Petrogenetic modelling of strongly residual metapelitic xenoliths within the southern Platreef,Bushveld Complex,South Africa     

T. E. JOHNSON  M. BROWN  R. W. WHITE 《Journal of Metamorphic Geology》2010,28(3):269-291

Xenoliths of quartz‐absent Fe‐rich aluminous metapelite are common within the platinum group element‐rich mafic/ultramafic magmatic rocks of the Platreef. Relative to well‐characterized protoliths, the xenoliths are strongly depleted in K₂O and H₂O, and have lost a substantial amount of melt (>50 vol.%). Mineral equilibria calculations in the NCKFMASHTO system yield results that are consistent with observations in natural samples. Lower‐grade rocks that lack staurolite constrain peak pressures to ～2.5 kbar in the southern Platreef. Smaller xenoliths and the margins of larger xenoliths comprise micro‐diatexite rich in coarse acicular corundum and spinel, which record evidence for the metastable persistence of lower‐grade hydrous phases and rapid melting consequent on a temperature overstep of several hundred degrees following their incorporation in the mafic/ultramafic magmas. In the cores of larger xenoliths, temperatures increased more slowly enabling progressive metamorphism by continuous prograde equilibration and the loss of H₂O by subsolidus dehydration; the H₂O migrated to xenolith margins where it may have promoted increased melting. According to variations in the original compositional layering, layers became aluminosilicate‐ and/or cordierite‐rich, commonly with spinel but only rarely with corundum. The differing mineralogical and microstructural evolution of the xenoliths depends on heating rates (governed by their size and, therefore, proximity to the Platreef magmas) and the pre‐intrusive metamorphic grade of the protoliths. The presence or absence of certain phases, particularly corundum, is strongly influenced by the degree of metastable retention of lower‐grade hydrates in otherwise identical protolith bulk compositions. The preservation of fine‐scale compositional layering that is inferred to be relict bedding in xenolith cores implies that melt loss by compaction was extremely efficient.  相似文献   

THERMODYNAMIC PROPERTIES AND ROLE OF THERMALS IN THE STRATUS-TOPPED BOUNDARY LAYER          下载免费PDF全文

申绍华  周明煜 《Acta Meteorologica Sinica》1994,(3)

From results of two large-eddy simulation of stratus-topped boundary layer,the structure,thermodynamic prop-erties and role of thermals are investigated by using conditional sampling methods,which divided the thermals into thewarm/moist,cool/dry,warm/dry and cool/moist events.The results show that the main turbulent circulation in thestratus-topped boundary layer is composed of the warm/moist updraft and cool/dry downdraft.Below entrainmentregion,the warm/moist updrafts and cool/dry downdrafts are,respectively,positively and negatively buoyant andcontribute most to total fluxes and variances.Evaporative cooling has important effect on the structure and thermodynamic properties of thermals instratus-topped boundary layer.  相似文献   

链烷烃的热力学性质与分子拓扑指数的关系   总被引：1，自引：0，他引：1  

饶火瑜  朱霞萍  乐长高 《华东地质学院学报》2002,25(3):244-249

定义了一种新的连接性指数^1Y=Σk1/m^2 n^2,研究了链烷烃的标准生成焓、标准熵、标准生成吉布斯自由能等三个热力学性质与碳原子个数N，^1Y之间的定量关系，相关系数为优，其计算值与实验值较为接近，对未参与回归的正癸烷的60个异构体的三个热力学性质进行了计算，计算值与实验值较一致。  相似文献   

高温铀物种形成(Speciation)的热力学数据     

黄克玲  周鲁民  张景廉 《铀矿地质》1993,(6)

本文依据C.M.Criss和J.W.Cobble的“离子熵对应原理”,对1978年D.Langmuir给出的铀物种形成常温热力学数据进行了高温值的处理,得出了一套较全面而系统的高温热力学参数,以供参考使用。  相似文献   

