土壤聚合物对几种重金属离子固化效果的研究   总被引：2，自引：0，他引：2  

金漫彤  楼敏晓  张琼  王连军 《矿物学报》2008,28(1):66-70

土壤聚合物是一种新型的无机聚合物,其分子链由Si、O、Al等以共价键或离子键连接而成,形成网络结构,对重金属有较强的固定作用.本文试图利用土壤聚合物固化铜、锌、铅三种重金属离子,实现资源化利用.实验以固化体抗压强度和浸出毒性作为性能表征量,结果表明:土壤聚合物对不同重金属的固化有各自的极限浓度,Cu2 、Zn2 、Pb2 的理想固化量分别为0.9%、1%、2%;若固化过程中添加一定量的高炉矿渣,则可以提高固化体的抗压强度.本文通过土壤聚合物固化体SEM分析,从固化体微观结构的形态来阐述土壤聚合物宏观上的优越表现.  相似文献   

冲绳海槽有孔虫壳体的微量元素Sr,Nd同位素地球化学   总被引：6，自引：1，他引：6  

孟宪伟  杜德文  程振波 《海洋学报》2001,23(2):62-68

钙质生物壳的微量元素组合和Sr,Nd同位素组成是识别海底混合源沉积物中生物源物质相对贡献的重要参数.冲绳海槽有孔虫壳体强烈富集Sr,P,Mn和Ba,富集Li,U,Th,Sc,Co,Pb,Zn,Cr,Rb,Y,Sb和轻稀土元素,弱富集V,Ga,Zr,Nb,Cd和中稀土元素,相对贫Ge,Mo,In,Sn,Cs,Hf,Ta,W,Tl,Bi和重稀土元素,海水中微量元素的背景含量和生物活动对微量元素的选择性吸收是有孔虫壳体中微量元素发生富集和贫化的主要机制,冲绳海槽有孔虫壳体的稀土元素配分模式与海水和太平洋有孔虫的有明显差异,表现出中稀土元素相对富集,并具有微弱的负Ce异常.有孔虫壳体的Sr,Nd同位素比值也与大洋海水不同,分别为0.709769和0.512162,前者略高于大洋海水,后者略低于大洋海水,表明冲绳海槽海水明显受大陆河水影响.  相似文献   

近江牡蛎作为重金属污染生物指示种的初步研究   总被引：17，自引：2，他引：17  

陆超华 《台湾海峡》1994,13(1):14-20

对近江牡砺作为监测广东岸海域Ｃｕ，Ｚｎ，Ｃｄ，Ｐｂ污染的生物指示种的可能性进行了初步研究和评价，应用ＰＯＬＹＤＩＶ统计技术对采自广东沿岩海域１４个站点的近江牡盛的重金属含量进行了统计分析，结果表明近江牡蛎受Ｃｕ，Ｚｎ，Ｃｄ污染的地理分布类型与广东沿海排放的工业废水的分布以及潮间带生物和表层沉积物的Ｃｕ，Ｚｎ，Ｃｄ含量分布相一致，因此，近江牡蛎可作为监测研究Ｃｕ，Ｚｎ，Ｃｄ污染的可靠生物指示种，但能  相似文献   

大亚湾沉积物中重金属元素背景值研究     

张银英 《热带海洋学报》1991,(3)

根据大亚湾的自然条件认为,大亚湾沉积物的物质来源是其周围集水区的岩石风化壳,并计算了其风化壳中重金属元素的平均丰度值;又根据沉积物的粒度和深层沉积物重金属元素的含量资料,列方程计算出湾内沉积物中重金属元素的平均含量,根据这两组数据,确定该区域内重金属元素的平均背景值。再通过粒度关系,计算得出大亚湾内各站沉积物中重金属元素的背景值。应用此结果和大亚湾沉积物重金属元素实测结果,计算了由人为影响带入沉积物中的重金属元素含量,了解其受污染的程度。  相似文献   

