Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment     

Holger L. Fröhlich  Lutz Breuer  Hans‐Georg Frede  Johan A. Huisman  Kellie B. Vaché 《水文研究》2008,22(12):2028-2043

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

深海原位取芯钻机作业机理分析及实验研究     

杨磊  丁忠军  李德威  李宝钢  杨雷  任玉刚  刘庆亮  刘敬喜 《海洋技术学报》2015,34(1):32-37

针对深海运载器海底岩芯原位取样作业需求,对基于水下运载器的深海原位取芯钻机在深海低温、高压、底层流速多变等特点条件下的作业机理及受力进行分析,并选取硬质合金钻头和PDC钻头进行了取芯钻头的轴向力、切向力和切削功率的数学力学对比计算,确定了单环四齿周向均布的金刚石复合片(PDC)钻头设计方案。在理论分析基础上,针对深海钴结壳设计了台架试验,开展钻进试验研究。通过理论计算和实验研究,探寻了一种基于深海运载器的钴结壳小型钻机设计方法,确定了钻机功率、转速、钻进正向压力和取芯率等基本参数选取范围,对开展海底岩芯原位取样作业具有重要的指导意义。  相似文献   

页岩气资源调查评价中的采样测试工作     

李昭容  梁晓玲  王志文 《国土资源导刊(湖南)》2015,(1):90-95

页岩气是一种新的能源矿产,具有巨大的勘查开发潜力,现已成为全球油气勘探的一个新领域。采样测试作为一种勘查手段,在页岩气气藏岩性、成因来源、赋存形式、成藏特征、成藏条件、含气量等方面的研究中起着极其重要的作用,在页岩气的勘查开发中具有极其重要的意义。在页岩气资源评价等勘查中,正确采集测试样品、合理选定测试项目和测试方法、有效运用采样测试这一勘查手段,是页岩气资源调查评价中一项十分重要的工作。  相似文献   

Impact of different sampling rates on precise point positioning performance using online processing service     

Serdar Erol  Reha Metin Alkan  ?.Murat Ozulu  Veli Il?i 《地球空间信息科学学报》2021,24(2):302-312

In this study, the effect of different sampling rates (i.e. observation recording interval) on the Precise Point Positioning (PPP) solutions in terms of accuracy was investigated. For this purpose, a field test was carried out in ?orum province, Turkey, on 11 September 2019. Within this context, a Geodetic Point (GP) was established and precisely coordinated. A static GNSS measurement was occupied on the GP for about 4-hour time at 0.10 second (s)/10 Hz measurement intervals with the Trimble R10 geodetic grade GNSS receiver. The original observation file was converted to RINEX format and then decimated into the different data sampling rates as 0.2 s, 0.5 s, 1 s, 5 s, 10 s, 30 s, 60 s, and 120 s. All these RINEX observation files were submitted to the Canadian Spatial Reference System-Precise Point Positioning (CSRS-PPP) online processing service the day after the data collection date by choosing both static and kinematic processing options. In this way, PPP-derived static coordinates, and the kinematic coordinates of each measurement epoch were calculated. The PPP-derived coordinates obtained from each decimated sampling intervals were compared to known coordinates of the GP for northing, easting, 2D position, and height components. According to the static and kinematic processing results, high data sampling rates did not change the PPP solutions in terms of accuracy when compared to the results obtained using lower sampling rates. The results of this study imply that it was not necessary to collect GNSS data with high-rate intervals for many surveying projects requiring cm-level accuracy.  相似文献   

Evaluation of the Historical Sampling Error for Global Models          下载免费PDF全文

SHEN Si  LIU Juan-Juan  WANG Bin 《大气和海洋科学快报》2015,8(5)

Various ensemble-based schemes are employed in data assimilation because they can use the ensemble to estimate the flow-dependent background error covariance. The most common way to generate the real-time ensemble is to use an ensemble forecast; however, this is very time-consuming. The historical sampling approach is an alternative way to generate the ensemble,by picking some snapshots from historical forecast series.With this approach, many ensemble-based assimilation schemes can be used in a deterministic forecast environment. Furthermore, considering the time that it saves, the method has the potential for operational application.However, the historical sampling approach carries with it a special kind of sampling error because, in a historical forecast, the way to integrate the ensemble members is different from the way to integrate the initial conditions at the analysis time(i.e., forcing and lateral boundary condition differences, and ‘warm start' or ‘cold start' differences). This study analyzes the results of an experiment with the Global Regional Assimilation Prediction System-Global Forecast System(GRAPES-GFS), to evaluate how the different integration configurations influence the historical sampling error for global models. The results show that the sampling error is dominated by diurnal cycle patterns as a result of the radiance forcing difference.Although the RMSEs of the sampling error are small, in view of the correlation coefficients of the perturbed ensemble, the sampling error for some variables on some levels(e.g., low-level temperature and humidity, stratospheric temperature and geopotential height and humidity), is non-negligible. The results suggest some caution must be applied, and advice taken, when using the historical sampling approach.  相似文献   

