常温和压力0.1～1300 MPa下硬石膏的拉曼光谱研究   总被引：1，自引：0，他引：1  

杨玉萍  郑海飞 《矿物学报》2005,25(3):299-302

利用立方氧化锆压腔装置测量了高压下硬石膏中硫酸根离子内部S-O键的四个振动（对称伸缩振动、弯曲振动、反对称伸缩振动和变形弯曲振动）的拉曼位移,研究结果表明：在25℃和0．1～1300MPa压力范围内硬石膏未发生相变,所观察到的硬石膏各个拉曼峰的位移值随压力的增加而线性增加,它们与压力之间的关系可分别表达为：υ1018=0．0053p＋1016.8,υ417=0．0013p＋416．82,υ498=0．0044P＋499．25,υ1129=0．0052p＋1128．5,υ1160=0．0067p＋1159．5,υ608=0．0028p＋608．76,υ627=0．0036p＋627．01,υ675=0．0039p＋675．32,且伸缩振动受压力的影响比弯曲振动大。其1018cm^-1峰强度大,是石英464cm^-1峰的6倍,因此硬石膏也是宝石压腔良好的压力标定物质。  相似文献   

高温高压下辉石岩的电导率实验研究   总被引：3，自引：0，他引：3  

代立东  李和平  刘丛强  单双明  崔桐娣  邓鹤鸣  许祖鸣 《矿物学报》2005,25(3):303-306

使用YJ-3000t紧装式六面顶高压设备和1260阻抗／增益-相位分析仪,在1．0～4．0GPa和773～1134K下用阻抗谱法就位测定了辉石岩的电导率。实验结果表明,电导率对频率具有很强的依赖性;温度是决定辉石岩电导率的一个重要物理参数,电导率随着温度升高而增大,lgσ与I／T之间符合Arrenhius关系式;随着压力升高。电导率降低,活化焓和独立于温度的指前因子亦降低。  相似文献   

An experimental study on microscopic characteristics of gas-bearing sediments under different gas reservoir pressures     

Zhenqi Guo  Tao Liu  Lei Guo  Xiuting Su  Yan Zhang  Sanpeng Li 《海洋学报(英文版)》2021,40(10):144-151

Gas-bearing sediments are widely distributed in five continents all over the world. Most of the gases exist in the soil skeleton in the form of discrete large bubbles. The existence of gas-phase may increase or decrease the strength of the soil skeleton. So far, bubbles’ structural morphology and evolution characteristics in soil skeleton lack research, and the influence of different gas reservoir pressures on bubbles are still unclear. The micro characteristics of bubbles in the same sediment sample were studied using an industrial CT scanning test system to solve these problems. Using the image processing software, the micro variation characteristics of gas-bearing sediments in gas reservoir pressure change are obtained. The results show that the number and volume of bubbles in different equivalent radius ranges will change regularly under different gas reservoir pressure. With the increase of gas reservoir pressure, the number and volume of tiny bubbles decrease. In contrast, the number and volume of large bubbles increase, and the gas content in different positions increases and occupies a dominant position, driving the reduction of pore water and soil skeleton movement.  相似文献   

臭氧卫星遥感六十年进展     

赵少华  杨晓钰  李正强  王中挺  张玉环  王玉  周春艳  马鹏飞 《遥感学报》2022,26(5):817-833

臭氧已成为中国继PM_2.5之后多地的首要污染物,臭氧污染防治是中国“十四五”及未来大气污染防治的重点。本文回顾了近60年来国内外臭氧卫星观测方面的主要进展,包括卫星探测载荷和臭氧相关的反演应用技术等,分为3个阶段总结了卫星载荷天底、临边和掩星3种探测方式的发展历程。臭氧卫星遥感反演算法和监测应用也随着载荷的发展在不断更新,本文重点介绍了臭氧柱总量和垂直廓线卫星遥感反演算法、近地面臭氧及其前体物观测、平流层臭氧入侵观测和区域传输、臭氧卫星观测数据的精度验证等方面的重要进展。对比国际臭氧卫星遥感监测,中国臭氧监测卫星发展滞后,虽然国家民用空间基础设施规划中陆续发射的高光谱观测卫星、大气环境监测卫星具有初步的臭氧监测能力,但在卫星载荷在功能、性能等方面还有不小差距,比如空间分辨率、信噪比等方面。在算法反演和监测应用方面,目前臭氧柱总量反演精度较高,还存在对流层中低层和近地面臭氧浓度反演精度不够,臭氧污染评估及成因分析不足,如近地面臭氧污染迁移转化过程、平流层臭氧侵入识别分析等问题,是下一步要重点关注的方向。  相似文献   

CTD海上剖面测量性能综合评定方法研究          下载免费PDF全文

周凯  杨健  张挺  赵希勇 《海洋技术学报》2024,(2)