我国干旱地区一次直升机自然结冰试飞天气个例分析     

王泽林  倪洪波  裴昌春 《沙漠与绿洲气象(新疆气象)》2020,14(2):68-74

2018年3月17日、27日,国产某型直升机在新疆五家渠地区成功完成2架次自然结冰试飞。利用NCEP/NCAR的1°×1°再分析资料、机测液态水含量资料结合常规气象资料,对2次结冰天气过程的天气环流形势、动力热力特征、液态水含量进行分析。结果表明:17日在高空冷涡、地面冷锋前的环流形势下,试飞高度层位于冷暖平流交汇处,温度为0～-4℃,比湿值为3～3.5 g/kg,处于强水汽辐合中心,并伴有弱上升运动,Ic积冰指数为20～30,云中液态水含量波动较大,飞机挂架上形成0.5 cm厚度的凇冰。27日在高空槽前和地面冷锋后的环流形势下,试飞高度层在弱冷平流中心附近,温度为0～-2℃,比湿值接近4.5 g/kg,处于弱水汽辐合中心边缘,伴有弱上升运动,Ic积冰指数为30～40,云中液态水含量稳定,飞机挂架上形成1～2 cm厚度的明冰。在气象保障中运用探空、云图、雷达、微波辐射计等资料有效预报了积冰区域及高度。  相似文献   

THE RELATIONSHIP BETWEEN SCS SUMMER MONSOON INTENSITY AND OCEANIC THERMODYNAMIC VARIABLES AT DIFFERENT TIME SCALE     

谷德军  纪忠萍  王东晓  梁建茵  方一川 《热带气象学报(英文版)》2007,13(1):85-88

The oscillation characteristics of 1948 - 2003 South China Sea (SCS) summer monsoon intensity (SCSSMI) is analyzed by wavelet transform and the relationship between SCSSMI filtered by Lanczos filter at different time scale and oceanic thermal conditions is studied. The results show that SCSSMI exhibits dominant interannual (about 4 a), decadal (about 9 a) and interdecadal (about 38 a) oscillation periods. The interannual variation is the strongest and the interdecadal variation the weakest. The region of significant correlation between SCS summer monsoon intensity and oceanic thermodynamic variables at different time scale is greatly different. Significant correlation area of interannual variation of SCSSMI is concentrated in near equatorial region. Corresponding correlation displays quasi-biannual variability. If positive anomalies of SST and the depth of thermocline happen in eastern equatorial Indian Ocean and western equatorial Pacific, and negative anomalies of SST and the depth of thermocline happen in western equatorial Indian Ocean and eastern equatorial Pacific in previous autumn and winter, the interannual variation of SCSSMI will enhance. If the condition is contrary, interannual variation of SCSSMI will weaken. The interannual variation of SCSSMI will influence SST. The region surrounding SCS and east of Australia shows significantly negative correlation in autumn, and significantly positive correlation exhibits in west equatorial Indian Ocean, eastern equatorial Pacific and equatorial Atlantic in winter. The decadal variation of SCSSMI is modulated by PDO. Interdecadal variation of SCSSMI is relevant to the global warming and PDO.  相似文献   

台风"云娜"的热动力结构模拟试验研究     

程锐  叶成志  许爱华  尹珊建 《湖北气象》2007,26(2):103-108

对2004年8月登陆我国的台风"云娜"的热动力结构及其演变进行了数值模拟。试验从大尺度环境场、台风中尺度动力和热力场三维结构、台风云雨特征等多角度,对模拟结果与实际观测进行了对比。结果表明,模式不仅较准确地再现了台风登陆前24h移动和演变的全过程,在移向、移速和登陆时间、地点上与实况十分接近,而且对台风系统中尺度结构、云雨特征的模拟与分析场及卫星观测也有较好的一致性。采用的模拟工具是新开发的双重嵌套AREM模式,该模式是静力模式,但对台风仍有较强的模拟能力。此外,本试验无任何人为台风模型的嵌入是其中的一个特点,从而增加了试验的可信度。  相似文献   

Modeling of gold mass transfer during the listwanitization and rodingitization using the example of the Ust’-Dep ophiolite complex in the upper Amur territory     

