成矿模式与勘查模型;(4)稀有金属与铅锌-金锑成矿作用的关系。喜马拉雅带新发现的稀有金属成矿作用大部分靠近我国边境地区,通过进一步的勘查评价工作有望形成西藏地区具有战略意义的稀有金属成矿带。  相似文献   

吉林延边小西南岔铜（金）矿床早白垩世中—酸性岩浆岩年代学、地球化学及其成因探讨     

王琳琳  霍亮  王莹 《吉林大学学报(地球科学版)》2022,52(5):1658-1674

小西南岔铜（金）矿床位于吉林省延边地区东部,通过对小西南岔铜（金）矿床早白垩世中—酸性岩浆岩进行野外地质、岩相学、年代学和地球化学等方面的研究,进一步探讨延边乃至东北地区中生代大地构造演化。年代学研究结果表明：其同位素年龄分别为(101.69±0.61) Ma（石英闪长岩）、(101.14±0.58) Ma（英云闪长岩）、(100.82±0.62) Ma（花岗闪长岩）和(100.20±1.10) Ma（闪长玢岩）,岩浆作用发生在早白垩世末期（102~100 Ma）,是同一构造演化过程的产物。岩石地球化学研究表明,闪长玢岩具有典型埃达克质岩石的地球化学特征,其w(SiO₂)=61.419%~62.153%,w(Al₂O₃)=16.872%~17.329%,w(MgO)=2.339%~2.643%,w(Na₂O)=5.749%~6.623%,w(K₂O)=1.483%~1.786%,w(Sr)=(691~888)×10^-6,w(Yb)=(0.71~0.83)×10^-6,Sr/Y值为87.4~120.0,LREE富集,说明闪长玢岩是由俯冲的大洋板片部分熔融产生的埃达克质岩浆上侵就位形成。埃达克质岩浆上侵过程中与下地壳重熔产生的酸性岩浆混合,形成的富集地幔源岩浆上侵就位形成石英闪长岩、英云闪长岩和花岗闪长岩等钙碱性花岗质杂岩;岩浆热液沿区域断裂上升过程中与大气降水混合,萃取围岩中的成矿物质,形成富铜（金）组分的成矿热液,在合适的部位卸载沉淀形成脉状铜（金）矿化。晚中生代延边地区位于古太平洋板块向欧亚大陆板块俯冲的大陆边缘环境,古太平洋板块的俯冲是形成早白垩世石英闪长岩、英云闪长岩、花岗闪长岩和闪长玢岩（脉）以及小西南岔矿床热液脉型铜（金）矿化的直接动力来源。  相似文献   

青海东昆仑洪水河铁矿床新元古代含铁建造铁同位素特征及其成因意义     

丁清峰  吴睿哲  张强  周轩 《吉林大学学报(地球科学版)》2022,52(5):1497-1511

青海省东昆仑造山带洪水河铁矿床为一中型铁矿床,其含铁建造产于狼牙山组千枚岩中,矿石类型主要为块状磁铁石英岩型,少量为条带状磁铁石英岩型,前人一般认为其属于沉积变质型铁矿床。本文在前人研究基础上,对洪水河铁矿区含铁建造中块状铁矿石进行了铁同位素、主量元素、稀土元素和微量元素分析。结果显示：除1件样品外,其余含铁建造样品的铁同位素δ56FeIRMM014均介于0.97‰~1.97‰之间,和全球典型新元古代含铁建造的Fe同位素特征基本一致;铁矿石的SiO₂+Fe₂O₃质量分数高达78.56%~98.06%,具有极低的Al/(Al+Fe+Mn)值（0.00~0.06）,为典型的化学沉积岩;总稀土元素（w (∑REE)）变化范围为(16.49~80.89)×10^-6,没有明显的Ce异常(Ce/Ce*为0.93~1.05),轻稀土元素轻微亏损,显示出类似新元古代含铁建造型的特点。综合对比洪水河铁矿区含铁建造的Fe同位素组成、沉积时代和地球化学特征,推断洪水河铁矿区含铁建造的沉积环境为新元古代柴达木—东昆北陆块的被动大陆边缘构造环境,铁等成矿物质主要来源于海相热液流体;富含Fe²+的海相热液流体上涌并逐渐演变为低温热液后在亚氧化水体环境中与含氧海水混合,最后导致Fe²+被部分氧化并形成氢氧化铁,氢氧化铁逐渐沉积在大陆斜坡上最终形成含铁建造。洪水河铁矿的成因类型可划归为拉皮坦型新元古代含铁建造。  相似文献   

