矽线石研究及应用综述   总被引：1，自引：0，他引：1  

叶先贤  刘平 《地质科技情报》1998,17(1):26-32

对矽线石的成分,有主邓－无序,结构,热力学行为及应用研究进展作了综述。通过对矽线石的研究,能够为矽线石的合理利用提供理论基础,强调应堤洄强对矽线碱珠杂质成分,结构及其变化的研究。  相似文献   

Subsolidus Phase Relations in the System MgO-SiO_2-Cr-O and Thermodynamic Properties of Related Cr~(2+)-Containing End-members     

H.St.CO'' Neill  F.Seifert 《《地质学报》英文版》1996,70(4):420-434

Subsolidus phase relations have been determined in the systems SiO2-Cr-O and MgO-SiO2-Cr-O in equilibrium with metallic Cr, at 1100 to 1500℃ and 0 to 2.88 GPa. The results show that there are no ternary phases in the SiO2-Cr-O system at these conditions, i.e., only the assemblage eskolaite-Cr-metal-quartz (or tridymite) is found. In the MgO-containing system, however, extensive substitution of Cr2+ for Mg is observed in (Mg, Cr2+)2SiO4 olivine, (Mg, Cr2+)2Si2O6 pyroxene, and (Mg, Cr2+)Cr2O4 spinel. Cr3+ levels in olivine and pyroxene are below detection limits. The pyroxene is orthohombic at XCrPx2+ < 0.2, monoclinic at higher XCrPx2+ . Thestructure of the spinels becomes tetragonally distorted at XCr2+Sp >0.2. The experimental datahave been fitted to a thermodynamic model, and the authors obtained the mixing parameter (W) of Mg-Cr2+ in olivine, pyroxene and spinel, and the relation between temperatures and free energies of formation for the end-members: Cr2+-olivine (Cr2SiO4), Cr2+-pyroxene (Cr2Si2O6)  相似文献   

An internally consistent dataset with uncertainties and correlations: 3. Applications to geobarometry, worked examples and a computer program   总被引：31，自引：4，他引：31  

R. POWELL  T.J.B. HOLLAND 《Journal of Metamorphic Geology》1988,6(2):173-204

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鄂尔多斯盆地东部紫金山岩体SHRIMP测年地质意义   总被引：3，自引：0，他引：3  

杨兴科  晁会霞  郑孟林  姚卫华  杨旭升 《矿物岩石》2008,28(1):54-63

通过对鄂尔多斯盆地东部晋西挠褶带紫金山碱性杂岩体的地质特征、岩石学特征、岩石地球化学、稀土元素地球化学分析及U-Pb同位素SHRIMP测年等研究发现:该碱性杂岩体作为鄂尔多斯盆地东部燕山期岩浆侵入热力作用的代表,具有富碱、较富铁、贫镁,钙,SiO2不饱和或极不饱和,属碱性-过碱性系列.地球化学特征显示富碱、铁、贫镁;稀土元素含量高,无铕异常;岩浆侵入表现出明显的方向和多阶段性,可侵入二叠纪-三叠纪地层中.盆地东部火成岩同位素测年数据表明岩浆-热力作用高峰期在110Ma～150 Ma.测试样品中有21组锆石样品年龄介于125 Ma～132 Ma之间,说明主期岩浆活动热力事件时代为早白垩世,是盆地形成演化的中晚期发生构造转换(深部的隆升)相对应,与华北地区较普遍的早白垩世构造热事件一致.早白垩世强烈的构造热力变动导致该盆地东翼大面积的抬升隆起、吕粱软流圈上涌和晋西挠褶带的形成.SHRIMP测年还发现,除主期125 Ma～132 Ma岩浆热力事件外,有捕获的早期岩浆锆石反映的热力活动事件,构造演化分析显示多阶段热力作用特点.  相似文献   

A Numerical Investigation of the Eyewall Evolution of a Tropical Cyclone          下载免费PDF全文

LI Qingqing  DUAN Yihong  FU Gang  YU Hui 《Acta Meteorologica Sinica》2009,23(5):517-538

