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121.
Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature 总被引:1,自引:0,他引:1
Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history. 相似文献
122.
An algorithm (differential mode) is presented for the improvement of harmonic tidal analysis along T/P tracks, in which the differences between the observed sea surface heights at adjacent points are taken as observations. Also, the observation equations are constrained with the results of the crossover analysis; the parameter estimations are performed at 0.1° latitude intervals by the least squares. Cycle 10 to 330 T/P altimeter data covering the China Sea and the Northwest Pacific Ocean (2°-50° N,105°-150° E) are adopted for a refined along-track harmonic tidal analysis, and harmonic constants of 12 constituents in 8 474 points are obtained, which indicates that the algorithm can efficiently remove non-tidal effects in the altimeter observations, and improve the precision of tide parameters. Moreover, parameters along altimetry tracks represent a smoother distribution than those obtained by traditional algorithms. The root mean squares of the fitting errors between the tidal height model and the observations reduce from 11 cm to 1.3 cm. 相似文献
123.
碎屑岩与火山岩混积岩系层序地层学研究初探——以准噶尔盆地西北缘佳木河组为例 总被引:1,自引:0,他引:1
准噶尔盆地西北缘前陆冲断带是剖析西准噶尔地区盆山耦合关系、沉积体系发育的关键地段。该区二叠系佳木河组为火山岩、火山碎屑岩、碎屑岩组成的混积地层。火山岩与碎屑岩组成的地层单元有广义上的成因联系,因为它们都属于史密斯地层,并均具有旋回特征。针对不同的岩性区:碎屑岩岩性区、火山岩与碎屑岩共存区、纯火山岩区,找出由于构造火山活动、相对湖平面变化等因素形成的可作为层序界面的不整合面。碎屑岩岩性区不整合面在地震剖面上主要表现为削蚀、底超、双向下超、顶超、下切谷等;共存区为同时发育火山岩与碎屑岩的削蚀带,不整合面类型较复杂;纯火山岩区表现为相对湖平面下降形成的削蚀不整合面。故可以通过地震、钻测井资料识别各类不整合面,并依据火山喷发方式、火山旋回、沉积旋回,按照不同对比原则进行经典层序地层学划分。 相似文献
124.
新疆北部石炭纪地层、岩相古地理与烃源岩 总被引:8,自引:1,他引:7
依据近几年新疆区域地质调查结果,结合新疆油田与吐哈油田最新勘探成果,通过区域构造背景和沉积充填演化特征推断石炭系沉积建造样式,理顺了新疆北疆地区石炭纪地层层序,目的是推断石炭纪烃源岩发育层段与主力生烃区范围。下石炭统有效烃源岩分布较广,主要发育于北疆西准噶尔达尔布特山前、博格达山前、准噶尔东部陆东—五彩湾地区早石炭世被动陆缘海相和海陆过渡相沉积盆地;上石炭统有效烃源岩分布相对局限,主要发育于东准噶尔克拉美丽山前石钱滩区、布尔津—吉木乃区及库普—三塘湖区海陆过渡相沉积盆地内。石炭系油气成藏严格遵循"源控论",有效生烃区决定其有效成藏范围,所伴随发育的火山岩体决定其富集程度。优选西准噶尔、东准噶尔、库普—三塘湖区、博格达山前区、布尔津—吉木乃区石炭系烃源岩发育区及其相邻构造带,作为今后石炭系油气勘探战略选区的重要领域和区带。 相似文献
125.
根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。 相似文献
126.
127.
化学地层学因其交叉学科特点和研究对象的复杂性使得研究过程中任何一个环节的不足都将造成测试出现偏差,成果的可信度也将出现问题。高昂的成本也要求研究者把有限的资源集中到正确的目标上。近20年研究历程却恰恰将此类性质的问题陆续暴露了出来。如采样阶段获取原生性状考虑不充分或依据不足、测试阶段缺乏校验、数据分析阶段挖潜和综合利用有待完善以及化学岩、碎屑岩和生物岩各自的基础性和针对性研究有待提高等。有些问题带有相当程度的普遍性,有些甚至是严重的核心技术问题。笔者结合最新相关研究成果对上述问题进行了逐一分析和系统修正。 相似文献
128.
上宫构造蚀变岩型金矿床地质特征及化探找金经验 总被引:1,自引:0,他引:1
上宫金矿位于河南省西部熊耳山北麓,在该区1 020 km2范围内进行了1:5万的地球化学水系沉积物测量,按水系划分取样单元,取样本着"小沟多取,支流放稀,大河不管"的原则进行。本次水系沉积物测量的特点是:取样少,控制面积大,速度快,省钱、省人、省物,找矿效果好、经济效益好。本区水系沉积物测量中所发现的金异常,后经异常检查、地质普查评价及钻探验证,确定为一大型构造蚀变岩型金矿床。 相似文献
129.
Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope (their δ^18O values range from -0.3‰- -0.1‰) and lighter oxygen isotope (their δ^18O values range from -22.1‰- -19.5‰). Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process. 相似文献
130.
川西南周公山及邻区下二叠统的中-低孔、中-低渗碳酸盐岩储层的储集空间以次生成因的溶孔、溶洞和构造裂缝为主.研究认为,多世代方解石胶结、化学充填作用以及埋藏期的压实(溶)作用是孔隙很难得到保存的主要原因;同生-准同生期的混合水云化作用和表生期、埋藏期的流体溶蚀作用则产生了大量的次生溶孔、洞,使储层的孔渗性得到明显的改善;构造破裂作用可以产生新的储集空间,还影响各储集体之间及单一储集体内部空隙的连通.成岩相分为混合水云化-溶蚀-破裂相、溶蚀-胶结相和胶结-压实-压溶相.各种成岩作用的叠加形成了现今下二叠统油气储层的分布格局. 相似文献