Calculated Phase Relations in the System Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O with Applications to UHP Eclogites and Whiteschists   总被引：2，自引：0，他引：2  

YANG  JIAN-JUN; POWELL  ROGER 《Journal of Petrology》2006,47(10):2047-2071

Pressure–temperature grids in the system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O and its subsystems have been calculatedin the range 15–45 kbar and 550–900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressure–temperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H₂O-carriersin subducting slabs. Depending on bulk composition and pressure–temperaturepath, amphibole may or may not be a major H₂O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H₂O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists  相似文献   

The Physico-Chemical Properties of a Subducted Slab from Garnet Zonation Patterns (Sesia Zone, Western Alps)   总被引：3，自引：0，他引：3  

KONRAD-SCHMOLKE  MATTHIAS; BABIST  JOCHEN; HANDY  MARK R.; O'BRIEN  PATRICK J. 《Journal of Petrology》2006,47(11):2123-2148

Garnets in continentally derived high-pressure (HP) rocks ofthe Sesia Zone (Western Alps) exhibit three different chemicalzonation patterns, depending on sample locality. Comparisonof observed garnet zonation patterns with thermodynamicallymodelled patterns shows that the different patterns are causedby differences in the water content of the subducted protolithsduring prograde metamorphism. Zonation patterns of garnets inwater-saturated host rocks show typical prograde chemical zonationswith steadily increasing pyrope content and increasing XMg,together with bell-shaped spessartine patterns. In contrast,garnets in water-undersaturated rocks have more complex zonationpatterns with a characteristic decrease in pyrope and XMg betweencore and inner rim. In some cases, garnets show an abrupt compositionalchange in core-to-rim profiles, possibly due to water-undersaturationprior to HP metamorphism. Garnets from both water-saturatedand water-undersaturated rocks show signs of intervening growthinterruptions and core resorption. This growth interruptionresults from bulk-rock depletion caused by fractional garnetcrystallization. The water content during burial influences significantly thephysical properties of the subducted rocks. Due to enhancedgarnet crystallization, water-undersaturated rocks, i.e. thoselacking a free fluid phase, become denser than their water-saturatedequivalents, facilitating the subduction of continental material.Although water-bearing phases such as phengite and epidote arestable up to eclogite-facies conditions in these rocks, dehydrationreactions during subduction are lacking in water-undersaturatedrocks up to the transition to the eclogite facies, due to thethermodynamic stability of such hydrous phases at high P–Tconditions. Our calculations show that garnet zonation patternsstrongly depend on the mineral parageneses stable during garnetgrowth and that certain co-genetic mineral assemblages causedistinct garnet zonation patterns. This observation enablesinterpretation of complex garnet growth zonation patterns interms of garnet-forming reactions and water content during HPmetamorphism, as well determination of detailed P–T paths. KEY WORDS: dehydration; high-pressure metamorphism; Sesia Zone; subduction; thermodynamic modelling  相似文献   

Ca-rich Garnet-Clinopyroxene Rocks at Hujialin in the Su-Lu Terrane (Eastern China): Deeply Subducted Arc Cumulates?   总被引：3，自引：0，他引：3  

YANG  JIAN-JUN 《Journal of Petrology》2006,47(5):965-990

Layers of Ca-rich garnet–clinopyroxene rocks enclosedin a serpentinite body at Hujialin, in the Su–Lu terraneof eastern China, preserve igneous textures, relict spinel ingarnet, and exsolution lamellae of Ca-rich garnet, ilmenite/magnetite,Fe-rich spinel, and also amphibole in clinopyroxene. In termsof their major and trace element compositions, the studied samplesform a trend from arc cumulates towards Fe–Ti gabbros.Reconstructed augite compositions plot on the trend for clinopyroxenein arc cumulates. These data suggest that the rocks crystallizedfrom mantle-derived magmas differentiated to various extentsbeneath an arc. The Ca-rich garnet + diopside assemblage isinferred to have formed by compressing Ca-rich augite, whereasthe relatively Mg-rich cores of garnet porphyroblasts may haveformed at the expense of spinel. The protolith cumulates weresubducted from near the crust–mantle boundary (c. 1 GPa)deep into the upper mantle (4·8 ± 0·6 GPaand 750 ± 50°C). Negatively sloped P–T pathsfor the garnet–clinopyroxene rocks and the corollary ofcorner flow induced subduction of mantle wedge peridotite arenot supported by the available data. Cooling with, or without,decompression of the cumulates after the igneous stage probablyoccurred prior to deep subduction. KEY WORDS: arc cumulates; Ca-rich garnet; garnet–clinopyroxene rocks; Su–Lu terrane; UHP metamorphism  相似文献   

低阻油气储层测井解释方法研究     

LI Zheng-xi 《吉林大学学报(地球科学版)》2006,(Z2)