珠江口沉积物酸挥发性硫化物与重金属生物毒性的研究     

杨永强  陈繁荣  张德荣  张凌  吕莹 《热带海洋学报》2006,25(3):72-78

研究了2003年10月采于珠江口5个站位的沉积物剖面酸挥发性硫化物(AVS)和同时提取的重金属(SEM:Pb,Zn,Cu,Cd,Ni)。其中,站位1、2位于中滩,其沉积物的AVS含量变化范围较小,为0.25—4.06μmol.g-1;站位3、4位于西滩,其沉积物的AVS含量变化范围较大,为0—26.09μmol.g-1。中滩和西滩沉积物的AVS含量均随深度增加。西滩表层沉积物的AVS含量接近于零,这可能与该水域较强的底层流和沉积物的再悬浮作用有关。站位5位于珠江口外侧,其表层沉积物的AVS含量相对较高,且垂向变化较小,可能是还原性沉积物间歇性再悬浮后重新沉积的结果。站位1、2和5沉积物中同时提取的重金属含量大体在0.95±0.2μmol.g-1范围内,随深度增加略呈下降趋势;而西滩沉积物重金属含量相对较高,为1.43—2.42μmol.g-1,且在一定深度范围内随深度增加呈明显下降的趋势,表明珠江口西滩沉积物中的重金属污染有加重的趋势。对AVS/SEM摩尔比值和单个金属的毒性效应研究显示,珠江口内尤其是西滩的表层沉积物存在重金属污染,对其中生活的底栖生物具有潜在的毒性效应。  相似文献   

渤海湾表层沉积物重金属与污染评价   总被引：10，自引：2，他引：10       下载免费PDF全文

秦延文  苏一兵  郑丙辉  张雷  万峻 《海洋科学》2007,31(12):28-33

用原子吸收法测定了渤海湾表层沉积物中重金属的含量,同时用2种评价方法对该海域底质环境进行了评价。结果表明:沉积物中汞、锌含量平均值超过标准,其余项目未发现超标;其分布特征由于受沿岸不同污染源的污染影响,重金属污染物难以形成一定规律的分布状态。同时该海域底质环境质量总指数已达到污染程度和很强的生态危害,其中主要污染元素是Hg,已达重污染,并形成极强的生态危害。  相似文献   

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献   

Trichodesmium erythraeum (Ehrenberg) bloom along the southwest coast of India (Arabian Sea) and its impact on trace metal concentrations in seawater     

Anoop A. Krishnan  P.K. Krishnakumar  M. Rajagopalan 《Estuarine, Coastal and Shelf Science》2007,71(3-4):641-646

The incidence of a large scale Trichodesmium erythraeum bloom along the southwest coast of India (Arabian Sea) observed in May 2005 is reported. Around 4802 filaments of T. erythraeum ml⁻¹ seawater was observed and a colony consisted of 3.6 × 10⁵ cells. The bloom was predominant off Suratkal (12° 59′N and 74° 31′E) with a depth of about 47 m, covering an area of 7 km in length and 2 km width. The concentrations of Zinc, Cadmium, Lead, Copper, Nickel and Cobalt were determined in samples collected from the bloom and non-bloom sites using stripping voltammetry. The observed hydrographical and meteorological parameters were found to be favorable for the bloom. The concentrations of Zinc, Cadmium and Nickel were found to be higher at bloom stations, while the concentrations of Lead, Copper and Cobalt were found to be very low at bloom stations. Elevated concentrations of Cadmium and Cobalt were observed at Valappad mainly due to the decomposition of detrital material produced in the bloom. Statistically significant differences (P > 0.01) in metal concentrations between the bloom and non-bloom stations were not observed except for Copper. Metals such as Lead, Copper and Cobalt were removed from the seawater at all places where bloom was observed. Cadmium was found to be slowly released during the decaying process of the bloom.  相似文献   

上海潮滩沉积物重金属的动力学累积特征   总被引：65，自引：3，他引：65  

许世远  陶静  陈振楼  陈中原  吕全荣 《海洋与湖沼》1997,28(5):509-515

１９９３年７－８月，在上海长江口南岸和杭州湾北岸淤泥质潮滩不同地貌部位，采集表层沉积物和柱状沉积物样品，采用筛析法，离心法、火焰原子吸收法，＾２１０Ｐｂ法等分别对沉积物粒度、重金属总量，不同粒级重金属含量以及沉积速率等进行了和测定。结果表明，潮滩沉积物重金属的空间分布格局并不受沿岸排污的直接影响，而与沉积动力作用密切相关。在水动力条件较弱的淤涨岸段和高潮滩部位，伴随着细颗粒起泥沙的大量堆积，Ｃｕ，  相似文献   

大别山地区石榴石橄榄岩的岩石学和地球化学     

韩宗珠 《中国海洋大学学报(自然科学版)》1989,(4)

本文首次对我国石榴石橄榄岩类岩石进行系统的岩石学和地球化学研究。通过对大别山地区两个不同类型岩体中的石榴石橄榄岩的岩石学、岩石化学、矿物化学和稀土元素地球化学研究,表明这类岩石属钙碱性系列超基性岩;与地幔成分相比,富集易熔元素,亏损难熔元素;利用矿物地质温压计估算其形成压力为2×10~9pa,成岩温度为600～700℃具有正铕异常和轻稀土元素富集特征 推测为地壳下部的超基性岩经深成变质而成。  相似文献