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The conditional acid dissociation constants (pKa′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pKa′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln−1):
The estimated accuracy of pH measurements using these calculated pKa′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.  相似文献   
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Abstract. Two sediment cores were collected in the southern Baltic Sea and sliced into 1.0cm-thick layers. Sediments of each layer were analysed for activities of 210Pb, 137Cs, 134Cs and for the density of meiobenthic organisms (meiofauna). Zones with the rapid mixing occur in the uppermost layers (0–3 cm) of the cores based on I34Cs profiles. The extent and density of meiofauna confirmed the rapid mixing and revealed layers with slow mixing (4–8 cm). Sedimentation rates were derived from 210Pb profiles below the mixing zones (1.21 and 1.72 mm a-I) and were confumed by 137Cs distribution. Of twenty-one major meiofauna taxa commonly found in the Baltic sediments, three were present in the cores.  相似文献   
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通过对张家山铁矿床矿体与围岩的接触关系、蚀变特征、矿石的矿物组合、化学组分等地质特征及成因的分析研究,认为张家山铁矿床应属风化淋滤型铁矿床,其原生矿床为铁多金属硫化物矿床,并厘定了该地区铁矿的找矿标志。  相似文献   
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Apatite fission-track (AFT) thermochronological modeling as a diagnostic tool for periods of stability (peneplanation) and tectonic activity (orogeny) has been broadly used in tectonic studies of Central Asia in recent years. We discuss more than 100 AFT ages of samples from the Kyrgyz Tien Shan and Altai and compare them with AFT data from northern Kazakhstan. Geological, geomorphological, and AFT data indicate intense activity in the Late Cenozoic Eurasian continental interior. The impact from the India-Eurasia collision on the northern Tien Shan, Altai, and northern Kazakhstan regions showed up at 11, 5, and 3 Ma, respectively, as a result of stress propagation into the continent, with the ensuing reactivation and mountain growth. We hypothesize that a distant effect of the Late Cenozoic India-Eurasia collision was to rejuvenate Paleozoic fault zones and to deform the Mesozoic sedimentary cover north of the collision front as far as the West Siberian Plate. The reactivation facilitated formation of tectonic oil and gas traps. The activity in northern Central Asia under the effect of the Indian indentation into Eurasia appears to continue and may evolve to include uplift of southern West Siberian plate with uplift.  相似文献   
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The recommended concentrations of 239Pu, 240Pu and 239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of 239Pu and 240Pu (239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of 242Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg?1, (28 ± 3) Bq kg?1 and (66 ± 4) Bq kg?1 are proposed as recommended values for 239Pu, 240Pu and 239+240Pu, respectively, and (9.5 ± 0.4) Bq kg?1 for 238Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg?1, (3.3 ± 0.4) ng kg?1 and (0.015 ± 0.003) ng kg?1 for 239Pu, 240Pu and 238Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.  相似文献   
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Predictably, in a country such as Britain, with its preponderance of consolidated, sedimentary, mainly fissure-flow aquifers, there is a very large number of springs, many of which are, or have been, used for public supply. Migratory springs are a feature of the British (Ur. Cretaceous) Chalk, the most important British aquifer. The Chalk's low specific yield and high capillary moisture retention together give rise to very considerable fluctuations (more than 33 m in some areas) of the unconfined water table. Along the gentle dip slopes of the Chalk (North and South Downs of southern and southeastern England) springs may migrate laterally for several miles, giving rise to seasonal streams locally known as bournes or lavants. However, springs such as at Duncton, West Sussex, at the base of the much steeper scarp slopes of the Chalk, form point sources, the flows from which tend to be relatively steady; such springs commonly supply and are the original reason for the existence of many of the small towns and villages which nestle along the bases of the chalk scarps of Sussex and Kent.Where the Chalk forms coastal cliffs, a number of springs break out at the base of the cliff between high and low tide levels; there are major chalk coastal springs, for instance, at St. Margaret's Bay (Kent) and at Arish Mells, east of Lulworth Cove, Dorset. Such springs are not used for direct supply (their salinity is usually too high) but are indicators of the presence of local reserves of groundwater for possible future development.  相似文献   
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三工河流域新老绿洲发育度的比较   总被引:1,自引:0,他引:1  
绿洲是干旱区最重要的景观单元之一。人工绿洲是在干旱条件下经长期人类活动改造而形成的特殊景观。随着人类对绿洲水土资源开发利用程度的不断加强,绿洲呈现出不同的发展阶段。从天然绿洲到人工绿洲,是人类适应和改造干旱区自然环境的历程。在这一人地相互作用的过程中,绿洲显示出明显的发育演化特征。从多学科综合的角度,提出绿洲发育度的概念,并从灌溉体系的建设状况、水资源的利用水平、植被与生态建设、农业发展程度、社会经济水平和绿洲景观结构等7个方面提出了绿洲发育度的评价指标体系,以天山北坡2个人工绿洲为例,从空间上定量比较2个绿洲的发育程度,其中阜康市绿洲发育度高于222团绿洲(阜北农场)。  相似文献   
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