对低阻油气储层的测井响应特征和储层物性特征进行了研究,并针对研究区域低阻储层的特点,以岩心与测井数据的相关性为依据,提出了适合地区特点的储层参数解释方法。通过应用三水导电模型,提高了低阻储层的测井解释精度。  相似文献   

基于GIS的供电台区经营综合评价     

王玲  边馥苓 《测绘信息与工程》2005,30(6):32-33

探讨了运用GIS技术对供电台区经营综合评价的实现方法,选取了业务属性和空间属性两个方面评价因子,介绍了从系统软硬件、评价实现过程及显示结果等方面评价过程的具体技术实现。  相似文献   

不等电极距情况下高密度电阻率法的反演结果分析     

吴云超  王传雷  陈超 《物探与化探》2005,29(1):19-21

通过高密度电阻率法的模型实验,得出不等电极距情况对直立高阻薄板和低阻球体反演结果的影响:缺失电极对它正下方的ρ_s影响最大,而异常形态主要在水平方向有明显的变化,异常体随电极缺失的位置有趋势变化,电极缺失的数目越多,异常形态变化越大,但是从整体来看反演剖面图基本相似。  相似文献   

宁夏自治区生态农业地质研究及其前景     

曾昭华 《西北地质》2005,38(3):111-118

论述了宁夏回族自治区土壤元素含量和农作物优质高产与土壤环境中化学元素N、P、K、S、Fe、Mn、Cu、Zn、B、Mo、V、Sr、Ti、Mg、La、Ce、Pr、Nd、Sm、Eu、Y、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Ca、Co、Ni、F、Tl、Si、Na、Cr、Pb、Cd、Hg、Se、Ba、Te、Ta有密切的关系.提出了生态农业地质研究的目的、内容、方法、管理及其前景。  相似文献   

塔里木盆地阿克库勒地区石炭系卡拉沙依组成岩作用     

刘辰生  郭建华  苏娟 《新疆地质》2005,23(3):288-291

阿克库勒地区卡拉沙依组碎屑岩储层的成分成熟度和结构成熟度均较低．储层的次生溶蚀孔隙所占比例远高了：原生孔隙，次生孔隙是储层的主要储集空间．样品数据统计显示，卡拉沙依组储层属于低孔、低渗储层类型．根据岩石薄片、铸体薄片观察及储层样品的扫描电镜和阴极发光分析结果，本区石炭系储层主要经历的成岩作用有压实（压溶）作用、胶结作用、溶蚀作用和交代作用，其中碳酸盐矿物的沉淀和溶蚀作用是本区卡拉沙依组储层所经历的最重要的成岩作用．成岩作用已达到晚成岩B期，早期方解石交代石英颗粒并发生大量溶蚀，生成大量次生孔隙，晚期方解石没有发生溶蚀．  相似文献   

过硫酸铵氧化容量法测定矿石中锰方法的改进   总被引：5，自引：1，他引：5  

范福南 《岩矿测试》2005,24(3):235-236

采用过硫酸铵氧化容量法测定锰时,可在低酸度(0.18mol/LH2SO4、0.29mol/LH3PO4)和大体积(300mL)溶液中氧化Mn2 至Mn7 。所测得的结果十分稳定,回收率为100%。采用管理样分析验证方法,其结果与铋酸钠容量法结果一致。对于w(Mn)=11.36%的试样进行10次分析测定,RSD=0.33%。方法可测定w(Mn)≥0.01%的常见矿种样品。  相似文献   

中国大陆科学钻探工程主孔榴辉岩的岩石学研究   总被引：19，自引：0，他引：19       下载免费PDF全文

张泽明张金凤  许志琴刘福来杨经绥  肖益林沈 昆 《中国地质》2005,32(2):205-217

中国大陆科学钻探工程5000m主孔位于苏鲁超高压变质带南部。该钻孔0～2000m主要由榴辉岩、片麻岩、石榴石橄榄岩和少量片岩和石英岩组成。累积厚度达1000多米的榴辉岩具有不同的矿物组成、不同的矿物含量和不同的全岩化学成分,可划分成富Si的石英榴辉岩、富Ti的金红石榴辉岩、富Al的多硅白云母和蓝晶石榴辉岩、富Mg的双矿物榴辉岩和具有正常玄武岩成分的普通榴辉岩。榴辉岩的原岩包括基性层状侵入岩和变质表壳岩。榴辉岩全岩成分对石榴石和绿辉石中某些化学组分的含量有明显控制,而且直接影响到变质条件估算的准确性。扩散成分环带的广泛发育表明超高压矿物在早期退变质过程中发生了成分再平衡。这一事实以及具有成分生长环带石榴石变斑晶的存在,为榴辉岩形成在更高温度(>940℃)和更高压力(>4.5GPa)条件下提供了有力的证据。  相似文献