Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field   总被引：2，自引：2，他引：2  

LAI Xingyun  YU Bingsong  CHEN Junyuan  CHEN Xiaolin  LIU Jianqing  MEI Mingxiang  JING Weiguang & CHENG Suhua School of Earth Sciences  Mineral Resources  China University of Geosciences  Beijing  China  Key Laboratory of Lithospheric Tectonics  Deep-level Process  Exploration of Ministry of Education  Beijing  China 《中国科学D辑(英文版)》2005,48(1):21-31

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,  相似文献   

Dynamics of Saxothuringian subduction channel/wedge constrained by phase‐equilibria modelling and micro‐fabric analysis          下载免费PDF全文

S. Collett  P. Štípská  V. Kusbach  K. Schulmann  G. Marciniak 《Journal of Metamorphic Geology》2017,35(3):253-280

Subduction and exhumation dynamics can be investigated through analysis of metamorphic and deformational evolution of associated high‐grade rocks. The Erzgebirge anticline, which forms at the boundary between the Saxothuringian and Teplá‐Barrandian domains of the Bohemian Massif, provides a useful study area for these processes owing to the occurrence of numerous meta‐basites preserving eclogite facies assemblages, and coesite and diamond bearing quartzofeldspathic lithologies indicating subduction to deep mantle depths. The prograde and retrograde evolution of meta‐basite from the Czech portion of the Erzgebirge anticline has been constrained through a combination of thermodynamic modelling and conventional thermobarometry. Garnet growth zoning indicates that the rocks underwent burial and heating to peak conditions of 2.6 GPa and at least 615 °C. Initial exhumation occurred with concurrent cooling and decompression resulting in the growth of amphibole and zoisite poikiloblasts overgrowing and including the eclogite facies assemblage. The development of clinopyroxene–plagioclase–amphibole symplectites after omphacite and Al‐rich rims on matrix amphibole indicate later heating at the base of the lower crust. Omphacite microstructures, in particular grain size analysis and lattice‐preferred orientations, indicate that the prograde evolution was characterized by a constrictional strain geometry transitioning into plane strain and oblate fabrics during exhumation. The initial constrictional strain pattern is interpreted as being controlled by competing slab pull and crustal buoyancy forces leading to necking of the subducting slab. The transition to plane strain and flattening geometries represents transfer of material from the subducting lithosphere into a subduction channel, break‐off of the dense slab and rebound of the buoyant crustal material.  相似文献   

夏季热带北大西洋海温异常对西北太平洋热带气旋生成的影响          下载免费PDF全文

霍利微  郭品文  张福颖 《大气科学学报》2016,39(1):55-63

利用1979—2012年西北太平洋热带气旋最佳路径资料,Hadley中心的海温资料和NCEP/NCAR再分析资料等,研究了夏季(6—10月)热带北大西洋海温异常与西北太平洋热带气旋(Tropical Cyclone,TC)生成的关系及其可能机制。结果表明,夏季热带北大西洋海温异常与同期西北太平洋TC生成频次之间存在显著的负相关关系。热带北大西洋海温的异常增暖可产生一对东—西向分布的偶极型低层异常环流,其中气旋性异常环流位于北大西洋/东太平洋地区,反气旋异常环流位于西北太平洋地区。该反气旋环流异常使得TC主要生成区的对流活动受到抑制、低层涡度正异常、中低层相对湿度负异常、中层下沉气流异常,这些动力/热力条件均不利于TC生成。此外,西北太平洋地区低层涡旋动能负异常,同时来自大尺度环流的涡旋动能的正压转换也受到抑制,不能为TC的生成和发展提供额外能量源。反之亦然。  相似文献   

ASO-S卫星工程科学应用系统的数据库设计          下载免费PDF全文

葛蕴翊  黎辉  黄宇  李敬伟  雷仕俊  藏京京  苏杨  封莉  李友平  李瑛  徐遵磊  李翔 《天文学报》2020,61(4):46

先进天基太阳天文台(Advanced Space-based Solar Observatory, ASO-S)卫星是我国首颗太阳观测卫星, 主要观测太阳耀斑和日冕物质抛射以及产生它们的磁场结构. ASO-S卫星的科学应用系统是科学卫星工程的6大系统之一, 它连接科学用户和卫星数据, 为将卫星的科学数据转化为科学成果提供保障. 科学应用系统的数据库是连接软件与海量数据的枢纽, 为科学数据生产和用户服务及运行提供数据层的支撑. 介绍了科学应用系统的数据库架构设计、数据库的选择以及数据库性能优化和表样例. 这里的数据库包括观测计划、工程参数、运维日志、科学数据、定标数据和特征事件识别等数据库. 这些数据库的建设将为ASO-S卫星工程科学应用系统的顺利运行提供数据支撑, 也可以为未来其他科学卫星类似数据库的搭建提供参考和借鉴.  相似文献   

Database of molecular masers and variable stars     

Andrej M.Sobolev  Dmitry A.Ladeyschikov  Jun-ichi Nakashima 《天文和天体物理学研究(英文版)》2019,(3):13-20

