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91.
Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes 总被引:7,自引:0,他引:7
Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ13C and δ18O values in calcite and heterogeneous single crystal δ13C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ13C and δ18O values in marbles by infiltration of low δ13C–δ18O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO2‐rich fluid, and that the infiltration had occurred under high temperature and low fO2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ13C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism. 相似文献
92.
REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan 总被引:3,自引:1,他引:3
Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas. 相似文献
93.
Ahmed Barakat Christian Marignac Marie-Christine Boiron Mohamed Bouabdelli 《Comptes Rendus Geoscience》2002,334(1):35-41
The gold showings at Bleida are hosted in Late Pan-African N50–80 °E quartz–hematite–chlorite 1 tension lenses that are related to the activity of major sinistral sub-east–west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35–41 相似文献
94.
对2000年1月15日姚安6.5级地震前后云南水汞异常进行分析研究,结果表明:在9个观测台站中,地震前有1个观测台站的水汞出现中期趋势异常,1个台站的水汞出现远震异常,4个台站的水汞出现短期异常,1个台站的水汞出现临震异常。地震前3个月内,水汞短期异常有活跃,平静的过程,在平静中(仅1个台站出现临震异常)发生姚安6.5级地震。姚安地震发生在距出现远震异常的水汞观测台站70km的地方。出现远震异常的水汞观测台站附近,可能是未来强震的发震地区。 相似文献
95.
Paleolatitudes of the Kerguelen hotspot: new paleomagnetic results and dynamic modeling 总被引:1,自引:0,他引:1
The Kerguelen Plateau, a Large Igneous Province in the southern Indian Ocean, was formed as a product of the Kerguelen hotspot in several eruptive phases during the last 120 Myr. We obtained new paleolatitudes for the central and northern Kerguelen Plateau from paleomagnetic investigations on basalts, which were drilled during ODP Leg 183 to the Kerguelen Plateau-Broken Ridge. The paleolatitudes coincide with paleolatitudes from previous investigations at the Kerguelen Plateau and Ninetyeast Ridge (the track of the Kerguelen hotspot) and indicate a difference between paleolatitudes and present position at 49°S of the Kerguelen hotspot. We show that true polar wander, the global motion between the mantle and the rotation axis, cannot explain this difference in latitudes. We present numerical model results of plume conduit motion in a large-scale mantle flow and the resulting surface hotspot motion. A large number of models all predict southward motion between 3° and 10° for the Kerguelen hotspot during the last 100 Myr, which is consistent with our paleomagnetic results. 相似文献
96.
Matthias KeyserJoachim R.R. Ritter Michael Jordan 《Earth and Planetary Science Letters》2002,203(1):59-82
The Quaternary Eifel volcanic fields, situated on the Rhenish Massif in Germany, are the focus of a major interdisciplinary project. The aim is a detailed study of the crustal and mantle structure of the intraplate volcanic fields and their deep origin. Recent results from a teleseismic P-wave tomography study reveal a deep low-velocity structure which we infer to be a plume in the upper mantle underneath the volcanic area [J.R.R. Ritter et al., Earth Planet. Sci. Lett. 186 (2001) 7-14]. Here we present a travel-time investigation of 5038 teleseismic shear-wave arrivals in the same region. First, the transverse (T) and radial (R) component travel-time residuals are treated separately to identify possible effects of seismic anisotropy. A comparison of 2044 T- and 2994 R-component residuals demonstrates that anisotropy does not cause any first-order travel-time effects. The data sets reveal a deep-seated low-velocity anomaly beneath the volcanic region, causing a delay for teleseismic shear waves of about 3 s. Using 3773 combined R- and T-component residuals, an isotropic non-linear inversion is calculated. The tomographic images reveal a prominent S-wave velocity reduction in the upper mantle underneath the Eifel region. The anomaly extends down to at least 400 km depth. The velocity contrast to the surrounding mantle is depth-dependent (from −5% at 31-100 km depth to at least −1% at 400 km depth). At about 170-240 km depth the anomaly is nearly absent. The resolution of the data is sufficient to recover the described features, however the anomaly in the lower asthenosphere is underestimated due to smearing and damping. The main anomaly is similar to the P-wave model except the latter lacks the ‘hole’ near 200 km depth, and both are consistent with an upper mantle plume structure. For plausible anhydrous plume material in the uppermost 100 km of the mantle, an excess temperature as great as 200-300 K is estimated from the seismic anomaly. However, 1% partial melt reduces the required temperature anomaly to about 100 K. The temperature anomaly associated with the deeper part of the plume (250 to about 450 km depth) is at least 70 K. However, this estimate is quite uncertain, because the amplitude of the shear-wave anomaly may be larger than the modelled one. Another possibility is water in the upwelling material. The gap at 170-240 km depth could arise from an increase of the shear modulus caused by dehydration processes which would not affect P-wave velocities as much. An interaction of temperature and compositional variations, including melt and possibly water, makes it difficult to differentiate quantitatively between the causes of the deep-seated low-velocity anomaly. 相似文献
97.
Determining gaseous composition of fluid inclusions with quadrupole mass spectrometer 总被引:3,自引:0,他引:3
Quadrupole mass spectrometer (QMS) is an instrument for effectively determining gaseous composition of fluid inclusion. The
gaseous component is extracted from inclusions with thermal decrepitation method and then determined with the sensitive QMS
instrument. The method is characterized by high sensitivity and high accuracy with the relative standard deviation (RSD,n=6) of less than 3%. It has been successfully used for analyzing fluid inclusions. The analytical results meet the requirement
of geological study. 相似文献
98.
99.
100.
This paper is dedicated to the identification of constitutive parameters of elasto‐viscoplastic constitutive law from measurements performed on deep underground cavities (typically tunnels). This inverse problem is solved by the minimization of a cost functional of least‐squares type. The exact gradient is computed by the direct differentiation method and the descent is done using the Levenberg–Marquardt algorithm. The method is presented for lined or unlined structures and is applied for an elastoviscoplastic constitutive law of the Perzyna class. Several identification problems are presented in one and two dimensions for different tunnel geometries. The used measurements have been obtained by a preliminary numerical simulation and perturbed with a white noise. The identified responses match the measurements. We also discuss the usage of the sensitivity analysis of the system, provided by the direct differentiation method, for the optimization of in situ monitoring. The sensitivity distribution in space and time assess the location of the measurements points as well as the time of observation needed for reliable identification. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献