In this study, a high-resolution numerical simulation is conducted to investigate the eyewall evolution of Typhoon Imbudo (2003). The eyewall contraction, breakdown, and reformation are successfully simulated by the model. The eyewall accordantly shrinks throughout the whole troposphere prior to landfall, while it exhibits di erent variations after landfall in the lower and upper troposphere, respectively. It is found that the dry air advected into the storm inner core through a low-θe channel, the reduced surface latent heat transfer, and the increased in ows in the coastal region are associated with the eyewall contraction.Accompanied with the high-to-low wavenumber change in the vortex Rossby waves, the initial polygonal eyewall transforms to an elliptical one. Such a wavenumber change is likely associated with the change of interaction between the rainbands and the eyewall. The corresponding features of the time-averaged and vertical dynamic and thermodynamic structures are also examined during the storm passage. A tangential wind budget analysis indicates that a strong acceleration due to the contributions of both the eddy and the mean circulation is located in the lower layer in the eyewall during pre-landfall, and the mean circulation contribution to the change in the tendency of the azimuthally averaged tangential wind counteracts the eddy contribution.  相似文献   

Antimony in hydrothermal processes: solubility, conditions of transfer, and metal-bearing capacity of solutions     

A.A. Obolensky  L.V. Gushchina  A.S. Borisenko  A.A. Borovikov  G.G. Pavlova 《Russian Geology and Geophysics》2007,48(12):992-1001

Based on data on the composition of ore-bearing hydrothermal solutions and parameters of ore-forming processes at various antimony and antimony-bearing deposits, which were obtained in studies of fluid inclusions in ore minerals, we investigated the behavior of Sb(III) in the system Sb–Cl–H₂S–H₂O describing the formation of these deposits.

We also performed thermodynamic modeling of native-antimony and stibnite dissolution in sulfide (m_HS⁻ = 0.0001−0.1) and chloride (m_Cl⁻ = 0.1−5) solutions and the joint dissolution of Sb_(s)⁰ and Sb₂S_3(s) in sulfide-chloride solution (m_HS⁻ = 0.01; m_Cl⁻ = 1) depending on Eh, pH, and temperature. All thermodynamic calculations were carried out using the Chiller computer program. Under the above conditions, stibnite precipitates in acid, weakly acid to neutral, and medium redox solutions, whereas native antimony precipitates before stibnite under more reducing conditions in neutral to alkaline solutions.

The metal-bearing capacity of hydrothermal solutions (200–250 °C) of different compositions and origins has been predicted. We have established that the highest capacity is specific for acid (pH = 2–3) high-chloride solutions poor in sulfide sulfur and alkaline (pH = 7–8) low-chloride low-sulfide solutions.  相似文献   

一个热动力海冰模式的改进与实验   总被引：2，自引：0，他引：2  

宋洁  孙照渤 《南京气象学院学报》2005,28(4):433-441

影响海冰变化的物理因素中热力和动力部分是同等重要的，但多数热动力海冰模式的热力部分考虑得较为简单。针对Hibler热动力海冰模式的不足，以1个3层热力模式为基础改进了其热力部分。比较了原模式中的零层热力模式和用于改进的3层热力模式；并应用改进前后的两种热动力模式对1983年的北极海冰进行了模拟。模拟结果表明，海冰厚度比原模式厚，季节变化减弱，海冰密集度与观测资料更为符合。  相似文献   

Matrix‐dependent garnet growth in polymetamorphic rocks of the Sesia zone,Italian Alps     

M. Robyr  B. Darbellay  L.P. Baumgartner 《Journal of Metamorphic Geology》2014,32(1):3-24

Mushroom‐ and atoll‐shaped garnet crystals were found in high‐pressure quartz‐rich pelitic layers from the Monte Mucrone area (Western Alps, Italy). These garnet crystals are characterized by a peninsula‐shaped core surrounded by a partially crystallized, dodecahedral external rim. Textural observations and thermodynamic modelling point towards growth of the atoll garnet from the Monte Mucrone area during two distinct orogenic cycles. The core region and the inner part of the ring forming the edge of the atoll grew under Barrovian metamorphic conditions of likely Hercynian age, while the outer rim of the atoll structure developed under Alpine high‐pressure conditions. Electron backscatter diffraction analyses indicate that the atoll‐shaped structure has one single crystallographic orientation, despite its complex compositional zoning. Thermodynamic modelling reveals marked changes in equilibrium assemblage leading to changes in stoichiometry of the garnet‐forming reaction, which in turn explain the characteristic garnet morphology. Small amounts of quartz are consumed during the earlier stage of garnet growth history, whereas the production of garnet requires a much larger amount of quartz during the final stage of its growth. This leads to a change from initial poikiloblastic to non‐poikiloblastic textures. This change is responsible for the formation of atoll‐shaped garnet. Finally, garnet in intercalated mica‐rich layers forms idiomorphic crystals, continuous from the centre to rim. This study highlights the importance of the difference between the local matrix composition and the aggregate composition of the reactants needed for the garnet‐forming reaction. Finally, we show that interaction between matrix and reaction stoichiometry can lead to porphyroblast precipitation inside the already grown porphyroblast.  相似文献   

