Metallogenesis of Porphyry Cu Deposits of the Western Luzon Arc, Philippines: K-Ar ages, SO₃ Contents of Microphenocrystic Apatite and Significance of Intrusive Rocks     

Akira IMAI 《Resource Geology》2002,52(2):147-161

Abstract: K–Ar ages of the following porphyry Cu deposits in the western Luzon arc are determined: Lobo-Boneng (10.50.4 Ma), Santo Niño (9.50.3 Ma), Black Mountain (2.10.1 Ma), Dizon (2.50.2 Ma) and Taysan (7.30.2 Ma). Microphenocrys-tic apatite in the late Cenozoic intermediate to silicic intrusions associated with porphyry Cu deposits in the western Luzon arc contains sulfur as SO₃ detectable by electron probe microanalyzer. Sulfur is supposed to have been accommodated dominantly as oxidized species in oxidizing hydrous magmas that generated porphyry Cu deposits. Likewise, such high SO₃ contents in microphenocrystic apatite are common characteristics of the intermediate to silicic magmatism of the western Luzon arc, from tonalitic rocks of the Luzon Central Cordillera of about 15 Ma to an active magmatism at Mount Pinatubo. Thus, the western Luzon arc has been generating porphyry Cu mineralization associated with oxidizing hydrous intermediate to silicic magmatism related to eastward subduction, since Miocene to the present day. Intermediate to silicic rocks since 15 Ma to present-day western Luzon arc generally show high whole-rock Sr/Y ratio ranging from 20 to 184. However, porphyry Cu deposit is not necessarily related to the rocks that show higher Sr/Y ratios compared to the other barren rocks in the western Luzon arc. The characteristics of the intermediate to silicic magma associated with porphyry Cu deposit are not attributed to the composition of the source material of the magma, but to the properties defined by the high activity of oxidized species of sulfur in the fluid phase that is encountered during the generation of intermediate to silicic magmas.  相似文献   

Variabilité isotopique des précipitations sahéliennes à différentes échelles de temps à Niamey (Niger) entre 1992 et 1999 : implication climatiqueIsotopic variability of Sahelian rainfall at different time steps in Niamey (Niger, 1992–1999): climatic implications     

Jean-Denis Taupin  Gaëlle Gaultier  Guillaume Favreau  Christian Leduc  Christelle Marlin 《Comptes Rendus Geoscience》2002,334(1):43-50

The isotopic content of rainfall was measured in Niamey (Niger) over a period of eight years (1992–1999). Seasonal distribution of rainy events depends on the monsoon movement over the region. At the beginning and at the end of the rainy season, low rainfall, high temperatures and low relative humidity favour isotopic enrichment. In the middle of the rainy season, heavy rainfall, low temperatures and relative humidity close to saturation lead to isotopically depleted contents because of the mass effect; moreover, in the case of low rainfall, marked vertical convective development favours high altitude condensation. How far the Intertropical Front moves north, determines the quality of the rainy season and influences the isotopic contents. Thus the isotopic contents of rainfall are good climatic indicators. To cite this article: J.-D. Taupin et al., C. R. Geoscience 334 (2002) 43–50  相似文献   

Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons   总被引：1，自引：0，他引：1  

B. Heisinger  D. Lal  A. J. T. Jull  P. Kubik  S. Ivy-Ochs  K. Knie  E. Nolte   《Earth and Planetary Science Letters》2002,200(3-4):357-369

We have determined the production yields for radionuclides in Al₂O₃, SiO₂, S, Ar, K₂SO₄, CaCO₃, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides ¹⁰Be, ¹⁴C and ²⁶Al produced in quartz targets, ²⁶Al in Al₂O₃ and S targets, ³⁶Cl in K₂SO₄ and CaCO₃ targets, and ⁵³Mn in Fe₂O₃ targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ⁻ capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ⁻ capture, by fast muons and by neutron capture.  相似文献   

Isotope variations in a Sierra Nevada snowpack and their relation to meltwater     

Padinare V. Unnikrishna  Jeffrey J. McDonnell  Carol Kendall   《Journal of Hydrology》2002,260(1-4):38-57