L. P. Plyusnina  G. G. Likhoidov  V. P. Molchanov  Zh. A. Shcheka 《Russian Journal of Pacific Geology》2007,1(5):464-472

Gold mass transfer with chloride and carbonate-chloride solutions was examined at the 300 and 400°C isotherms and P _tot = 1 kbar by means of experimental modeling and theoretical simulations. CO₂ was confirmed to suppress Au solubility in fluids. The low Au solubility (mAu < 10^?8) determined in the experiments explains the mechanism of its precipitation when serpentinites and listwanites interact with acidic mineralized solutions. Listwanitization, which was genetically related with the emplacement of orogenic granitoids, was determined to have overprinted serpentinites and rodingites and strongly affected Au transport in the oregeochemical system. The characteristics of the metasomatic processes in the Ust’-Dep ophiolites and the gold concentration in the rocks produced by these processes confirm this conclusion.  相似文献   

An enlarged and updated internally consistent thermodynamic dataset with uncertainties and correlations: the system K2O–Na2O–CaO–MgO–MnO–FeO–Fe2O3–Al2O3–TiO2–SiO2–C–H2–O2     

T. J. B. HOLLAND  R. POWELL 《Journal of Metamorphic Geology》1990,8(1):89-124

We present, as a progress report, a revised and much enlarged version of the thermodynamic dataset given earlier (Holland & Powell, 1985). This new set includes data for 123 mineral and fluid end-members made consistent with over 200 P–T–X_CO2–f_O2 phase equilibrium experiments. Several improvements and advances have been made, in addition to the increased coverage of mineral phases: the data are now presented in three groups ranked according to reliability; a large number of iron-bearing phases has been included through experimental and, in some cases, natural Fe:Mg partitioning data; H₂O and CO₂ contents of cordierites are accounted for with the solution model of Kurepin (1985); simple Landau theory is used to model lambda anomalies in heat capacity and the Al/Si order–disorder behaviour in some silicates, and Tschermak-substituted end-members have been derived for iron and magnesium end-members of chlorite, talc, muscovite, biotite, pyroxene and amphibole. For the subset of data which overlap those of Berman (1988), it is encouraging to find both (1) very substantial agreement between the two sets of thermodynamic data and (2) that the two sets reproduce the phase equilibrium experimental brackets to a very similar degree of accuracy. The main differences in the two datasets involve size (123 as compared to 67 end-members), the methods used in data reduction (least squares as compared to linear programming), and the provision for estimation of uncertainties with this dataset. For calculations on mineral assemblages in rocks, we aim to maximize the information available from the dataset, by combining the equilibria from all the reactions which can be written between the end-members in the minerals. For phase diagram calculations, we calculate the compositions of complex solid solutions (together with P and T) involved in invariant, univariant and divariant assemblages. Moreover we strongly believe in attempting to assess the probable uncertainties in calculated equilibria and hence provide a framework for performing simple error propagation in all calculations in thermocalc, the computer program we offer for an effective use of the dataset and the calculation methods we advocate.  相似文献   

迭代法计算H2O-CO2-NaCl包裹体均一压力的改进及其应用   总被引：1，自引：0，他引：1  

席斌斌  施伟军  张德会  徐文刚  蒋宏  王成 《矿床地质》2010,29(6):1138-1144

文章在宋玉财等于2007年提出的利用迭代法计算流体包裹体成分及均一压力的基础上,结合Duan等通过热力学模拟研究所获得的最新的热力学方程及H2O-CO2-NaCl包裹体pVtx计算程序,对宋玉财等所提出的H2O-CO2-NaCl包裹体成分及均一压力的迭代计算法提出了改进意见,同时对其进行了适当的修改。文章利用中-低温条件下求解CO2在盐水中的溶解度及摩尔体积的方程,提高了原方法的计算精度,并将原方法的适用范围（均一温度≥300 ℃）扩展到中_低温（0～260 ℃）、中_低压力（0～1 000×105Pa）以及中等盐度的范围。本方法适用于求解CO2部分均一温度高于笼形物融化温度、不含石盐子矿物且完全均一到水溶液相的H2O-CO2-NaCl包裹体。  相似文献