We present the database of maser sources in H2 O, OH and Si O lines that can be used to identify and study variable stars at evolved stages. Detecting the maser emission in H2 O, OH and Si O molecules toward infrared-excess objects is one of the methods for identifing long-period variables(LPVs, including miras and semiregulars), because these stars exhibit maser activity in their circumstellar shells. Our sample contains 1803 known LPV objects. Forty-six percent of these stars(832 objects) manifest maser emission in the line of at least one molecule: H2 O, OH or Si O. We use the database of circumstellar masers in order to search for LPVs which are not included in the General Catalogue of Variable Stars(GCVS). Our database contains 4806 objects(3866 objects without associations in GCVS) with maser detection in at least one molecule. Therefore it is possible to use the database in order to locate and study the large sample of LPV stars. The database can be accessed at http://maserdb.net.  相似文献   

热带风暴热力非对称结构对其运动的影响     

赵凯  沈树勤  王卫芳  王清楼 《海洋科学》2008,32(2):36-41

研究了热力非对称结构对0421号热带风暴"海马(Haima)"的移动和强度变化的影响。通过物理量场诊断分析发现,热带风暴(气旋)的热力结构在垂直、水平方向均呈非对称分布。热力因子对热带风暴的影响,主要体现在低层。热带风暴朝其移向前方的风暴内部的非绝热增温中心偏折,并有向此方向加速的趋势。了解热带风暴的热力结构分布特征及其对热带风暴移动的影响,对短期预报热带风暴的移动有一定的指示意义。  相似文献   

台风"云娜"的热动力结构模拟试验研究     

程锐  叶成志  许爱华  尹珊建 《湖北气象》2007,26(2):103-108

对2004年8月登陆我国的台风"云娜"的热动力结构及其演变进行了数值模拟。试验从大尺度环境场、台风中尺度动力和热力场三维结构、台风云雨特征等多角度,对模拟结果与实际观测进行了对比。结果表明,模式不仅较准确地再现了台风登陆前24h移动和演变的全过程,在移向、移速和登陆时间、地点上与实况十分接近,而且对台风系统中尺度结构、云雨特征的模拟与分析场及卫星观测也有较好的一致性。采用的模拟工具是新开发的双重嵌套AREM模式,该模式是静力模式,但对台风仍有较强的模拟能力。此外,本试验无任何人为台风模型的嵌入是其中的一个特点,从而增加了试验的可信度。  相似文献   

相变前的热力学平衡态对铁电液晶排列的影响     

唐先柱  彭增辉  刘永刚  鲁兴海  宣丽 《海洋学报》2010,32(9):6261-6265

本实验选用ZLI-3654型铁电液晶(FLC)以及SE-3140型取向剂制备FLC器件样品,通过改变FLC相变过程中的降温速率以及相变前的热力学平衡态来研究FLC相变前的热力学平衡态对FLC排列的影响,共进行了十组实验.实验后,将FLC器件静态对比度进行比较,得出手性向列相到近晶A相(N^*-SmA)相变前的热力学平衡态对FLC实现均匀排列起着极其重要的作用的结论.实验结果表明:器件的静态对比度可高达620 ∶1, N^*-SmA相变前的热力学平衡态有利于形成高对比  相似文献   

Cu₃ N弹性和热力学性质的第一性原理研究     

李世娜  刘永 《海洋学报》2010,32(10):6882-6888

利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO₃结构Cu₃N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu₃N的弹性常数,Poisson比等,并分析出Cu₃N在零温零压下是稳定的. 通过准谐Debye模型计算Cu₃N的热力学性质,得到了Cu₃N的晶格常数、等压比热容、等容比热  相似文献   

Petrogenetic modelling of strongly residual metapelitic xenoliths within the southern Platreef,Bushveld Complex,South Africa     

T. E. JOHNSON  M. BROWN  R. W. WHITE 《Journal of Metamorphic Geology》2010,28(3):269-291

Xenoliths of quartz‐absent Fe‐rich aluminous metapelite are common within the platinum group element‐rich mafic/ultramafic magmatic rocks of the Platreef. Relative to well‐characterized protoliths, the xenoliths are strongly depleted in K₂O and H₂O, and have lost a substantial amount of melt (>50 vol.%). Mineral equilibria calculations in the NCKFMASHTO system yield results that are consistent with observations in natural samples. Lower‐grade rocks that lack staurolite constrain peak pressures to ～2.5 kbar in the southern Platreef. Smaller xenoliths and the margins of larger xenoliths comprise micro‐diatexite rich in coarse acicular corundum and spinel, which record evidence for the metastable persistence of lower‐grade hydrous phases and rapid melting consequent on a temperature overstep of several hundred degrees following their incorporation in the mafic/ultramafic magmas. In the cores of larger xenoliths, temperatures increased more slowly enabling progressive metamorphism by continuous prograde equilibration and the loss of H₂O by subsolidus dehydration; the H₂O migrated to xenolith margins where it may have promoted increased melting. According to variations in the original compositional layering, layers became aluminosilicate‐ and/or cordierite‐rich, commonly with spinel but only rarely with corundum. The differing mineralogical and microstructural evolution of the xenoliths depends on heating rates (governed by their size and, therefore, proximity to the Platreef magmas) and the pre‐intrusive metamorphic grade of the protoliths. The presence or absence of certain phases, particularly corundum, is strongly influenced by the degree of metastable retention of lower‐grade hydrates in otherwise identical protolith bulk compositions. The preservation of fine‐scale compositional layering that is inferred to be relict bedding in xenolith cores implies that melt loss by compaction was extremely efficient.  相似文献