随着国产温盐深剖面仪（Conductivity-Temperature-Depth profiler,CTD） 测量性能的不断提高,其使用范围和规模也逐步扩大,需要规范CTD 海上剖面测量性能评定方法。在威海附近海域开展基于锚泊式平台CTD 海上比对试验,通过改变同架比对CTD 数量、引入相关系数和平均差数据处理方法研究海上比对试验效果,提出以精准度和灵敏度为目标层的CTD 海上剖面测量性能评价指标体系,实现了对被测CTD 海上剖面测量性能相对全面的评价,准确量化了被测CTD 在实际海洋环境中的剖面测量性能,为国产CTD 海上剖面测量性能的优化提供依据。  相似文献   

基于PIES观测东沙群岛附近声传播变化          下载免费PDF全文

郭平  徐永生  黄超  张林  张庆君  张利强  彭泳卿  张祥光  徐立军  王黎明  袁延茂  马树青  杨亮  尹善明 《应用海洋学学报》2024,43(2):333-341

本研究旨在将PIES观测数据应用于海洋水声环境的监测。利用一次南海PIES观测数据,反演得到温盐剖面,进而计算声场信息。结合观测期间的暖涡及台风事件对反演及计算结果进行了分析验证。结果表明,PIES能够在长期连续观测中较为敏感地捕获上层水体及表面声道的变化特征,为水声通信、探测及潜航路径规划等提供参考,在水声研究及海洋军事环境保障中都具有良好的应用前景。  相似文献   

多路气压检定系统的设计与实现          下载免费PDF全文

陆扬  李迪  朱君 《中低纬山地气象》2020,44(1)

该文针对气象用的PTB220、PTB330气压传感器检定效率低,检定中存在人工误差等现状,研发了多路气压检定系统。系统采用具有8个RS-232/422/485的三合一串口的MOXA-Nport5650-8-DTL型号串口服务器,实现了8个气压传感器的同步检定和数据处理,提高了气压检定的工作效率,排除人工检定带来的误差。  相似文献   

Coupled thermo-hydro-mechanical modelling of bentonite buffer material     

T. Kanno  T. Fujita  S. Takeuchi  H. Ishikawa  K. Hara  M. Nakano 《国际地质力学数值与分析法杂志》1999,23(12):1281-1307

Mechanistic model development and numerical analyses were carried out on coupled thermo-hydraulic-mechanical processes in bentonite-based buffer material for the geological disposal of high-level radioactive waste with small-scale laboratory experiments and a full-scale test. The mechanism of water movement in compacted bentonite was identified by applying theoretical equations to the experimental results. The application clearly explained the observed results of the temperature dependence of the hydraulic conductivity in the saturated state and the water diffusivity in the unsaturated state for the compacted bentonite and the dry density dependence of the diffusivity. The full-scale coupled test, BIG-BEN, was conducted at PNC (Power Reactor and Nuclear Fuel Development Corporation) Tokai Works. The results of the numerical analyses for the full-scale test which are based on the present knowledge of coupled processes and our small-scale experiments were in good agreement with the measured results except for mechanical phenomena. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Segmentation of soil roughness profiles     

Lorenzo Borselli 《地球表面变化过程与地形》1999,24(1):71-90

A robust and flexible algorithm to study spatial series like soil roughness profile has been introduced. It avoids using classic spectral analysis, considers the profile first and foremost as non-stationary and makes it possible to identify the separate domains inside the profile where chosen statistical parameters and roughness indexes have their own value. The method analyses a roughness profile considering it as an assemblage of several entities that may differ in terms of statistical properties and length, without establishing constraints as to number and extension. The method derives the variability of statistical and roughness properties along the profile and extracts the possible components - random and oriented - detectable inside the sample. Some examples of application illustrate the possibility offered by the method to study real roughness profiles recorded in the field by a portable laser microprofilometer. The procedure proposed allows the investigation of local roughness properties with varying degrees of accuracy and should be useful to monitor the differential evolution of roughness on patterned soil surface, increasing the overall information content. A general definition of ‘ordered roughness’ is introduced. The definition proposed seems more suited to current techniques for the numerical treatment of digital profiles and for the existing physical relationships between the scale of observation of roughness and the scale of the process investigated (hydraulic resistance, water storage in depressions). Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

A tangential wind profile for simulating strong tropical cyclones with MM5   总被引：5，自引：0，他引：5  

GAOShanhong YANGBo WUZengmao 《中国海洋大学学报(英文版)》2005,4(1):21-28

A new tangential wind profile for simulating strong tropical cyclones is put forward and planted into the NCARAFWA tropical cyclone bogussing scheme in MM5. The scheme for the new profile can make full use of the information from routine typhoon reports, including not only the maximum wind, but also the additional information of the wind speeds of 25.7 and 15.4 ms^-1 and their corresponding radii, which are usually provided for strong cyclones. Thus, the new profile can be used to describe the outer structure of cyclones more accurately than by using the earlier scheme of MM5 in which only the maximum wind speed is considered. Numerical experimental forecasts of two strong tropical cyclones are performed to examine the new profile. Results show that by using the new profile the prediction of both cyclones‘ intensity can be obviously improved, but the effects on the track prediction of the two cyclones are different. It seems that the new profile might be more suitable for strong cyclones with shifted tracks. However, the conclusion is drawn from only two typhoon cases, so more cases are needed to evaluate the new profile.  相似文献