Isotopic variations in melting snow are poorly understood. We made weekly measurements at the Central Sierra Snow Laboratory, California, of snow temperature, density, water equivalent and liquid water volume to examine how physical changes within the snowpack govern meltwater δ¹⁸O. Snowpack samples were extracted at 0.1 m intervals from ground level to the top of the snowpack profile between December 1991 and April 1992. Approximately 800 mm of precipitation fell during the study period with δ¹⁸O values between −21.35 and −4.25‰. Corresponding snowpack δ¹⁸O ranged from −22.25 to −6.25‰. The coefficient of variation of δ¹⁸O in snowpack levels decreased from −0.37 to −0.07 from winter to spring, indicating isotopic snowpack homogenization. Meltwater δ¹⁸O ranged from −15.30 to −8.05‰, with variations of up to 2.95‰ observed within a single snowmelt episode, highlighting the need for frequent sampling. Early snowmelt originated in the lower snowpack with higher δ¹⁸O through ground heat flux and rainfall. After the snowpack became isothermal, infiltrating snowmelt displaced the higher δ¹⁸O liquid in the lower snowpack through a piston flow process. Fractionation analysis using a two-component mixing model on the isothermal snowpack indicated that δ¹⁸O in the initial and final half of major snowmelt was 1.30‰ lower and 1.45‰ higher, respectively, than the value from simple mixing. Mean snowpack δ¹⁸O on individual profiling days showed a steady increase from −15.15 to −12.05‰ due to removal of lower δ¹⁸O snowmelt and addition of higher δ¹⁸O rainfall. Results suggest that direct sampling of snowmelt and snow cores should be undertaken to quantify tracer input compositions adequately. The snowmelt sequence also suggests that regimes of early lower δ¹⁸O and later higher δ¹⁸O melt may be modeled and used in catchment tracing studies.  相似文献   

Stable isotope values of Costa Rican surface waters   总被引：3，自引：0，他引：3  

Matthew S. Lachniet  William P. Patterson 《Journal of Hydrology》2002,260(1-4):135-150

Stable isotope data of surface waters from the humid tropics in general, and Costa Rica in particular, are scarce. To improve our understanding of the spatial distribution of stable isotopes in surface waters, we measured δ¹⁸O and δD in river and lake (n=63) and precipitation (n=3) samples from Costa Rica. We also present data from the IAEA/WMO isotopes in precipitation network as context for our study. Surface water isotope values do not strongly correlate with elevation, stream head elevation, stream length, distance from Caribbean Sea, or estimated mean annual precipitation for the country as a whole. However, the data show distinct regional trends. The δ¹⁸O and δD values downwind of mountain ranges are inversely related to the altitude of the ranges the air masses traverse. In the lee of the high Talamanca Range, δ¹⁸O values are 6–8‰ lower, while in the lee of the lower Tilarán Range δ¹⁸O values are 2–3‰ lower than upwind sites along the Caribbean Slope. An altitude effect of −1.4‰ δ¹⁸O/km is present on the Pacific slope of southern Costa Rica, equivalent to a temperature effect of −0.3‰/°C. The Nicoya and Osa Peninsulas have higher values than upwind sites, suggesting input of Pacific-sourced moisture, evaporative enrichment, or decreased condensation temperatures. Elevated and increasing d-excess values inland along the Nicaragua Trough suggest a recycled component may be an important contributor to the water budget. These data provide preliminary stable isotope information for Costa Rica, and will benefit paleoclimatic research in the region. More detailed studies would be beneficial to our understanding of the controls on stable isotope composition of tropical waters.  相似文献   

Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A     

Lui-Heung Chan  Jeffrey C Alt 《Earth and Planetary Science Letters》2002,201(1):187-201

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.  相似文献   

Changes in the mode of Southern Ocean circulation over the last glacial cycle revealed by foraminiferal stable isotopic variability     

Ulysses S Ninnemann  Christopher D Charles 《Earth and Planetary Science Letters》2002,201(2):383-396