Early Carboniferous blueschist facies metamorphism in metapelites of the West Sudetes (Northern Saxothuringian Domain,Bohemian Massif)     

E. ŽÁČKOVÁ  J. KONOPÁSEK  P. JEŘÁBEK  F. FINGER  J. KOŠLER 《Journal of Metamorphic Geology》2010,28(4):361-379

The metamorphic evolution of micaschists in the north‐eastern part of the Saxothuringian Domain in the Central European Variscides is characterized by the early high‐pressure M1 assemblage with chloritoid in cores of large garnet porphyroblasts and a Grt–Chl–Phe–Qtz ± Pg M2 assemblage in the matrix. Minerals of the M1–M2 stage were overprinted by the low‐pressure M3 assemblage Ab–Chl–Ms–Qtz ± Ep. Samples with the best‐preserved M1–M2 mineralogy mostly appear in domains dominated by the earlier D1 deformation phase and are only weakly affected by subsequent D2 overprint. Thermodynamic modelling suggests that mineral assemblages record peak‐pressure conditions of ≥18–19 kbar at 460–520 °C (M1) followed by isothermal decompression 10.5–13.5 kbar (M2) and final decompression to <8.5 kbar and <480 °C (M3). The calculated peak P–T conditions indicate a high‐pressure/low‐temperature apparent thermal gradient of ～7–7.5 °C km^?1. Laser ablation inductively coupled plasma mass spectrometry isotopic dating and electron microprobe chemical dating of monazite from the M1–M2 mineral assemblages give ages of 330 ± 10 and 328 ± 6 Ma, respectively, which are interpreted as the timing of a peak pressure to early decompression stage. The observed metamorphic record and timing of metamorphism in the studied metapelites show striking similarities with the evolution of the central and south‐western parts of the Saxothuringian Domain and suggest a common tectonic evolution along the entire eastern flank of the Saxothuringian Domain during the Devonian–Carboniferous periods.  相似文献   

Modelling grain‐recycling zoning during metamorphism     

M. A. PEARCE  J. WHEELER 《Journal of Metamorphic Geology》2010,28(4):423-437

Chemical zoning, recorded by grain growth during metamorphism, is a key source of information about P–T–t paths. Interpretation of these data must be carried out using appropriate models and recognizing their inherent assumptions. To assist with defining how zoned minerals form, a set of geometric criteria for three types of chemical zoning developed in minerals (diffusion, growth and grain recycling) is outlined. Re‐equilibration of minerals by lattice diffusion causes zoning if the re‐equilibration is incomplete. Growth of porphyroblasts is commonly considered in pelites, but in metagranitoids, large monophase domains undergo coarsening by recycling of material from one grain to another as grain boundaries migrate driven by surface energy. This type of grain size increase is termed here ‘grain recycling’. Zoning developed during grain recycling due to equilibration of the recycled material with grain‐boundary chemistry is termed ‘grain‐recycling zoning’. Furthermore, short lattice diffusion lengths relative to grain sizes cause metamorphic fractionation because material in the grain cores is not in communication thermodynamically with the rest of the rock. A new model is derived for this sort of grain size increase coupled with metamorphic reactions using Theriak–Domino. An example is given of plagioclase undergoing an increase in anorthite content as epidote breaks down during amphibolite facies metamorphism of a metagranitoid. Agreement between naturally occurring zoning profiles and those derived from modelled P–T–t paths shows that this model can be used to extract metamorphic conditions from rocks which are not accessible using conventional thermobarometry.  相似文献