Lu–Hf constraints on pre-, syn,and post-collision associations of the Gurupi Belt,Brazil: Insights on the Rhyacian crustal evolution     

《地学前缘(英文版)》2022,13(5):101199

The Gurupi Belt (together with the São Luís cratonic fragment), in north-northeastern Brazil, has been described in previous studies that used extensive field geology, structural analysis, airborne geophysics, zircon U–Pb dating, and whole-rock Sm–Nd isotope and geochemical data as a polyphase orogenic belt, with the Rhyacian being the main period of crust formation. This was related to a 2240 Ma to 2140 Ma accretionary processes that produced juvenile crust, which has subsequently been reworked during a collisional event at 2100 ± 20 Ma, with little evidence of Archean crust. In this study, we use Lu–Hf isotopic data in zircon from granitoids (including gneiss) of variable magmatic series, and amphibolite to improve the knowledge of this scenario, and investigate additional evidence of recycling of Archean basement. Pre-collisional high Ba-Sr and ferroan granitoids and amphibolite formed in island arc (2180–2145 Ma), show only zircons with suprachondritic εHf values (ca. +1 to +8) indicating the large predominance of juvenile magmas. Only 10% of the data show slightly negative εHf values (0 to ?4), which have been observed in granodiorite-gneiss formed in continental arc (2170–2140 Ma), and in strongly peraluminous collisional granites (2125–2070 Ma), indicating the rework of older Paleoproterozoic to Archean components (Hf_TDM = 2.11–3.69 Ga). A two-component mixing model using both Hf and published Nd isotope data are in line with this interpretation and indicate more than 90% of juvenile material, and less influence of Archean materials. Comparing with other Rhyacian terranes that are interpreted to have been close to Gurupi in a pre-Columbia configuration (ca. 2.0 Ga), our results differ from those of SE-Guiana Shield, which show strong influence of Archean protoliths, and are very similar to those of the central-eastern portion of the Baoulé-Mossi Domain of the West African Craton, which has also been formed largely by juvenile magmas in an accretionary-collisional orogen.  相似文献   

Temporal variations of reference evapotranspiration and controlling factors: Implications for climatic drought in karst areas          下载免费PDF全文

Guo Xiao-jiao  Wang Wen-zhong  Li Cheng-xi  Wang Wei  Shi Jian-sheng  Miao Ying  Hao Xing-bo  Yuan Dao-xian 《地下水科学与工程》2022,10(3):267-284

Variations in reference evapotranspiration (ET₀) and drought characteristics play a key role in the effect of climate change on water cycle and associated ecohydrological patterns. The accurate estimation of ET₀ is still a challenge due to the lack of meteorological data and the heterogeneity of hydrological system. Although there is an increasing trend in extreme drought events with global climate change, the relationship between ET₀ and aridity index in karst areas has been poorly studied. In this study, we used the Penman–Monteith method based on a long time series of meteorological data from 1951 to 2015 to calculate ET₀ in a typical karst area, Guilin, Southwest China. The temporal variations in climate variables, ET₀ and aridity index (AI) were analyzed with the Mann–Kendall trend test and linear regression to determine the climatic characteristics, associated controlling factors of ET₀ variations, and further to estimate the relationship between ET₀ and AI. We found that the mean, maximum and minimum temperatures had increased significantly during the 65-year study period, while sunshine duration, wind speed and relative humidity exhibited significant decreasing trends. The annual ET₀ showed a significant decreasing trend at the rate of ?8.02 mm/10a. However, significant increase in air temperature should have contributed to the enhancement of ET₀, indicating an “evaporation paradox”. In comparison, AI showed a slightly declining trend of ?0.0005/a during 1951–2015. The change in sunshine duration was the major factor causing the decrease in ET₀, followed by wind speed. AI had a higher correlation with precipitation amount, indicating that the variations of AI was more dependent on precipitation, but not substantially dependent on the ET₀. Although AI was not directly related to ET₀, ET₀ had a major contribution to seasonal AI changes. The seasonal variations of ET₀ played a critical role in dryness/wetness changes to regulate water and energy supply, which can lead to seasonal droughts or water shortages in karst areas. Overall, these findings provide an important reference for the management of agricultural production and water resources, and have an important implication for drought in karst regions of China.  相似文献   

Geology and mineralization of the supergiant Shimensi granitic-type W-Cu-Mo deposit (1.168 Mt) in northern Jiangxi,South China: A Review     