Benthic foraminiferal oxygen and carbon isotopic records from Southern Ocean sediment cores show that during the last glacial period, the South Atlantic sector of the deep Southern Ocean filled to roughly 2500 m with water uniformly low in δ¹³C, resulting in the appearance of a strong mid-depth nutricline similar to those observed in glacial northern oceans. Concomitantly, deep water isotopic gradients developed between the Pacific and Atlantic sectors of the Southern Ocean; the δ¹³C of benthic foraminifera in Pacific sediments remained significantly higher than those in the Atlantic during the glacial episode. These two observations help to define the extent of what has become known as the ‘Southern Ocean low δ¹³C problem’. One explanation for this glacial distribution of δ¹³C calls upon surface productivity overprints or changes in the microhabitat of benthic foraminifera to lower glacial age δ¹³C values. We show here, however, that glacial-interglacial δ¹³C shifts are similarly large everywhere in the deep South Atlantic, regardless of productivity regime or sedimentary environment. Furthermore, the degree of isotopic decoupling between the Atlantic and Pacific basins is proportional to the magnitude of δ¹³C change in the Atlantic on all time scales. Thus, we conclude that the profoundly altered distribution of δ¹³C in the glacial Southern Ocean is most likely the result of deep ocean circulation changes. While the characteristics of the Southern Ocean δ¹³C records clearly point to reduced North Atlantic Deep Water input during glacial periods, the basinal differences suggest that the mode of Southern Ocean deep water formation must have been altered as well.  相似文献   

极地冰雪氢氧同位素指标及其指示意义   总被引：1，自引：0，他引：1       下载免费PDF全文

张小伟  康建成  周尚哲 《极地研究》2002,14(1):73-80

本文综述了水汽来源状况、降水季节变化、火山喷发、太阳活动等气候环境因素对极地冰雪中同位素含量的可能影响及其程度 ,以及降水区域不均衡性、降水年际不均衡性、逆温层和同位素在冰雪中的扩散迁移作用等几种不稳定因素可能对冰雪同位素分析造成的干扰 ;在此基础上 ,综述了极地冰雪中δ1 8O、δD和其差值d(d =δD - 8δ1 8O)与局部或全球气温之间的一些线性关系 (包括全球尺度 ,格陵兰地区 ,南极地区等 )及它们在空间分布上的变化规律  相似文献   

贵州寒武系底部黑色硅质岩成因及沉积环境探讨   总被引：14，自引：1，他引：14  

张位华  姜立君  高慧  杨瑞东 《矿物岩石地球化学通报》2003,22(2):174-178

贵州寒武系底部形成的黑色层状硅质岩，岩石展布广，层位稳定，厚度较大。硅质岩的δ^30Si值为—0．1‰～0．9‰，平均0．314‰；δ^18O值为12．8‰～21．2‰，通过δ^18O值计算出该区硅质岩形成温度82．2～162．5℃；硅质岩富含Ba、As、Sb、Bi和U，呈明显的Ce负异常。硅质岩的地球化学特征表明其主要成因是热水沉积作用。同时由于硅质岩主要是热水来源，所以在讨论其形成环境时还结合了岩相古地理的方法，指出该套硅质岩形成于深水缓坡至浅水滞流海环境之中。  相似文献   

兰坪白秧坪铜银多金属矿床成矿物质来源的铅和硫同位素示踪   总被引：9，自引：0，他引：9       下载免费PDF全文

王峰  何明友 《沉积与特提斯地质》2003,23(2):82-85

白秧坪铜银多金属矿床主要产于白垩系下统景星组石英砂岩、粉砂岩中，矿石铅同位素组成特征与景星组砂岩的铅同位素组成比较接近，表明壳源物质参与了成矿作用。作ZartMan图解和△γ—△β图解表明，矿石铅属于壳幔混合来源。矿石铅μ值介于9．43—9．65之间，Th/U比值介于3．72—3．87之间，表明矿石铅为壳幔混合铅。该矿床硫同位素组成表明，硫来源于深部地幔硫遭受地壳硫的混入。该矿床的成矿作用发生于开放体系之中，成矿物质来源为深部幔源物质混合了壳源物质。  相似文献