原油族组分成气的化学动力学模型及其标定   总被引：27，自引：2，他引：27       下载免费PDF全文

卢双舫  付晓泰 《地质学报》1997,71(4):367-373

利用等温密封热解实验技术及恒速升温热解实验与PY—GC分析技术的结合,本文分别建立并标定了原油中各族组分,即饱和烃、芳烃、非烃和沥青质成气的化学动力学模型。结果表明,原油中不同族组分成气的过程均可用平行一级反应描述,但不同组分在平均活化能及活化能分布上有明显的差异。各族组分在地史过程中成气的过程可由各自的化学动力学模型来描述。这将使原油成气过程的定量、动态描述成为可能。  相似文献   

大跨度切眼锚网锚索支护研究   总被引：5，自引：0，他引：5  

吴添泉 《岩土力学》2004,25(Z1):141-143

全煤大跨度切眼传统的支护方式是钢棚支护,为解决无轨胶轮车直接进入工作面,提高工作面设备安装效率,课题组进行锚网锚索支护试验与研究。该项目的试验成功,为矿井高产高效创造了条件。  相似文献   

鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究   总被引：15，自引：0，他引：15  

刘德汉  付金华  郑聪斌  肖贤明  米敬奎 《地质学报》2004,78(4):542-550

用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%～ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰～ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰～ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因  相似文献   

Differential retardation of organic matter maturation by overpressure   总被引：2，自引：1，他引：2  

HAO Fang    JIANG Jianqun  ZOU Huayao  FANG Yong & ZENG Zhiping . Key Lab for Hydrocarbon Accumulation Mechanism in the Ministry of Education  Petroleum University  Beijing  China  . Department of Petroleum Geology  China University of Geosciences  Wuhan  China 《中国科学D辑(英文版)》2004,47(9)

Thetraditionalhydrocarbongenerationmodeldoesnottakeintoaccounttheeffectofpressure[1].Astotheroleofpressureinorganicmattermaturationandpetroleumgeneration,threeconflictingopinionshaveeverbeenproposed:(1)Increasingpressurehasnodetectableeffectonorganic-mattermaturation[1,2];(2)increasingpressureenhanceshydrocarbon-thermaldestruction[3];(3)increasingpressuresignificantlyretardsorganic-mattermaturationandhydrocarbongeneration[4,5].Therearemorethan180overpressuredbasinsintheworld.Theroleofoverpress…  相似文献   

Accuracy analysis, dem generation and validation using russian tk-350 stereo-images     

Gürcan Büyüksalih  Güven Koçak  Murat Oruç  Hakan Akçin  Karsten Jacobsen 《The Photogrammetric Record》2004,19(107):200-218

TK-350 stereo-scenes of the Zonguldak testfield in the north-west of Turkey have been analysed. The imagery had a base-to-height ratio of 0·52 and covered an area of 200 km × 300 km, with each pixel representing 10 m on the ground. Control points digitised from 1:25 000 scale topographic maps were used in the test. A bundle orientation was executed using the University of Hanover program BLUH and PCI Geomatica OrthoEngine AE software packages. Tests revealed that TK-350 stereo-images can yield 3D geopositioning to an accuracy of about 10 m in planimetry and 17 m in height. A 40 m resolution digital elevation model (DEM) was generated by the PCI system and compared against a reference DEM, which was derived from digitised contour lines provided by 1:25 000 scale topographic maps. This comparison showed that accuracy depends mainly on the surface structure and the slope of the local terrain. Root mean square errors in height were found to be about 27 and 39 m outside and inside forested areas, respectively. The matched DEM demonstrated a systematic shift against the reference DEM visible as an asymmetric shift in the frequency distribution. This is perhaps caused by the presence of vegetation and buildings.  相似文献   

复杂区域四边形网格生成的一种改进方法     

冯道雨  陈尚法  陈胜宏 《岩土力学》2004,25(6):917-921

提出了一种改进的四边形网格生成算法。该法在行波法生成平面三角形网格的基础上，将一个三角形单元分解为三个四边形单元。经过优化处理，获得优良的计算域四边形网格。针对岩土工程结构问题，还提出了网格剖分中尖灭不连续面和锚杆及锚索的处理方案。地下洞室和边坡算例表明了这种方法的可行性和可靠性。  相似文献   

潜水面变动的空间四面体单元网格自动生成方法          下载免费PDF全文

成建梅  黄丹红  胡进武 《水科学进展》2004,15(3):276-279

提出了一种由平面三角网格自动生成三维空间四面体单元网格的方法,其基本思路是将含水层平面分成三角形单元网格,将每个三角形沿垂直方向对应一个三棱柱,作为最初的三棱柱;依次将每个三棱柱按照潜水面位置和分层信息划分成不同数目的四面体,从而生成三维空间四面体单元网格。剖分结果表明,此方法综合考虑了潜水面的位置和各含水层顶底板的起伏情况,能够简洁地生成层面起伏的空间四面体网格,特别适用于刻画潜水面波动、含水层顶底板起伏和存在透镜体或岩性缺失等含水层结构复杂的情况下,自动地剖分并生成单元信息,为三维计算的实现奠定了基础。  相似文献   

闽东北地区夏季对流云特征的初步分析     

左平昭  陈秋萍  郭正明  陈德汶  刘锐志 《气象科技》2005,(Z1)