《China Geology》2022,5(3):510-527

The Shimensi deposit is a recently discovered W-Cu-Mo polymetallic deposit located in the Jiangnan porphyry-skarn W belt in South China. The deposit has a resource of 0.74×10⁶ t of WO₃ accompanied by 0.4×10⁶ t Cu and 28000 t Mo and other useful components like Ga, making it one of the largest W deposits in the world. This paper is aimed to reveal the ore-controlling mechanisms of the Shimensi deposit, involving the role of the ore-related granites, the tectonic background for its formation, and the metallogenesis model. The systematic geological survey suggests multi-types of alteration are developed in the deposit, mainly including greisenization, potassic-alteration, sericitization, chloritization, and silicification. Drilling engineering data and mining works indicate that the Shimensi deposit consists of two main orebodies of I and II. Therein, the W resource has reached a supergiant scale, and the accompanied Cu, Mo, Au, Bi, Ga, and some other useful components are also of economic significance. The main ore-minerals consist of scheelite, wolframite and chalcopyrite. Disseminated mineralization is the dominant type of the W-Cu-Mo polymetallic orebodies, and mainly distributes in the inner and external contact zone that between the Neoproterozoic biotite granodiorite and the Yanshanian granites. The main orebody occurs at the external contact zone, and the pegmatoid crust near the inner contact zone is an important prospecting marker of the W mineralization. Of them, the disseminated W ores within the wall rock of the Neoproterozoic biotite granodiorite is a new mineralization type identified in this paper. Combining previous geochronological and isotopic data, we propose that the mineralization of the Shimensi deposit is closely related to the intruding of the Yanshanian porphyritic biotite granite and granite porphyry. Geochemical data suggest that the biotite granodiorite is rich in Ca and had provided a large amount of Ca for the precipitation of scheelite in this area. Thus, it is a favorable wall rock type for W mineralization. The Shimensi deposit belongs to granitic-type W polymetallic deposit related to post-magmatic hydrothermal, and the ore-forming fluid was initially derived from the Yanshanian magmas.©2022 China Geology Editorial Office.  相似文献   

Inverse modeling of lichen growth curves and implications for lichenometric dating     

《Quaternary Geochronology》2022

Lichenometric dating represents a quick and affordable surface exposure dating method that has been widely used to provide a minimum age constraint on tectonic and geomorphic landscape changes as well as buildings and anthropogenic landscape changes in various settings during the late Holocene. Despite its widespread usage, this method has several limitations. Major problems relate to the sampling of lichen population on any given rock surface and the modeling of growth curves. In order to overcome these issues, it has been suggested to subdivide the rock surface into some areas and measure the largest lichen thallus on each one. However, how to express the data in terms of a probability distribution function and link it to an age of last exposure of the rock surface are still a matter of debate. Here, we propose a novel approach to the modeling of lichen growth curves by treating lichen growth as a continuous-time Markov process with a time-varying rate and additive Brownian noise. Given the growth rates, the probability distribution of the lichen population at any time can then be obtained by solving the Fokker–Planck equation. This method is illustrated using a dataset from the Huashan area of eastern China, which consists of measurements of the largest thalli on 12 rock surfaces of known age. We first build up the probability distribution of the lichen population for each rock surface based on extreme value theory and then use these to optimize the growth curve by minimizing the Jensen–Shannon divergence. A new method is also proposed to use the growth curve to map a sample of size data from an undated rock surface to the calendar age domain so as to yield a fully probabilistic estimate of the exposure age of the undated rock surface rather than a point estimate.  相似文献   

Testing a new combined (U,Th)–He and U/Th dating approach on Plio-Pleistocene calcite speleothems     

