25～75℃酸性NaCl溶液中方铅矿的溶解动力学   总被引：4，自引：0，他引：4  

张生  李建平  王玉荣  胡光黔 《地球化学》2002,31(6):587-592

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。  相似文献   

Ordovician Graptolite Rhabdosome Complication and Its Implications on Sea Level Changes     

Wang Chuanshang  Wang Xiaofeng  Chen Xiaohong 《中国地质大学学报(英文版)》2002,13(3)

A total of four times of rhabdosome complication events, i.e., the lateral branching of graptolite stipes during the Late Middle Ordovician, the secondary branching of graptolite stipes at the earliest Upper Ordovician, the early Qiantangjiangian of Upper Ordovician and the middle Qiantangjiangian, respectively, is discussed in this paper. These events and other adaptation events demonstrate close relationships between a diverse graptolite fauna and sea level changes, and consequently can be employed to study sea level fluctuations. It is safe to conclude that the complication of rhabdosome started at the maximum flooding surface (MFS) and terminated at the beginning of regression.  相似文献   

Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol     

Mark E. Hodson 《Chemical Geology》2002,190(1-4):91-112

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.  相似文献   

桩土接触面单元参数分析   总被引：11，自引：0，他引：11       下载免费PDF全文

许宏发  吴华杰  郭少平  廖铁平 《探矿工程》2002,(5):10-12

桩的抗拔特性与接触面的特性密切相关，正确选定接触面的力学参数对于分析桩的抗拔机理有重要意义。根据桩土接触面点面接触模型和库仑摩擦变形原理，在10组土－结构（钢、混凝土）剪切摩擦试验分析的基础上，对桩土接触面摩擦参数的取值问题进行了研究，得到了一些结论，对于桩土接触面力学参数正确取值有一定的参考价值。  相似文献   

Une méthode de quantification de la dégradation d'un escarpement de faille au cours des cycles climatiques du Quaternaire : la faille de Jobourg (Nord Cotentin,France)Quantification of a fault-scarp degradation through Quaternary: the Jobourg fault (North Cotentin,France)     

Marianne Font  Jean-Louis Lagarde  Daniel Amorese  Jean-Pierre Coutard  Jean-Claude Ozouf 《Comptes Rendus Geoscience》2002,334(3):171-178

The degradation of the Jobourg fault-scarp occurred by cryoclastic processes in a periglacial environment during a part of Quaternary time. An attempt of quantification indicates a bulk scarp erosion of about 39 m³ m^?2, while the head accumulated at the bottom of the fault scarp only represents 4.6 m³ m^?2. To cite this article: M. Font et al., C. R. Geoscience 334 (2002) 171–178.  相似文献   

山西水2井和岳42井水位记震能力分析   总被引：2，自引：1，他引：2       下载免费PDF全文

张子广  张素欣  郑云贞  王贺生 《地震工程学报》2002,24(3):262-266

对比分析了唐山地区同一地质单元内、同一观测含水层、水位动态相同的山西水2井和岳42井记录的水震波曲线，显示两井记震能力相差很大，从井孔结构、地震面波特性等方面分析了两井记震能力差异性的成因机理，结果表明，井孔的固有周期是影响水位记震能力大小的首要条件。  相似文献   

Processes in microbial transport in the natural subsurface     

Timothy R. Ginn  Brian D. Wood  Kirk E. Nelson  Timothy D. Scheibe  Ellyn M. Murphy  T.Prabhakar Clement   《Advances in water resources》2002,25(8-12)

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辽宁城市活断层探测思路与方法探讨     

高常波  吴小兵  万波  钟以章 《东北地震研究》2002,18(4):1-6

介绍了开展地震活断层探测的意义及在辽宁省开展地震活断层探测的必要性，对在辽宁城市开展活断层探测的基本思路和方法进行了探讨，选取沈阳，抚顺作为试点城市，设定目标区和目标断裂，分别对活断层危险性，危害性和深部发震构造环境进行评价。在断裂探测过程中，确定初步探测和详细探测两个阶段，主要采用人工地震方法并结合钻探，地震划分结果，对目标区内的目标断裂进行评价。  相似文献   

Improved treatments for evaluating horizontal magnetic components through the 3-D FDM in E -polarization induction problems     

Chen Po-fang 《地震学报(英文版)》2002,15(5):519-525

To improve the accuracy of the numerical evaluation through the 3-D finite difference method, the surface boundary conditions are added to modify the old program. The author has tested the new program by making calculations for the model constructed by Wanamaker, et al (1984). The comparison between the numerical results obtained from this paper and those by Wannamaker, et al (1984) indicates that a pronounced improvement is realized in the evaluation of the horizontal magnetic components. Moreover, better calculations for the vertical magnetic components are also obtainable by using the new program.  相似文献   

青藏高原大气—植被相互作用的模拟试验——Ⅰ.物理通量和参数   总被引：5，自引：0，他引：5       下载免费PDF全文

吕建华  季劲钧 《大气科学》2002,26(1):111-126

在原大气-植被相互作用模式AVIM的基础上作了改进，包括对值被生理过程，如（1）光合作用：（2）呼吸；（3）分配和（4）物候等新的描述方法。对青藏高原上30个站点进行模拟计算，给出了高压上地表辐射及水热物理通量以及地表拖曳系数和地面反照率的分布特征。模拟结果表明净辐射和感热通量由东南和西北增加，高原西北部地表反照率较高，东南部地表反照率较低。  相似文献