利用新一代天气雷达资料分析闽东北地区夏季对流云的回波特征。分析表明:多单体合并对流云在生命史、回波高度、强度、尺度等方面都超过了单体对流云,其液态水总量也更大,自然降水条件和人工影响潜力都优于单体对流云,是夏季降水和人工催化的重要云系。分析得到对流云发展的不同阶段、不同高度层辐合辐散特点,为进一步研究夏季对流云结构和降水原理提供科学依据。通过对两个个例的天气形势分析,指出冷空气对对流发展有一定的激发作用。  相似文献   

Magma generation and crustal accretion as evidenced by supra-subduction ophiolites of the Albanide–Hellenide Subpelagonian zone     

Luigi  Beccaluva  Massimo  Coltorti  Emilio  Saccani  Franca  Siena 《Island Arc》2005,14(4):551-563

Abstract Ophiolites of the Mirdita–Subpelagonian zone form a nearly continuous belt in the Albanide–Hellenide orogen, including mid‐ocean ridge basalt (MORB) associations in the western Mirdita sector and supra‐subduction zone (SSZ) complexes, with prevalent island arc tholeiitic (IAT) and minor boninitic affinities in the eastern part of the belt (i.e. eastern Mirdita, Pindos, Vourinos). In addition, basalts with geochemical features intermediate between MORB and IAT (MORB/IAT) are found in the central Mirdita and in the Aspropotamos sequence (Pindos). These basalts alternate with pure MORB and are cut by boninitic dykes. The distinctive compositional characteristics of the mafic magmas parental to the different ophiolitic suites can be accounted for by partial melting of mantle sources progressively depleted by melt extractions. Partial melting processes (10–20%) of lherzolitic sources generated pure MORB, leaving clinopyroxene‐poor lherzolite as a residuum. Approximately 10% water‐assisted partial melting of this latter source, in an SSZ setting, may in turn generate basalts with MORB/IAT intermediate characteristics, whereas IAT basalts and boninites may have been derived from 10–20% and 30% partial melting, respectively, of the same source variably enriched by subduction‐derived fluids. In addition, boninites may also have been derived by comparatively lower degrees of hydrated partial melting of more refractory harzburgitic sources. A generalized petrologic model based on mass balance calculations between bulk rock and mineral compositions, indicate that most of the intrusives (from ultramafic cumulates to gabbronorites and plagiogranites), as well as sheeted dykes and volcanics (from basalts to rhyodacites) forming the bulk crustal section of the SSZ ophiolites, may be accounted for by shallow fractional crystallization from low‐Ti picritic parental magmas very similar in composition to IAT picrites from Pacific intraoceanic arcs. The most appropriate tectono‐magmatic model for the generation of the SSZ Tethyan ophiolites implies low velocity plate‐convergence of the intraoceanic subduction and generation of a nascent arc with IAT affinity and progressive slab roll‐back, mantle diapirism and extension from the arc axis to the forearc region, with generation of MORB/IAT intermediate basalts and boninitic magmas.  相似文献   

玄武岩浆起源和演化的一些基本概念以及对中国东部中-新生代基性火山岩成因的新思路   总被引：44，自引：3，他引：44  

牛耀龄 《高校地质学报》2005,11(1):9-46

以全球大地构造为背景讨论了玄武岩浆起源和演化的一些基本概念.这些概念的正确理解有助于合理解释各种环境中火成岩的形成机制,也有助于依据野外岩石组合来判别古构造环境.在此基础上结合已有资料和观察,对中国东部中生代岩石圈减薄及中-新生代基性火山岩成因提出了一些新解释.这些解释与地质观察相吻合,且符合基本的物理学原理.虽然中国东部基性火山活动可称为"板内"火山活动,但它实际上是板块构造的特殊产物.中国东部中生代岩石圈减薄是其下部被改造为软流层的缘故.这种改造是加水"软化"所致.水则源于中国东部地幔过渡带(410～660 km)内古太平洋(或其前身)俯冲板块脱水作用.其将岩石圈底部改造为软流层的过程,实际上就是岩石圈减薄的过程.因为软流层是地幔对流的重要部分,而大陆岩石圈则不直接参与地幔对流.中生代玄武岩具有εNd＜0的特征,说明其源于新近改造而成的软流层,亦即原古老岩石圈之底部.中国大陆北北东-南南西向的海拔梯度突变界线与东-西部重力异常,陆壳厚度变化,以及地幔地震波速变化梯度吻合.因此可将北北东-南南西向梯度线称为"东-西梯度界".该界东-西海拔高差(西部高原与东部丘陵平原),陆壳厚度差异(西部厚而东部薄)和100～150 km的深度范围地幔地震波速差异(西部快而东部慢),均受控于上地幔重力均衡原理.这表明西部高原岩石圈厚度＞150～200 km,而东部丘陵平原岩石圈厚度＜80km."遥远"的西太平洋俯冲带具有自然的地幔楔吸引作用.此吸引作用可引起中国东部"新生"软流层东流.软流层东流必将引起西部高原底部软流层的东向补给(流动).这一过程必然导致东移软流层的减压,即从西部的深源(岩石圈深度＞150～200 km处)到东部的浅源(岩石圈深度～80km处).东移软流层的减压分熔可合理解释具有软流圈地球化学特征(εNd＞0)的新生代中国东部基性火山活动及玄武岩的成因.这些对中国东部中-新生代地质过程的解释,将为更加细致的,以岩石学和地球化学为主的讨论所验证.  相似文献