Common bivalve larvae from New Zealand: Leptonacea   总被引：1，自引：1，他引：0  

J. D. Booth 《新西兰海洋与淡水研究杂志》2013,47(2):241-254

The late stage larvae of three erycinid bivalves (Mollusca: Pelecypoda: Leptonacea) taken from the brood chamber of the adult are described (Kellia cycladiformis, Lasaea rubra hinemoa, and L. maoria), and the provisionally identified late stage larva of the erycinid Arthritica bijurca taken from the plankton is described. Also, the D‐shaped larvae of the erycinid bivalves Kellia cycladiformis, Borniola reniformis, Arlhritica crassijormis, and A. bifurca taken from the parent brood chamber are described. The seasonal occurrence of each late stage larva in the plankton at the Bay of Islands (35° 15'S, 174° 10'E), Wellington Harbour (41° 16'S, 174° 51'E), and Raumati Beach (40° 56'S, 174° 58'E), New Zealand is described. Aspects of the reproductive cycles of Lasaea rubra hinemoa and Arthritica bifurca are presented.  相似文献   

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales     

Krahn MM  Hanson MB  Baird RW  Boyer RH  Burrows DG  Emmons CK  Ford JK  Jones LL  Noren DP  Ross PS  Schorr GS  Collier TK 《Marine pollution bulletin》2007,54(12):1903-1911

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.  相似文献   

Capturing temporal variability for estimates of annual hydrochemical export from a first‐order agricultural catchment in southern Ontario,Canada     

M. L. Macrae  M. C. English  S. L. Schiff  M. Stone 《水文研究》2007,21(13):1651-1663

This 2‐year study (2000, 2001) reports annual nutrient (phosphorus, nitrate) export from a first‐order agricultural watershed in southern Ontario based on an intensive monitoring programme. The importance of storm and melt events in annual export estimates is demonstrated and the temporal variability in nutrient loading during events is related to processes occurring within the catchment. The feasibility of predicting event‐related nutrient export from hydrometric data is explored. The importance of sampling frequency throughout events is also shown. Export of total phosphorus (TP), soluble reactive phosphorus (SRP) and nitrate ( ) for 2000 and 2001 averaged 0·35 kg ha^?1 year^?1, 0·09 kg ha^?1 year^?1, and 35 kg ha^?1 year^?1 (as N) respectively. Approximately 75% of annual TP export, 80% of annual SRP export and 70% of annual export occurred during 28 events per year. A small number of large‐magnitude events (>34 mm) accounted for 18–42% of annual TP export, 0–61% of annual SRP export and 13–33% of annual NO export. Our results show that temporal variability in nutrient export is largely governed by discharge in this basin, and export can be predicted from discharge. SRP and TP export can also be predicted from discharge, but only for events that are not large in magnitude. The sampling interval throughout events is important in obtaining precise estimates of nutrient export, as infrequent sampling intervals may over‐ or under‐estimate nutrient export by ± 45% per event for P. This study improves our understanding of and P export patterns and our ability to predict or model them by relating temporal variability in event nutrient export to discharge and processes occurring within the basin, and also by exploring the significance of sampling interval in the context of the importance of individual events, season and temporal variability during events. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

复杂应力条件下长江口原状饱和软黏土门槛循环应力比试验研究     

刘功勋  栾茂田  郭莹  王忠涛  贺林  张俊峰 《岩土力学》2010,31(4):1123-1129

针对取自于长江口的海洋原状饱和软黏土,利用土工静力-动力液压三轴-扭转多功能剪切仪,在控制不同初始固结参数的三向非均等固结状态和不排水条件下,分别进行了轴向和扭转双向耦合循环剪切以及循环扭剪等多种复杂循环剪切试验。分别研究了初始大主应力方向角、初始偏应力比、初始中主应力系数以及循环剪切应力模式等因素对门槛循环应力比的影响。试验结果表明,在三向非均等固结条件下,初始大主应力方向角、初始偏应力比对门槛循环应力比影响显著,门槛循环应力比随着初始大主应力方向角与初始偏应力比的增大而明显减小;而初始中主应力系数对门槛循环应力比基本没有影响。循环剪切应力模式对门槛循环应力比具有显著影响,在相同的初始固结应力条件下,循环耦合剪切试验确定的门槛循环应力比明显小于循环扭剪试验所确定的门槛循环应力比。  相似文献   

洪水频率分析的次序统计量   总被引：1，自引：1，他引：0       下载免费PDF全文

刘九夫  谢自银  鲍振鑫  朱元甡 《水科学进展》2010,21(2):179-187

系统阐述了洪水频率分析涉及的洪水次序统计量和广义次序统计量及其抽样分布,并通过数学实验和统计试验两种途径研究了洪水次序统计量、频率次序统计量和重现期次序统计量抽样分布的统计特征及其关系。研究得到的次序统计量和广义次序统计量抽样分布的期望值和中值关系为系统分析和评价适线法奠定了理论基础。  相似文献