《Quaternary Geochronology》2022

The geochronology of cave deposits in the Cradle of Humankind UNESCO World Heritage Site in South Africa provides a timeframe essential for the interpretation of its fossils. The uranium-lead (U–Pb) and uranium-thorium disequilibrium (U/Th) dating of speleothems, mostly flowstones that underlie and blanket the fossil-bearing sediments, have been effective in this sense, but U–Pb is limited by the requirement of ∼1 ppm U concentrations and low common Pb contents, and U/Th has a c. 500 ka limit of applicability. Here we report age results for calcite-aragonite speleothems obtained using a new combined uranium-thorium-helium ((U,Th)–He) and U/Th dating routine. We reproduced within analytical uncertainty, the published U–Pb or U/Th ages for (a) flowstone in three drill core samples in the range 2000–3000 ka, (b) a flowstone hand sample taken at surface with an age of 1800 ka, and (c) five underground flowstone samples in the range 100–800 ka. Calcite retentivity for He under cave conditions is thus demonstrated. In the few cases where helium loss was observed in speleothems, only some of the subsamples were affected, and to varying degrees, suggesting loss by lattice damage not related to diagenetic processes, rather than volume diffusion. In the 100 to 800 ka range, the combined U/Th disequilibrium and (U,Th)–He method also yielded reliable values for initial (²³⁰Th/²³⁸U) and (²³⁴U/²³⁸U) activity ratios. Importantly, most subsamples had high initial (²³⁰Th/²³⁸U) values, ranging from 1.0 to 19.7, although having low Th/U ratios. This is probably due to incorporation of Fe–Mn oxides-hydroxides dust, on which ²³⁰Th was previously adsorbed. Such samples are mostly not dateable by U/Th without the additional input from the He analysis. If not detected and corrected for, such high initial (²³⁰Th/²³⁸U) values can lead to inaccurate U/Th and U–Pb ages. Our study shows that the incorporation of He analysis in U/Th dating has broad potential application, with four methods for calculating the ages, in carbonates from different environments where U-Pb or U/Th dating would not work.  相似文献   

Holocene volcanic activity in Anjouan Island (Comoros archipelago) revealed by new Cassignol-Gillot groundmass K–Ar and 14C ages     

《Quaternary Geochronology》2022

The Comoros archipelago has attracted renewed attention since 2018 due to the submarine volcano growing east of the island of Mayotte and the associated ongoing seismic crisis. However, the origin of Comorian magmatism remains controversial, as it is either interpreted as related to a hotspot trail, to a fracture zone, or to a plate boundary. Lying in the central part of the archipelago, Anjouan is a key island to better understand the relationship between volcanism and geodynamics. Together with a careful selection of published whole-rock K–Ar ages, our new set of 13 groundmass K–Ar ages on lava flows and one radiocarbon age on a charcoal from a strombolian deposit, allow us to reassess the volcano-tectonic evolution of Anjouan Island. New groundmass K–Ar ages lie within the last 1 Ma, i.e. from 899 ± 14 to 11 ± 1 ka. They suggest that most of the subaerial volcanism in Anjouan is much younger than previously inferred, and occurred as pulses at 900–750 ka, perhaps 530 ka, 230–290 ka, and since 60 ka, with erosional periods in between. Among our new data, one ¹⁴C age of 7513–7089 yrs calBCE (9.3 ± 0.2 ka) and five K–Ar ages younger than 60 ka show that recent volcanism occurred in Anjouan. Moreover, the concentration of eruptive vents along a N150° alignment, parallel to the maximum horizontal stress, suggests a strong link between regional tectonics and volcanism. Considering the presence of active volcanoes on both the western and eastern extremities of the Comoros archipelago, our discovery of Holocene activity on Anjouan provides strong arguments against a chronological progression of volcanism along the archipelago, and therefore contradicts the hotspot hypothesis for the origin of volcanism.Finally, this study provides a robust geochronological timeframe of the different volcanic stages of Anjouan. It demonstrates that Anjouan is an active island and suggests that volcanism and tectonics can both resume at any time.  相似文献   

内蒙古科右中旗两类基性岩的年代学、地球化学及其构造意义          下载免费PDF全文

金松  李英杰  钱程  张杨  孟都  杨海波  王博  伍光锋 《地球科学》2022,47(1):342-356

兴蒙造山带东段晚古生代构造演化存在争议,基性岩浆作用是构造演化过程中的良好地质记录. 对贺根山缝合带东段内蒙古科右中旗构造混杂岩带内的杜尔基基性岩和甲哈达基性岩进行了系统的地质特征、岩相学、年代学和地球化学研究. 杜尔基基性岩岩性为枕状玄武岩和辉绿岩,辉绿岩锆石LA-ICP-MS U-Pb年龄为348.3±2.6 Ma,为低钾拉斑玄武系列,相对富集LILE,亏损Nb、Ta等高场强元素. 甲哈达基性岩岩性主要为玄武岩,锆石U-Pb年龄为317.6±3.0 Ma,为钙碱性系列,同样具有HFSE亏损和LILE富集的特点,与杜尔基基性岩相比更加富集LILE和LREE. 结合贺根山缝合带早石炭世蛇绿岩及洋内俯冲作用的研究成果,认为从杜尔基基性岩到甲哈达基性岩的演化,可能指示了古亚洲洋东段早-晚石炭世洋内俯冲的渐进过程,洋内弧从不成熟向逐渐成熟演化.   相似文献